Rapid formation of iron sulfides alters soil morphology and chemistry following simulated marsh restoration

Geoderma ◽  
2019 ◽  
Vol 351 ◽  
pp. 76-84 ◽  
Author(s):  
Jacob F. Berkowitz ◽  
Christine M. VanZomeren ◽  
Nicole D. Fresard
Keyword(s):  
Soil Morphology ◽  
Iron Sulfides ◽  
Marsh Restoration ◽  
Rapid Formation

scholarly journals Rapid formation of iron sulfides alters soil morphology and chemistry following simulated marsh restoration

2021 ◽  
Author(s):  
Jacob Berkowitz ◽  
Christine VanZomeren ◽  
Nicole Fresard
Keyword(s):  
Iron Sulfide ◽  
Chemical Constituents ◽  
Soil Morphology ◽  
Case Scenario ◽  
Salt Marsh Restoration ◽  
Marsh Soil ◽  
Worst Case ◽  
Marsh Restoration ◽  
In Situ Conditions ◽  
Rapid Formation

Many marshes show signs of degradation due to fragmentation, lack of sediment inputs, and erosion which may be exacerbated by sea level rise and increasing storm frequency/intensity. As a result, resource managers seek to restore marshes via introduction of sediment to increase elevation and stabilize the marsh platform. Recent field observations suggest the rapid formation of iron sulfide (FeS) materials following restoration in several marshes. To investigate, a laboratory microcosm study evaluated the formation of FeS following simulated restoration activities under continually inundated, simulated drought, and simulated tidal conditions. Results indicate that FeS horizon development initiated within 16 days, expanding to encompass > 30% of the soil profile after 120 days under continuously inundated and simulated tidal conditions. Continuously inundated conditions supported higher FeS content compared to other treatments. Dissolved and total Fe and S measurements suggest the movement and diffusion of chemical constituents from native marsh soil upwards into the overlying sediments, driving FeS precipitation. The study highlights the need to consider biogeochemical factors resulting in FeS formation during salt marsh restoration activities. Additional field research is required to link laboratory studies, which may represent a worst-case scenario, with in-situ conditions.

Stabilizing pyritic material

1989 ◽  
Vol 4 ◽  
pp. 244-248 ◽  
Author(s):  
Donald L. Wolberg
Keyword(s):  
Significant Contribution ◽  
Organic Materials ◽  
Sedimentary Rocks ◽  
Iron Sulfides ◽  
Decomposition Products ◽  
Iron Minerals ◽  
Pyrite Formation ◽  
Organic Sediments ◽  
Freshwater Environments

The minerals pyrite and marcasite (broadly termed pyritic minerals) are iron sulfides that are common if not ubiquitous in sedimentary rocks, especially in association with organic materials (Berner, 1970). In most marine sedimentary associations, pyrite and marcasite are associated with organic sediments rich in dissolved sulfate and iron minerals. Because of the rapid consumption of sulfate in freshwater environments, however, pyrite formation is more restricted in nonmarine sediments (Berner, 1983). The origin of the sulfur in nonmarine environments must lie within pre-existing rocks or volcanic detritus; a relatively small, but significant contribution may derive from plant and animal decomposition products.

scholarly journals Ripple Formation during Oblique Angle Etching

Coatings ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 272
Author(s):  
Mehmet F. Cansizoglu ◽  
Mesut Yurukcu ◽  
Tansel Karabacak
Keyword(s):  
Plasma Etching ◽  
Incidence Angle ◽  
Incident Beam ◽  
Root Mean Square Roughness ◽  
Sticking Coefficient ◽  
Oblique Angle ◽  
Nano Fabrication ◽  
Ripple Formation ◽  
Rapid Formation ◽  
Roughness Analysis

