Hierarchical assembly of the siliceous skeletal lattice of the hexactinellid sponge Euplectella aspergillum

2007 ◽  
Vol 158 (1) ◽  
pp. 93-106 ◽  
Author(s):  
James C. Weaver ◽  
Joanna Aizenberg ◽  
Georg E. Fantner ◽  
David Kisailus ◽  
Alexander Woesz ◽  
...  
Keyword(s):  
Hierarchical Assembly ◽  
Hexactinellid Sponge

Supramolecular Assembly of U(IV) Clusters and Superatoms

2020 ◽  
Author(s):  
Ian Colliard ◽  
Gregory Morrosin ◽  
Hans-Conrad zur Loye ◽  
May Nyman
Keyword(s):  
Quantum Dots ◽  
Supramolecular Assembly ◽  
Emergent Properties ◽  
Organic Media ◽  
Body Centered Cubic ◽  
Cluster Anions ◽  
Charge Balance ◽  
Interpenetrating Networks ◽  
Hierarchical Assembly ◽  
Two Parameters

Superatoms are nanometer-sized molecules or particles that can form ordered lattices, mimicking their atomic counterparts. Hierarchical assembly of superatoms gives rise to emergent properties in superlattices of quantum-dots, p-block clusters, and fullerenes. Here, we introduce a family of uranium-oxysulfate cluster anions whose hierarchical assembly in water is controlled by two parameters; acidity and the countercation. In acid, larger Ln<sup>III</sup> (Ln=La-Ho) link hexamer (U<sub>6</sub>) oxoclusters into body-centered cubic frameworks, while smaller Ln<sup>III</sup> (Ln=Er-Lu &Y) promote linking of fourteen U<sub>6</sub>-clusters into hollow superclusters (U<sub>84</sub> superatoms). U<sub>84</sub> assembles into superlattices including cubic-closest packed, body-centered cubic, and interpenetrating networks, bridged by interstitial countercations, and U<sub>6</sub>-clusters. Divalent transition metals (TM=Mn<sup>II </sup>and Zn<sup>II</sup>), with no added acid, charge-balance and promote the fusion of 10 U<sub>6</sub> and 10 U-monomers into a wheel–shaped cluster (U<sub>70</sub>). Dissolution of U<sub>70</sub> in organic media reveals (by small-angle Xray scattering) that differing supramolecular assemblies are accessed, controlled by TM-linking of U<sub>70</sub>-clusters. <br>

scholarly journals From helices to superhelices: hierarchical assembly of homochiral van der Waals 1D coordination polymers

2021 ◽  
Vol 12 (38) ◽  
pp. 12619-12630
Author(s):  
Guo-Guo Weng ◽  
Ben-Kun Hong ◽  
Song-Song Bao ◽  
Yujie Wen ◽  
Lan-Qing Wu ◽  
...  
Keyword(s):  
Growth Mechanism ◽  
Coordination Polymers ◽  
Van Der Waals ◽  
Hierarchical Assembly ◽  
New Type

Superhelices of terbium phosphonates formed following a new type of “chain-twist-growth” mechanism involving flexible cyclohexyl groups.

Oleylamine Impurities Regulate Temperature-Dependent Hierarchical Assembly of Ultranarrow Gold Nanowires on Biotemplated Interfaces

ACS Nano ◽  
2021 ◽  
Author(s):  
Erin N. Lang ◽  
Ashlin G. Porter ◽  
Tianhong Ouyang ◽  
Anni Shi ◽  
Tyler R. Hayes ◽  
...  
Keyword(s):  
Gold Nanowires ◽  
Temperature Dependent ◽  
Hierarchical Assembly

Hierarchical Assembly of Viral Nanotemplates with Encoded Microparticles via Nucleic Acid Hybridization

Langmuir ◽  
2008 ◽  
Vol 24 (21) ◽  
pp. 12483-12488 ◽  
Author(s):  
Wui Siew Tan ◽  
Christina L. Lewis ◽  
Nicholas E. Horelik ◽  
Daniel C. Pregibon ◽  
Patrick S. Doyle ◽  
...  
Keyword(s):  
Nucleic Acid ◽  
Nucleic Acid Hybridization ◽  
Hierarchical Assembly

