Effect of amino-functionalization on the interfacial adhesion of multi-walled carbon nanotubes/epoxy nanocomposites

2012 ◽  
Vol 33 ◽  
pp. 405-412 ◽  
Author(s):  
Yunfeng Luo ◽  
Yan Zhao ◽  
Jizhe Cai ◽  
Yuexin Duan ◽  
Shanyi Du
Keyword(s):  
Carbon Nanotubes ◽  
Interfacial Adhesion ◽  
Epoxy Nanocomposites ◽  
Amino Functionalization ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

scholarly journals Temperature-Dependent Synergistic Effect of Multi-Walled Carbon Nanotubes and Graphene Nanoplatelets on the Tensile Quasi-Static and Fatigue Properties of Epoxy Nanocomposites

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 84
Author(s):  
Yi-Ming Jen ◽  
Hao-Huai Chang ◽  
Chien-Min Lu ◽  
Shin-Yu Liang
Keyword(s):  
Carbon Nanotubes ◽  
Fatigue Strength ◽  
Synergistic Effect ◽  
Polymer Nanocomposites ◽  
Graphene Nanoplatelets ◽  
Temperature Dependent ◽  
Epoxy Nanocomposites ◽  
Hybrid Fillers ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Even though the characteristics of polymer materials are sensitive to temperature, the mechanical properties of polymer nanocomposites have rarely been studied before, especially for the fatigue behavior of hybrid polymer nanocomposites. Hence, the tensile quasi-static and fatigue tests for the epoxy nanocomposites reinforced with multi-walled carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs) were performed at different temperatures in the study to investigate the temperature-dependent synergistic effect of hybrid nano-fillers on the studied properties. The temperature and the filler ratio were the main variables considered in the experimental program. A synergistic index was employed to quantify and evaluate the synergistic effect of hybrid fillers on the studied properties. Experimental results show that both the monotonic and fatigue strength decrease with increasing temperature significantly. The nanocomposites with a MWCNT (multi-walled CNT): GNP ratio of 9:1 display higher monotonic modulus/strength and fatigue strength than those with other filler ratios. The tensile strengths of the nanocomposite specimens with a MWCNT:GNP ratio of 9:1 are 10.0, 5.5, 12.9, 23.4, and 58.9% higher than those of neat epoxy at −28, 2, 22, 52, and 82 °C, respectively. The endurance limits of the nanocomposites with this specific filler ratio are increased by 7.7, 26.7, 5.6, 30.6, and 42.4% from those of pristine epoxy under the identical temperature conditions, respectively. Furthermore, the synergistic effect for this optimal nanocomposite increases with temperature. The CNTs bridge the adjacent GNPs to constitute the 3-D network of nano-filler and prevent the agglomeration of GNPs, further improve the studied strength. Observing the fracture surfaces reveals that crack deflect effect and the bridging effect of nano-fillers are the main reinforcement mechanisms to improve the studied properties. The pullout of nano-fillers from polymer matrix at high temperatures reduces the monotonic and fatigue strengths. However, high temperature is beneficial to the synergistic effect of hybrid fillers because the nano-fillers dispersed in the softened matrix are easy to align toward the directions favorable to load transfer.

Characterization of Mechanical and Viscoelastic Properties of SC-15 Epoxy Nanocomposites Reinforced With Multi-Walled Carbon Nanotubes, Nanoclay and Binary Nanoparticles

2014 ◽  
Author(s):  
Tanjheel H. Mahdi ◽  
Mohammad E. Islam ◽  
Mahesh V. Hosur ◽  
Alfred Tcherbi-Narteh ◽  
S. Jeelani
Keyword(s):  
Carbon Nanotubes ◽  
Epoxy Resin ◽  
Viscoelastic Properties ◽  
Flexural Modulus ◽  
Epoxy Nanocomposites ◽  
Multiwalled Carbon ◽  
Epoxy Resin System ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Binary Nanoparticles

