pH- and sugar-sensitive multilayer films composed of phenylboronic acid (PBA)-modified poly(allylamine hydrochloride) (PBA-PAH) and poly(vinyl alcohol) (PVA): A significant effect of PBA content on the film stability

2016 ◽  
Vol 62 ◽  
pp. 474-479 ◽  
Author(s):  
Masaru Seno ◽  
Kentaro Yoshida ◽  
Katsuhiko Sato ◽  
Jun-ichi Anzai
Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1854 ◽  
Author(s):  
Kentaro Yoshida ◽  
Akane Yamaguchi ◽  
Hiroki Midorikawa ◽  
Toshio Kamijo ◽  
Tetsuya Ono ◽  
...  

Phenylboronic acid-bearing polyamidoamine dendrimer (PBA-PAMAM)/poly(vinyl alcohol) (PVA) multilayer films were prepared through the layer-by-layer (LbL) deposition of PBA-PAMAM solution and PVA solution. PBA-PAMAM/PVA films were constructed successfully through the formation of boronate ester bonds between the boronic acid moiety in PBA and 1,3-diol units in PVA. When the (PBA-PAMAM/PVA)5 films were immersed in rose bengal (RB) solution, RB was adsorbed onto the LbL films. The amount of RB adsorbed was higher in the LbL films immersed in acidic solution than in basic solution. The release of RB from the LbL films was also promoted in the basic solution, while it was suppressed in the acidic solution. The boronic acid ester is oxidized to phenol by hydrogen peroxide (H2O2) and the carbon-boron bond is cleaved, so that the (PBA-PAMAM/PVA)5 films can be decomposed by immersion in H2O2 solution. Therefore, when RB-adsorbed (PBA-PAMAM/PVA)5 films were immersed in H2O2 solution, the release of RB was moderately promoted when the solution was weakly acidic.


2015 ◽  
Vol 135 ◽  
pp. 133-142 ◽  
Author(s):  
Katarzyna Zasada ◽  
Magdalena Łukasiewicz-Atanasov ◽  
Katarzyna Kłysik ◽  
Joanna Lewandowska-Łańcucka ◽  
Barbara Gzyl-Malcher ◽  
...  

2013 ◽  
Vol 114 (2) ◽  
pp. 153-157 ◽  
Author(s):  
Marta Stroescu ◽  
Anicuta Stoica-Guzun ◽  
Iuliana Mihaela Jipa

2018 ◽  
Vol 66 (4) ◽  
pp. 368-374 ◽  
Author(s):  
Chihiro Takei ◽  
Yui Ohno ◽  
Tomohiro Seki ◽  
Ryotaro Miki ◽  
Toshinobu Seki ◽  
...  

2015 ◽  
Vol 3 (39) ◽  
pp. 7796-7802 ◽  
Author(s):  
Katsuhiko Sato ◽  
Mao Takahashi ◽  
Megumi Ito ◽  
Eiichi Abe ◽  
Jun-Ichi Anzai

Phenylboronic acid-bearing poly(allylamine)/poly(vinyl alcohol) layer-by-layer films coupled with glucose oxidase decomposed in the presence of glucose under physiological conditions.


Langmuir ◽  
2014 ◽  
Vol 30 (31) ◽  
pp. 9247-9250 ◽  
Author(s):  
Katsuhiko Sato ◽  
Mao Takahashi ◽  
Megumi Ito ◽  
Eiichi Abe ◽  
Jun-ichi Anzai

Polymer ◽  
2014 ◽  
Vol 55 (12) ◽  
pp. 2841-2847 ◽  
Author(s):  
Toshiyuki Kida ◽  
Tomoya Ohta ◽  
Kenta Kondo ◽  
Mitsuru Akashi

2015 ◽  
Vol 3 (33) ◽  
pp. 6740-6745 ◽  
Author(s):  
Taka-Aki Asoh ◽  
Kohtaroh Takaishi ◽  
Akihiko Kikuchi

Poly(vinyl alcohol) (PVA) hydrogels adhered to each other following the electrophoretic manipulation of water-soluble intermediate phenylboronic acid copolymers at the interface of the PVA hydrogels.


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