Compact Magneto‐Fluorescent Colloids by Hierarchical Assembly of Dual‐Components in Radial Channels for Sensitive Point‐of‐Care Immunoassay

Small ◽  
2021 ◽  
pp. 2100862
Author(s):  
Liang Huang ◽  
Yuxing Zhang ◽  
Tao Liao ◽  
Kui Xu ◽  
Chenxing Jiang ◽  
...  
Keyword(s):  
Point Of Care ◽  
Hierarchical Assembly

scholarly journals Dimerization and oligomerization of DNA-assembled building blocks for controlled multi-motion in high-order architectures

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Ling Xin ◽  
Xiaoyang Duan ◽  
Na Liu
Keyword(s):  
Building Block ◽  
Degrees Of Freedom ◽  
Building Blocks ◽  
Single Type ◽  
Hierarchical Assembly ◽  
Optical Responses ◽  
Self Association ◽  
Living Organisms ◽  
Order Structures ◽  
Chiral System

AbstractIn living organisms, proteins are organized prevalently through a self-association mechanism to form dimers and oligomers, which often confer new functions at the intermolecular interfaces. Despite the progress on DNA-assembled artificial systems, endeavors have been largely paid to achieve monomeric nanostructures that mimic motor proteins for a single type of motion. Here, we demonstrate a DNA-assembled building block with rotary and walking modules, which can introduce new motion through dimerization and oligomerization. The building block is a chiral system, comprising two interacting gold nanorods to perform rotation and walking, respectively. Through dimerization, two building blocks can form a dimer to yield coordinated sliding. Further oligomerization leads to higher-order structures, containing alternating rotation and sliding dimer interfaces to impose structural twisting. Our hierarchical assembly scheme offers a design blueprint to construct DNA-assembled advanced architectures with high degrees of freedom to tailor the optical responses and regulate multi-motion on the nanoscale.

Green Fluorescent Tripeptide Nanostructures: Synergetic Effects of Oxidation and Hierarchical Assembly

2021 ◽  
pp. 825-830
Author(s):  
Jun Guo ◽  
Xiaofang Li ◽  
Jiaqi Lian ◽  
Feng Gao ◽  
Ruoyang Zhao ◽  
...  
Keyword(s):  
Hierarchical Assembly ◽  
Synergetic Effects ◽  
Green Fluorescent

DNA-based self-assembly of nanostructures

2017 ◽  
Author(s):  
Joshua D. Carter ◽  
Chenxiang Lin ◽  
Yan Liu ◽  
Hao Yan ◽  
Thomas H. LaBean
Keyword(s):  
Self Assembly ◽  
Materials Science ◽  
Directed Assembly ◽  
Building Blocks ◽  
Hierarchical Assembly ◽  
Synthetic Dna ◽  
Nanoscale Manufacturing ◽  
Covalently Linked ◽  
Design Construction ◽  
Proteins And Peptides

This article examines the DNA-based self-assembly of nanostructures. It first reviews the development of DNA self-assembly and DNA-directed assembly, focusing on the main strategies and building blocks available in the modern molecular construction toolbox, including the design, construction, and analysis of nanostructures composed entirely of synthetic DNA, as well as origami nanostructures formed from a mixture of synthetic and biological DNA. In particular, it considers the stepwise covalent synthesis of DNA nanomaterials, unmediated assembly of DNA nanomaterials, hierarchical assembly, nucleated assembly, and algorithmic assembly. It then discusses DNA-directed assembly of heteromaterials such as proteins and peptides, gold nanoparticles, and multicomponent nanostructures. It also describes the use of complementary DNA cohesion as 'smart glue' for bringing together covalently linked functional groups, biomolecules, and nanomaterials. Finally, it evaluates the potential future of DNA-based self-assembly for nanoscale manufacturing for applications in medicine, electronics, photonics, and materials science.

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