Mechanical and viscoelastic properties of polymer nanocomposites reinforced with carboxyl functionalized multiwalled carbon nanotubes (COOH-MWCNT), montmorillonite nanoclays (MMT) and MWCNT/MMT binary nanoparticle were investigated. In this study, 0.3 wt. % of COOH-MWCNT, 2 wt. % of MMT and 0.1 wt. % COOH-MWCNT/2 wt. % MMT binary nanoparticles by weight of epoxy were incorporated to modify SC-15 epoxy resin system. The nanocomposites were subjected to flexure test, dynamic mechanical and thermomechanical analyses. Morphological study was conducted with scanning electron microscope. Addition of each of the nanoparticles in epoxy showed significant improvement in mechanical and viscoelastic properties compared to those of control ones. But, best results were obtained for addition of 0.1% MWCNT/2% MMT binary nanoparticles in epoxy. Nanocomposites modified with binary nanoparticles exhibited about 20% increase in storage modulus as well as 25° C increase in glass transition temperature. Flexural modulus for binary nanoparticle modified composites depicted about 30% improvement compared to control ones. Thus, improvement of mechanical and viscoelastic properties was achieved by incorporating binary nanoparticles to epoxy nanocomposites. The increase in properties was attributed to synergistic effect of MWCNTs and nanoclay in chemically interacting with each other and epoxy resin as well as in arresting and delaying the crack growth once initiated.

scholarly journals Functionalised multi-walled carbon nanotubes for epoxy nanocomposites with improved performance

2009 ◽  
Vol 58 (9) ◽  
pp. 1002-1009 ◽  
Author(s):  
Gordon Armstrong ◽  
Manuel Ruether ◽  
Fiona Blighe ◽  
Werner Blau
Keyword(s):  
Carbon Nanotubes ◽  
Epoxy Nanocomposites ◽  
Multi Walled Carbon Nanotubes ◽  
Improved Performance ◽  
Walled Carbon Nanotubes

Studies on preparation and properties of the multi-walled carbon nanotubes (MWNTs)/epoxy nanocomposites

2011 ◽  
Vol 528 (18) ◽  
pp. 5759-5763 ◽  
Author(s):  
Huayang Deng ◽  
Qi Cao ◽  
Xianyou Wang ◽  
Quanqi Chen ◽  
Hao Kuang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Epoxy Nanocomposites ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Static and Fatigue Strengths of Carbon Nanotube/Epoxy Composites under Hygrothermal Environments

2013 ◽  
Vol 284-287 ◽  
pp. 204-210
Author(s):  
Yi Ming Jen ◽  
Chien Yang Huang
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Stress Concentration ◽  
Interfacial Adhesion ◽  
Epoxy Composites ◽  
Hygrothermal Effect ◽  
Multi Walled Carbon Nanotubes ◽  
Hygrothermal Environments ◽  
Stress Concentration Effect ◽  
Walled Carbon Nanotubes

This study experimentally analyzed the hygrothermal effect on the static and fatigue strengths of acid-treated multi-walled carbon nanotubes (CNTs)/epoxy composites. The nanocomposite specimens with various CNT contents (0., 0.5, and 1.0 wt.%) were statically and fatigue-tested under three different hygrothermal conditions (25 °C/60% RH, 25° C/85% RH, and 40 °C/85% RH) to investigate the influences of hygrothermal conditions and CNT contents on the tensile static and fatigue strengths of the studied nanocomposites. The results show that the static and fatigue strengths decreased slightly at 25 °C/85% RH environments compared with those tested under the 25 °C/60% RH condition. However, the static and fatigue strengths of the studied nanocomposites decreased substantially under the 40 °C/85% RH condition. The combined temperature and humidity environments weaken the interfacial adhesion between the CNT surfaces and the epoxy matrix. Moreover, the experimental results show that the addition of 0.5 wt.% of carbon nanotubes improved the static and fatigue strengths considerably under the same hygrothermal environments. However, when an excessive amount of CNTs was used (1.0 wt.%), the nanocomposite exhibited the lowest strengths compared with the specimens with 0 and 0.5 wt.% CNTs. The stress concentration effect caused by the CNT aggregates was detrimental to the static and fatigue strengths of the studied nanocomposites.

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