Experimental determination and correlation of tie line data for the system (water+butyric acid+methylcyclohexane) at four temperatures

2012 ◽  
Vol 332 ◽  
pp. 151-158 ◽  
Author(s):  
H. Ghanadzadeh ◽  
A. Ghanadzadeh ◽  
M. Janbaz ◽  
S. Shekarsaraee
2014 ◽  
Vol 361 ◽  
pp. 45-53 ◽  
Author(s):  
A. Ghanadzadeh Gilani ◽  
H. Ghanadzadeh Gilani ◽  
S.L. Seyed Saadat

2017 ◽  
Vol 91 (11) ◽  
pp. 2078-2084 ◽  
Author(s):  
Sina Shekarsaraee ◽  
Hossein Taherpour Nahzomi ◽  
Elham Nasiri-Touli

2012 ◽  
Vol 29 (11) ◽  
pp. 1615-1621 ◽  
Author(s):  
Hossein Ghanadzadeh ◽  
Sara Asgharzadeh ◽  
Nastran Dastmoozeh ◽  
Sina Shekarsaraee

1992 ◽  
Vol 70 (8) ◽  
pp. 2310-2313 ◽  
Author(s):  
Horacio N. Sólimo ◽  
José L. Zurita

To evaluate the influence of temperature on the extraction of ethanol from aqueous solutions with 1,2-dichloroethane, liquid–liquid equilibrium data for the system water + ethanol + 1,2-dichloroethane were obtained at 298.15, 308.15, and 318.15 K. The binodal curves were determined by the cloud-point method, and conjugate points on the tie-lines were obtained by correlating the refractive index of these curves as a function of composition. The tie-line data at each temperature were satisfactorily correlated using the method of Othmer and Tobias, and the plait-point coordinates were estimated. The experimental data were also compared to values calculated by the UNIFAC group contribution method for the activity coefficients using the isoactivity conditions as restraint equations, and with the NRTL and UNIQUAC models. The UNIFAC method proved to be more accurate than the NRTL and UNIQUAC equations fitted to the experimental data. Under the experimental conditions used, ethanol extraction by 1,2-dichloroethane appears to be independent of the temperature.


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