Vanadium-containing mesoporous carbon and mesoporous carbon nanoparticles as catalysts for benzene hydroxylation reaction

2017 ◽  
Vol 11 ◽  
pp. 61-67 ◽  
Author(s):  
Liya Hu ◽  
Cheng Wang ◽  
Bin Yue ◽  
Xueying Chen ◽  
Heyong He
Author(s):  
Danlei Wei ◽  
Lianqi Huang ◽  
Hanying Liang ◽  
Junhua Zou ◽  
Wenwen Chen ◽  
...  

Photocatalytic benzene hydroxylation reaction using clean oxidant such as H2O2 is a green synthetic approach for phenol synthesis. Here, our study shows that the silylated iron vanadate (FeVO4) nanorods can...


2020 ◽  
Vol 229 ◽  
pp. 115508 ◽  
Author(s):  
Hongyan Lu ◽  
Guangzhao Yang ◽  
Fu Ran ◽  
Tianbin Gao ◽  
Changshan Sun ◽  
...  

NANO ◽  
2018 ◽  
Vol 13 (08) ◽  
pp. 1850094
Author(s):  
Qiang Sun ◽  
Long Liu ◽  
Yi-Ding Li ◽  
Zeng-Rong Wang ◽  
Xue Zhang

We report engineered iron-based nanoparticles supported on cagelike mesoporous carbon that leaves its most mesopores empty to retain an open pore network and are expected to be efficient catalyst with fast molecular diffusion/transportation. The nano-scale iron-based particle inlayed in mesoporous carbon catalyst was obtained via the introduction of N atoms as an anchor. Results of X-ray diffraction, N2 sorption and transmission electron microscopy showed that the cagelike mesoporous structure of the carbon matrix was retained during catalyst preparation and iron-based nanoparticles were spatially dispersed on the mesoporous carbon. Importantly, it was found that the obtained iron-based nanoparticles inlayed into mesoporous carbon with a low Fe loading of 1.26[Formula: see text]wt.% was an appropriate catalyst for the benzene hydroxylation to phenol using H2O2 as the oxidant. At a low temperature of 30∘C, 19.4% conversion to benzene and 14.6% phenol yield were obtained; in addition, the catalyst could be recycled at least four times.


2020 ◽  
Vol 293 ◽  
pp. 109803
Author(s):  
Juan Liu ◽  
Yajuan Zhao ◽  
Lingling Xu ◽  
Xiufang Wang ◽  
Yong Tian

2020 ◽  
Vol 7 (17) ◽  
pp. 3653-3655 ◽  
Author(s):  
Seong‐Jun Kim ◽  
Minchul Ahn ◽  
Jungjin Park ◽  
Yunseo Jeoun ◽  
Seung‐Ho Yu ◽  
...  

2020 ◽  
Vol 12 (13) ◽  
pp. 14946-14957 ◽  
Author(s):  
Miguel Gisbert-Garzarán ◽  
Julia C. Berkmann ◽  
Dimitra Giasafaki ◽  
Daniel Lozano ◽  
Konstantinos Spyrou ◽  
...  

2017 ◽  
Vol 38 (2) ◽  
pp. 271-277 ◽  
Author(s):  
Ganesan Raja ◽  
Siwon Kim ◽  
Dahye Yoon ◽  
Changshin Yoon ◽  
Suhkmann Kim

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