scholarly journals Temperature-Dependent Synergistic Effect of Multi-Walled Carbon Nanotubes and Graphene Nanoplatelets on the Tensile Quasi-Static and Fatigue Properties of Epoxy Nanocomposites

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 84
Author(s):  
Yi-Ming Jen ◽  
Hao-Huai Chang ◽  
Chien-Min Lu ◽  
Shin-Yu Liang
Keyword(s):  
Carbon Nanotubes ◽  
Fatigue Strength ◽  
Synergistic Effect ◽  
Polymer Nanocomposites ◽  
Graphene Nanoplatelets ◽  
Temperature Dependent ◽  
Epoxy Nanocomposites ◽  
Hybrid Fillers ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Even though the characteristics of polymer materials are sensitive to temperature, the mechanical properties of polymer nanocomposites have rarely been studied before, especially for the fatigue behavior of hybrid polymer nanocomposites. Hence, the tensile quasi-static and fatigue tests for the epoxy nanocomposites reinforced with multi-walled carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs) were performed at different temperatures in the study to investigate the temperature-dependent synergistic effect of hybrid nano-fillers on the studied properties. The temperature and the filler ratio were the main variables considered in the experimental program. A synergistic index was employed to quantify and evaluate the synergistic effect of hybrid fillers on the studied properties. Experimental results show that both the monotonic and fatigue strength decrease with increasing temperature significantly. The nanocomposites with a MWCNT (multi-walled CNT): GNP ratio of 9:1 display higher monotonic modulus/strength and fatigue strength than those with other filler ratios. The tensile strengths of the nanocomposite specimens with a MWCNT:GNP ratio of 9:1 are 10.0, 5.5, 12.9, 23.4, and 58.9% higher than those of neat epoxy at −28, 2, 22, 52, and 82 °C, respectively. The endurance limits of the nanocomposites with this specific filler ratio are increased by 7.7, 26.7, 5.6, 30.6, and 42.4% from those of pristine epoxy under the identical temperature conditions, respectively. Furthermore, the synergistic effect for this optimal nanocomposite increases with temperature. The CNTs bridge the adjacent GNPs to constitute the 3-D network of nano-filler and prevent the agglomeration of GNPs, further improve the studied strength. Observing the fracture surfaces reveals that crack deflect effect and the bridging effect of nano-fillers are the main reinforcement mechanisms to improve the studied properties. The pullout of nano-fillers from polymer matrix at high temperatures reduces the monotonic and fatigue strengths. However, high temperature is beneficial to the synergistic effect of hybrid fillers because the nano-fillers dispersed in the softened matrix are easy to align toward the directions favorable to load transfer.

Enhanced Thermal Conductivity of Nanofluid by Synergistic Effect of Multi-Walled Carbon Nanotubes and Fe2O3 Nanoparticles

2014 ◽  
Vol 548-549 ◽  
pp. 118-123 ◽  
Author(s):  
Li Fei Chen ◽  
Min Cheng ◽  
De Jun Yang ◽  
Lei Yang
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Synergistic Effect ◽  
Interfacial Adhesion ◽  
Conductivity Enhancement ◽  
Hybrid Fillers ◽  
Water Based ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Enhanced Thermal Conductivity

This study investigates the synergistic effect of combining multi-walled carbon nanotubes (MWNTs) and Fe2O3nanoparticles on thermal conductivity of nanofluid. Results show that low percentage hybrid fillers loading improve thermal conductivity of water based nanofluid, due to the good dispersion and interfacial adhesion, which is confirmed by scanning electron microscope. Furthermore, the hybrid fillers provide synergistic effect on heat conductive networks. The thermal conductivity enhancement of water based nanofluid containing 0.05 wt % MWNTs and 0.02 wt % Fe2O3nanoparticles is 27.75%, which is higher than that of nanofluid containing 0.2 wt % single MWNTs or Fe2O3nanoparticles.

Wear behavior of silica and alumina-based nanocomposites reinforced with multi walled carbon nanotubes and graphene nanoplatelets

Wear ◽  
2019 ◽  
Vol 418-419 ◽  
pp. 290-304 ◽  
Author(s):  
Nidhi Sharma ◽  
Syed Nasimul Alam ◽  
Bankim Chandra Ray ◽  
Surekha Yadav ◽  
Krishanu Biswas
Keyword(s):  
Carbon Nanotubes ◽  
Wear Behavior ◽  
Graphene Nanoplatelets ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Characterization of Mechanical and Viscoelastic Properties of SC-15 Epoxy Nanocomposites Reinforced With Multi-Walled Carbon Nanotubes, Nanoclay and Binary Nanoparticles

2014 ◽  
Author(s):  
Tanjheel H. Mahdi ◽  
Mohammad E. Islam ◽  
Mahesh V. Hosur ◽  
Alfred Tcherbi-Narteh ◽  
S. Jeelani
Keyword(s):  
Carbon Nanotubes ◽  
Epoxy Resin ◽  
Viscoelastic Properties ◽  
Flexural Modulus ◽  
Epoxy Nanocomposites ◽  
Multiwalled Carbon ◽  
Epoxy Resin System ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Binary Nanoparticles

Mechanical and viscoelastic properties of polymer nanocomposites reinforced with carboxyl functionalized multiwalled carbon nanotubes (COOH-MWCNT), montmorillonite nanoclays (MMT) and MWCNT/MMT binary nanoparticle were investigated. In this study, 0.3 wt. % of COOH-MWCNT, 2 wt. % of MMT and 0.1 wt. % COOH-MWCNT/2 wt. % MMT binary nanoparticles by weight of epoxy were incorporated to modify SC-15 epoxy resin system. The nanocomposites were subjected to flexure test, dynamic mechanical and thermomechanical analyses. Morphological study was conducted with scanning electron microscope. Addition of each of the nanoparticles in epoxy showed significant improvement in mechanical and viscoelastic properties compared to those of control ones. But, best results were obtained for addition of 0.1% MWCNT/2% MMT binary nanoparticles in epoxy. Nanocomposites modified with binary nanoparticles exhibited about 20% increase in storage modulus as well as 25° C increase in glass transition temperature. Flexural modulus for binary nanoparticle modified composites depicted about 30% improvement compared to control ones. Thus, improvement of mechanical and viscoelastic properties was achieved by incorporating binary nanoparticles to epoxy nanocomposites. The increase in properties was attributed to synergistic effect of MWCNTs and nanoclay in chemically interacting with each other and epoxy resin as well as in arresting and delaying the crack growth once initiated.

Sign in / Sign up

Export Citation Format

Share Document