Permanent light-induced polar orientation via all-optical poling and photothermal cross-linking in a polymer thin film

2006 ◽  
Vol 260 (2) ◽  
pp. 708-711 ◽  
Author(s):  
A. Apostoluk ◽  
J.-M. Nunzi ◽  
V. Boucher ◽  
A. Essahlaoui ◽  
R. Seveno ◽  
...  
Keyword(s):  
Thin Film ◽  
Cross Linking ◽  
Polymer Thin Film ◽  
All Optical ◽  
Polar Orientation

ALL-OPTICAL REFLECTANCE CONTROL BASED ON PHOTOINDUCED COMPLEX REFRACTIVE INDEX CHANGES IN GUIDED MODE THIN FILMS CONTAINING INDIUM OR GALLIUM PHTHALOCYANINES

2002 ◽  
Vol 11 (03) ◽  
pp. 205-218 ◽  
Author(s):  
TOSHIHIKO NAGAMURA ◽  
ATSUSHI NAITO ◽  
IORI YOSHIDA ◽  
YU CHEN ◽  
MICHAEL HANACK
Keyword(s):  
Thin Film ◽  
Refractive Index ◽  
Complex Refractive Index ◽  
Nanosecond Laser ◽  
Polymer Thin Film ◽  
Optical Reflectance ◽  
Guided Mode ◽  
All Optical ◽  
Silver Thin Film ◽  
Index Changes

Tetrasubstituted indium or gallium phthalocyanines and their dimers bridged with various ligands were dispersed in a polymer thin film, which was spin-coated on silver thin film vacuum-evaporated on a glass slide. All-optical reflectance control was achieved by complex refractive index changes upon photoexcitation of phthalocyanines by nanosecond laser in such a guided mode geometry. They gave rise in less than ns pulse width, and a few to a few tens of microseconds decay characteristic to the lifetime of the excited triplet state. Repeated and reversible reflectance changes were achieved. Axially bridged phthalocyanine dimers showed almost the same photoresponses as monomers.

Radically- and Thermally-cured High-SiOH Methylvinylsiloxane Polymer Thin Film for Electric Insulator Applications for TFT

2010 ◽  
Vol 1247 ◽  
Author(s):  
Tadashi Nakano ◽  
An KiHwan ◽  
Jung SoRa
Keyword(s):  
Thin Film ◽  
Thin Film Transistor ◽  
Gate Insulator ◽  
Light Transmittance ◽  
Cross Linking ◽  
Polymer Thin Film ◽  
Pencil Hardness ◽  
Flexible Displays ◽  
Touch Panels ◽  
Ft Raman

AbstractHydrolytically polymerized poly(methyl-co-vinyl)siloxane is cross-linked by radically and dehydrolytically at elevated temperature. Peroxide-type thermal radical generator is found to cross-link the polymer at the vinyl and methyl pendant groups. In parallel, free silanol (Si-OH) end groups in the polymer also contribute to cross-linking by dehydrolytic polycondensation. By use of these two-fold cross-linking mechanisms, we were able to deposit highly cross-linked siloxane polymer film which provides excellent optical and electrical properties. Cured film of 500 nm thickness exhibited the pencil hardness of 9H on glass with > 95% visible light transmittance. These excellent features are applied to optical hard coating for flexible displays and touch panels. The cured film also exhibited excellent electric properties. The leakage current of the film is as low as that of CVD dielectric film, and the break down field is exceeded 3 MV/cm, which enabled the film to be applied to insulator in thin film transistor. We carried out analyses of the polymer in film and powder form with 13C- and 29Si-NMR MAS, FT-RAMAN and FTIR-ATR methods to investigate curing mechanism. The analysis results clearly indicated that the cured film contains unique Si-(CH)n-Si bonds generated by radical crosslinking, and all the Si-OH bonds are consumed by hydrolytic polycondensation as well. The Si-(CH)n-Si bonds are more rigid and less polar than Si-O-Si bond, which should be the major reasons that radical condensation remarkably reinforced the film. This radically and thermally cured poly(methyl-co-vinyl)siloxane film was applied to Mo-gate thin film transistor fabricated on glass as the gate insulator. The I-V characteristics from the transistor were equivalent to those made using CVD-SiN insulator.

