Prediction of the surface tension, surface concentration, and the relative Gibbs adsorption isotherm of binary liquid systems

2006 ◽  
Vol 246 (1-2) ◽  
pp. 119-130 ◽  
Author(s):  
Luis Felipe Ramírez-Verduzco ◽  
Ascención Romero-Martínez ◽  
Arturo Trejo
2013 ◽  
Vol 2013 ◽  
pp. 1-13 ◽  
Author(s):  
R. Ahluwalia ◽  
Ritu Gupta ◽  
J. L. Vashisht ◽  
R. K. Wanchoo

The density (), viscosity (), and surface tension () of binary mixtures of carboxylic acids (CAs) (ethanoic acid (EA), propanoic acid (PA), butanoic acid (BA)) + benzene (BEN) or acetophenone (ACT) have been measured at 298.15, 308.15, and 318.15 K. From the experimental results, excess values of molar volume (), viscosity (), Gibb's free energy for the activation of low (), and surface tension () were evaluated and fitted to a Redlich-Kister type of equation. The parameter “” of Grunberg and Nissan expression has also been calculated. From the sign and magnitude of , , , , and “” values, it is concluded that specific interactions are present in CA+ACT system and these interactions are absent in CA + BEN mixtures. Various viscosity and surface tension models have been used to test the consistency of the data.


1970 ◽  
Vol 48 (24) ◽  
pp. 3773-3781 ◽  
Author(s):  
V. T. Lam ◽  
G. C. Benson

Surface tensions were measured for the ten binary liquid systems: cyclopentane + carbon tetrachloride, cyclopentane + tetrachloroethylene, cyclopentane + benzene, cyclopentane + toluene, cyclohexane + tetrachloroethylene, cyclohexane + benzene, cyclohexane + toluene, cyclohexane + cis-decalin, cyclohexane + trans-decalin, and benzene + o-xylene. The system cyclohexane + benzene was studied at 20 and 30 °C. Measurements for the other nine systems were carried out at 25 °C. The principle of corresponding states was used to correlate the surface tension results with other properties of the pure component liquids and of their binary mixtures.


Author(s):  
I. Cibulka ◽  
J.-C. Fontaine ◽  
K. Sosnkowska-Kehiaian ◽  
H. V. Kehiaian
Keyword(s):  

1978 ◽  
Vol 56 (3) ◽  
pp. 507-510 ◽  
Author(s):  
Anil Kumar ◽  
M.K. Tiwari ◽  
E.S.R. Gopal
Keyword(s):  

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