scholarly journals The absorption spectrum of water vapor in the 2.2 μm transparency window: High sensitivity measurements and spectroscopic database

Author(s):  
A. Campargue ◽  
S.N. Mikhailenko ◽  
S. Vasilchenko ◽  
C. Reynaud ◽  
S. Béguier ◽  
...  
Author(s):  
S. Vasilchenko ◽  
M. Konefal ◽  
D. Mondelain ◽  
S. Kassi ◽  
P. Čermák ◽  
...  

2011 ◽  
Vol 128-129 ◽  
pp. 607-610
Author(s):  
Min Wang ◽  
Jie Chen ◽  
Niu Liu ◽  
Ya Wang

Mid-infrared lasers are very suitable for high-sensitive trace-gases detection for their wavelengths cover the fundamental absorption lines of most gases. Quantum-cascade (QC) lasers have been demonstrated to be ideal light sources with its special power, tuning and capability of operating in room-temperature. All these merits make it appropriate for the high resolution spectrum analysis. The absorption spectrum monitoring technology based on the QC laser pulsed operating in the room temperature, combining with the strong absorption of the gas molecule in the basic frequency, has become an effective way to monitor the trace gas with the characteristic of high sensitivity, good selectivity and fast response. In this paper, the inter-pulse spectroscopy based on a room-temperature distributed-feedback pulsed QC laser was introduced. Our approach to trace gas monitoring with QC lasers relies on short current pulses which are designed to produce even shorter light pulses. Each pulse corresponds to a single point in a spectrum. The N2O absorption spectrum centered at 2178.2cm-1was also obtained.


2013 ◽  
Vol 6 (5) ◽  
pp. 9263-9295
Author(s):  
P. Boylan ◽  
D. Helmig ◽  
J.-H. Park

Abstract. Laboratory experiments were conducted to investigate the effects of water vapor on the reaction of nitric oxide with ozone in a chemiluminescence instrument used for fast response and high sensitivity detection of atmospheric ozone. Water vapor was introduced into a constant level ozone standard and both ozone and water vapor signals were recorded at 10 Hz. The presence of water vapor was found to reduce, i.e. quench the ozone signal. A correction factor was determined to be 4.15 ± 0.14 × 10−3, which corresponds to a 4.15% increase in the measured ozone signal per 10 mmol mol−1 co-sampled water vapor. An ozone-inert water vapor permeable membrane (Nafion dryer) was installed in the sampling line and was shown to remove the bulk of the water vapor mole fraction in the sample air. At water vapor mole fractions above 25 mmol mol−1, the Nafion dryer removed over 75% of the water vapor in the sample. This reduced the ozone signal correction from over 11% to less than 2.5%. The Nafion dryer was highly effective at reducing the fast fluctuations of the water vapor signal (more than 97%) while leaving the ozone signal unaffected, which is a crucial improvement for minimizing the interference of water vapor fluxes on the ozone flux determination by the eddy covariance technique.


2020 ◽  
Vol 154 ◽  
pp. 112704 ◽  
Author(s):  
Somia Yassin Hussain Abdalkarim ◽  
Yanyan Wang ◽  
Hou-Yong Yu ◽  
Zhaofeng Ouyang ◽  
Rabie A.M. Asad ◽  
...  

Author(s):  
A. Campargue ◽  
E.V. Karlovets ◽  
E. Starikova ◽  
A. Sidorenko ◽  
D. Mondelain

2003 ◽  
Vol 57 (3) ◽  
pp. 317-322 ◽  
Author(s):  
Yukiteru Katsumoto ◽  
Yukihiro Ozaki

Quantitative data analysis and high-sensitivity measurements by use of Raman and infrared spectroscopy often suffer from noisy spikes such as those due to cosmic rays and water vapor. Since these spikes are unidirectional and isolated, the conventional smoothing techniques do a poor job of removing them. However, a small modification can improve these smoothing techniques significantly. In this paper, we present a simple denoising technique for a single-scan spectrum that is corrupted by convex spikes. In general, the noisy spikes arising from cosmic rays or water vapor have a much narrower bandwidth compared with target “informative” bands in Raman and infrared spectra. This means that these noisy spikes can be separated from the target bands by means of the difference in the bandwidths. The proposed method employs the moving window averaging procedure to distinguish and separate the convex spike. The proposed algorithm allows us to take away the convex spikes from measured spectra without preparing multiply recorded spectra and (much) biasing the measured spectrum.


2015 ◽  
Vol 6 (20) ◽  
pp. 4148-4152 ◽  
Author(s):  
Benjamin Demirdjian ◽  
Frederic Bedu ◽  
Alain Ranguis ◽  
Igor Ozerov ◽  
Artak Karapetyan ◽  
...  
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