Real-time monitoring of all-optical poling of azo-dye polymer thin film

2000 ◽  
Vol 25 (13) ◽  
pp. 960 ◽  
Author(s):  
Victor M. Churikov ◽  
Meng Feng Hung ◽  
Chia Chen Hsu
Keyword(s):  
Thin Film ◽  
Real Time ◽  
Azo Dye ◽  
Real Time Monitoring ◽  
Polymer Thin Film ◽  
All Optical

Effect of Illumination on Organic Polymer Thin-Film Transistors

2003 ◽  
Vol 771 ◽  
Author(s):  
Michael C. Hamilton ◽  
Sandrine Martin ◽  
Jerzy Kanicki
Keyword(s):  
Thin Film ◽  
Thin Film Transistors ◽  
Drain Current ◽  
Charge Carriers ◽  
Electrical Performance ◽  
Organic Polymer ◽  
Light Illumination ◽  
Polymer Thin Film ◽  
Channel Region ◽  
White Light Illumination

AbstractWe have investigated the effects of white-light illumination on the electrical performance of organic polymer thin-film transistors (OP-TFTs). The OFF-state drain current is significantly increased, while the drain current in the strong accumulation regime is relatively unaffected. At the same time, the threshold voltage is decreased and the subthreshold slope is increased, while the field-effect mobility of the charge carriers is not affected. The observed effects are explained in terms of the photogeneration of free charge carriers in the channel region due to the absorbed photons.

Cross-Linking of Poly(arylenebutadiynylene)s and Its Effect on Charge Carrier Mobilities in Thin-Film Transistors

2021 ◽  
Author(s):  
Sultan Otep ◽  
Kosuke Ogita ◽  
Naomasa Yomogita ◽  
Kazunori Motai ◽  
Yang Wang ◽  
...  
Keyword(s):  
Thin Film ◽  
Charge Carrier ◽  
Thin Film Transistors ◽  
Cross Linking

Conducting polymer thin film for optoelectronic devices applications

2021 ◽  
Author(s):  
Mohamed H. Abdel‐Aziz ◽  
Mohammed Zwawi ◽  
Ahmed F. Al‐Hossainy ◽  
Mohamed Sh. Zoromba
Keyword(s):  
Thin Film ◽  
Conducting Polymer ◽  
Optoelectronic Devices ◽  
Polymer Thin Film

Radical-triggered cross-linking for molecular layer deposition of SiAlCOH hybrid thin films

2021 ◽  
Author(s):  
Kristina Ashurbekova ◽  
Karina Ashurbekova ◽  
Iva Saric ◽  
Evgeny Modin ◽  
Mladen Petravic ◽  
...  
Keyword(s):  
Thin Film ◽  
Film Growth ◽  
Molecular Layer ◽  
Thin Film Growth ◽  
Cross Linking ◽  
Layer By Layer ◽  
Molecular Layer Deposition ◽  
Layer Deposition ◽  
Hybrid Thin Films ◽  
Enhanced Stability

We developed a thin film growth with a radical-initiated cross-linking of vinyl groups in a layer-by-layer manner via molecular layer deposition (MLD). The cross-linked film exhibited improved properties like 12% higher density and enhanced stability compared to the non-cross-linked film.

scholarly journals A Theoretical Study on an Elastic Polymer Thin Film-Based Capacitive Wind-Pressure Sensor

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2133
Author(s):  
Xue Li ◽  
Jun-Yi Sun ◽  
Bin-Bin Shi ◽  
Zhi-Hang Zhao ◽  
Xiao-Ting He
Keyword(s):  
Thin Film ◽  
Closed Form ◽  
Pressure Sensor ◽  
Closed Form Solution ◽  
Form Solution ◽  
Wind Pressure ◽  
Polymer Thin Film ◽  
Movable Electrode ◽  
Elastic Polymer ◽  
Electrode Plate

This study is devoted to the design of an elastic polymer thin film-based capacitive wind-pressure sensor to meet the anticipated use for real-time monitoring of structural wind pressure in civil engineering. This sensor is composed of four basic units: lateral elastic deflection unit of a wind-driven circular polymer thin film, parallel plate capacitor with a movable circular electrode plate, spring-driven return unit of the movable electrode plate, and dielectric materials between electrode plates. The capacitance of the capacitor varies with the parallel move of the movable electrode plate which is first driven by the lateral elastic deflection of the wind-driven film and then is, after the wind pressure is reduced or eliminated, returned quickly by the drive springs. The closed-form solution for the contact problem between the wind-driven thin film and the spring-driven movable electrode plate is presented, and its reliability is proved by the experiment conducted. The numerical examples conducted show that it is workable that by using the numerical calibration based on the presented closed-form solution the proposed sensor is designed into a nonlinear sensor with larger pressure-monitoring range and faster response speed than the linear sensor usually based on experimental calibration.

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