Enthalpy of vaporization, its temperature dependence and correlation with surface tension: A theoretical approach

2017 ◽  
Vol 432 ◽  
pp. 62-69 ◽  
Author(s):  
Amin Alibakhshi
2020 ◽  
Vol 42 (2) ◽  
Author(s):  
Thomas Leitner ◽  
Anna Werkovits ◽  
Siegfried Kleber ◽  
Gernot Pottlacher

AbstractW360 is a hot work tool steel produced by voestalpine BÖHLER Edelstahl GmbH & Co KG, a special steel producer located in Styria, Austria. Surface tension and density of liquid W360 were studied as a function of temperature in a non-contact, containerless fashion using the oscillating drop method inside an electromagnetic levitation setup. For both, surface tension and density, a linear model was adapted to present the temperature dependence of these measures, including values for the uncertainties of the fit parameters found. The data obtained are compared to pure iron (with 91 wt% the main component of W360), showing an overlap for the liquid density while there is a significant difference in surface tension (− 5.8 % at the melting temperature of pure iron of 1811 K).


1997 ◽  
Vol 11 (13) ◽  
pp. 585-592
Author(s):  
S. P. Kruchinin ◽  
A. M. Yaremko ◽  
E. V. Mozdor

The new theoretical approach is proposed for study the states responsible for superconductivity of crystals. Within the frameworks of worked out approach it is shown that in electron–phonon system a class of new so-called coupled states arises. Postulated in BCS method electron-pair states k1 + k2 = 0, s + s′ = 0 are in natural manner included in this class. The model numerical calculations have shown that SC gap depends on number of bands crossing the Fermi level on the momenta k1+k2 = K≠ 0 of interacting electrons and that the temperature dependence of SC gap for HTSC is more complicated (in agreement with the recent experimental data) then predicted in BCS approach.


Author(s):  
Qian Su ◽  
Guang Xu Yu ◽  
Hua Sheng Wang ◽  
John W. Rose

In recent years several correlations have been proposed for calculating the heat-transfer coefficient during condensation in circular and non-circular channels of typical dimension around 1 mm where surface tension effects are important and correlations for larger diameter channels are inappropriate. A wholly theoretical approach applicable to annular flow has also been proposed. The correlations are all based on data for R134a, while the theory is applicable to any fluid. In this paper comparisons are made between the correlations for R134a and ammonia; plots based on theory are also included. Fair agreement is seen between all calculation methods for R134a but wide differences are seen for ammonia indicating that the correlations, based only on one fluid, do not capture the fluid property dependence accurately.


2020 ◽  
Vol 992 ◽  
pp. 545-550
Author(s):  
Vladimir V. Vyukhin ◽  
O.A. Chikova ◽  
Ksenya Yu. Shmakova

Fe-Cu alloys are used as structural materials for manufacture of large machine parts subjected to shock loads. Fe-Cu alloys have a higher corrosion resistance in a humid atmosphere and in salt solutions than cast steel. Fe-Cu alloys have high enough damping characteristics. Upon cooling the Fe-Cu melts is stratified into two phases before crystallization which in field of gravity are separated by density. It is possible to suppress delamination and obtain a material with structure of a “frozen emulsion” by heating melt to the temperature T* determined for each composition by a specific way. In this paper, we studied surface tension of liquid alloys of Fe-1wt.% Cu, Fe-20wt.% Cu, and Fe-30wt.%Cu in order to determine the temperature T*. For the melt of Fe-20wt.% Cu value T*=1670°C is highest. It is confirmed by results of measuring temperature dependence of surface tension. Temperature dependence of the surface tension Fe-Cu melts is characterized by a positive value of the temperature coefficient of surface tension dσ/dT which is abnormal for metal melts. Experimental data on the density, the surface tension of Fe-Cu liquid alloys have of independent metrological importance for practical foundry.


2006 ◽  
Vol 250 (1-2) ◽  
pp. 125-130 ◽  
Author(s):  
Aliaksei A. Strechan ◽  
Gennady J. Kabo ◽  
Yauheni U. Paulechka

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