Chemical removal of materials from the surface is a fundamental step in micro- and nano-fabrication processes. In conventional plasma etching, etchant molecules are non-directional and perform a uniform etching over the surface. However, using a highly directional obliquely incident beam of etching agent, it can be possible to engineer surfaces in the micro- or nano- scales. Surfaces can be patterned with periodic morphologies like ripples and mounds by controlling parameters including the incidence angle with the surface and sticking coefficient of etching particles. In this study, the dynamic evolution of a rippled morphology has been investigated during oblique angle etching (OAE) using Monte Carlo simulations. Fourier space and roughness analysis were performed on the resulting simulated surfaces. The ripple formation was observed to originate from re-emission and shadowing effects during OAE. Our results show that the ripple wavelength and root-mean-square roughness evolved at a more stable rate with accompanying quasi-periodic ripple formation at higher etching angles (θ > 60°) and at sticking coefficient values (Sc) 0.5 ≤ Sc ≤ 1. On the other hand, smaller etching angle (θ < 60°) and lower sticking coefficient values lead to a rapid formation of wider and deeper ripples. This result of this study can be helpful to develop new surface patterning techniques by etching.

SOIL MORPHOLOGY AND SOIL PHYSICAL PROPERTIES. I. SOIL AERATION

1972 ◽  
Vol 52 (3) ◽  
pp. 311-321 ◽  
Author(s):  
K. W. AYRES ◽  
R. G. BUTTON ◽  
E. DE JONG
Keyword(s):  
Soil Structure ◽  
Regression Coefficient ◽  
The Other ◽  
Soil Morphology ◽  
Soil Horizons ◽  
Undisturbed Soil ◽  
Soil Aeration ◽  
Structural Types ◽  
Highly Correlated ◽  
Undisturbed Soil Cores

The relation between soil structure and soil aeration was investigated on undisturbed soil cores from soil horizons exhibiting six distinct kinds of soil structure (prismatic, columnar, blocky, granular, platy, massive) over a broad range of soil texture. Soil aeration was characterized at ⅓ atm suction by measurements of air porosity, relative diffusivity (D/Do) and the rate of oxygen diffusion to a platinum microelectrode (ODR). Aeration was adequate in most of the Chernozemic soil horizons studied; however, aeration in many of the Bnt horizons of the Solonetzic soils was inadequate. Air porosity and D/Do were highly correlated. The regression coefficient for D/Do vs. air porosity for blocky structures was significantly different from that found for the other five structural types. For granular structures a negative correlation was found for ODR vs. air porosity compared with a low positive correlation found for the other structure types.

scholarly journals Morphology and Physicochemical Properties of Alluvial Soils in Riparian Forests after River Regulation

Forests ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 329
Author(s):  
Dorota Kawalko ◽  
Paweł Jezierski ◽  
Cezary Kabala
Keyword(s):  
Large Scale ◽  
Soil Classification ◽  
River Regulation ◽  
Riparian Forests ◽  
Deep Penetration ◽  
Alluvial Soils ◽  
Soil Morphology ◽  
Groundwater Supply ◽  
Quantitative Alteration ◽  
Favorable Conditions

The elimination of flooding and lowering of the groundwater table after large-scale river regulation allow deep penetration of soils by plant roots, soil fauna, and microorganisms, thus creating favorable conditions for advanced pedogenesis. Although the changes of the morphology and properties of agriculturally used drained alluvial soils in Central Europe have been well characterized, studies in riparian forests remain insufficient. An analysis of 21 profiles of forest soils located on the Holocene river terrace (a floodplain before river regulation and embankment) in SW Poland confirmed a noticeable pedogenic transformation of soil morphology and properties resulting from river regulation. Gleyic properties were in most profiles replaced with stagnic properties, testifying to a transition from dominant groundwater supply to precipitation-water supply. The development of a diagnostic mollic and cambic horizons, correlated with the shift in soil classification from Fluvisols to Phaeozems, and in the majority, to Cambisols, demonstrated a substantial change in habitat conditions. The transformation of alluvial soils may result in an inevitable modification of forest management in the river valley, including quantitative alteration in species composition of primarily riparian forests.

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