Three-Dimensional Porous Nitrogen doped Graphene Hydrogel for High Energy Density supercapacitors

2016 ◽  
Vol 213 ◽  
pp. 291-297 ◽  
Author(s):  
Dan Liu ◽  
Chaopeng Fu ◽  
Ningshuang Zhang ◽  
Haihui Zhou ◽  
Yafei Kuang
2019 ◽  
Vol 7 (34) ◽  
pp. 19909-19921 ◽  
Author(s):  
Ronghua Wang ◽  
Qiannan Zhao ◽  
Weikang Zheng ◽  
Zongling Ren ◽  
Xiaolin Hu ◽  
...  

A 4.5 V “dual carbon” LIC device is constructed based on all nitrogen doped graphene nanostructures. It could achieve an ultrahigh energy density of 187.9 W h kg−1 at a high power density of 2250 W kg−1 due to the alleviating kinetic mismatch.


2017 ◽  
Vol 5 (11) ◽  
pp. 5523-5531 ◽  
Author(s):  
Li Liu ◽  
Lijun Su ◽  
Junwei Lang ◽  
Bin Hu ◽  
Shan Xu ◽  
...  

Supercapacitors using ionic liquids (ILs) as electrolytes have triggered great interest due to their much higher energy density when compared to aqueous supercapacitors.


2019 ◽  
Vol 318 ◽  
pp. 865-874 ◽  
Author(s):  
Yanan Jin ◽  
Yuena Meng ◽  
Wei Fan ◽  
Hengyi Lu ◽  
Tianxi Liu ◽  
...  

2020 ◽  
Vol 302 ◽  
pp. 51-61 ◽  
Author(s):  
Viratchara Laokawee ◽  
Thanapat Autthawong ◽  
Bralee Chayasombat ◽  
Aishui Yu ◽  
Thapanee Sarakonsri

Nowadays, there is an increasing of the demanding in high energy density lithium-ion batteries (LIBs) due to the growing of energy storage needs for electronic vehicles and portable devices. Silicon (Si) and Tin (Sn) are the promising anode materials for LIBs due to their high theoretical capacity of 4200 mAh/g and 994 mAh/g. Moreover, Si can be derived from rice husk which is the main agricultural product in Thailand. However, the using of Si and Sn encounters with the huge volume expansion during lithiation and delithiation process. To alleviate this problem, Nitrogen-doped graphene (NrGO), carbon supporter, is used as composite with these metals to buffer the volume change and increase the electrical conductivity of composites. This work aims to synthesis Si/NrGO and SiSn/NrGO nanocomposites and Si used in these composites is derived from rice husk. All products were characterized by X-rays diffraction (XRD), Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques. XRD results showed that the composites contained phases of Si, Sn and carbon. The electron microscopy techniques were the main part to clarify the morphology and distribution of Si and Sn particles on NrGO. SEM and TEM results confirm that there were small sized particles of Si and Sn dispersed and covered on NrGO surface. Furthermore, the electrochemical properties of prepared composites were measured to confirm their efficiency as anode materials in lithium-ion batteries by coin cell assembly. The composite with 10 percent Si and 10 percent Sn on NrGO could deliver a high capacity around 480 mAh/g over 100 cycles and expected to use as anode materials in the next generation lithium-ion batteries.


Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3121
Author(s):  
Hosna Ghanbarlou ◽  
Nikoline Loklindt Pedersen ◽  
Morten Enggrob Simonsen ◽  
Jens Muff

The synergy between electrochemical oxidation and adsorption on particle electrodes was investigated in three-dimensional (3D) systems for p-nitrosodimethylaniline (RNO) decolorization and pesticide removal. A comparison was made between granular activated carbon (GAC) and a novel synthesized nitrogen-doped graphene-based particle electrode (NCPE). Experiments on RNO decolorization show that the synergy parameter of the 3D-NCPE system was improved 3000 times compared to the studied 3D-GAC system. This was due to the specific nanostructure and composition of the NCPE material. Nitrogen-doped graphene triggered an oxygen reduction reaction, producing hydrogen peroxide that simultaneously catalyzed on iron sites of the NCPEs to hydroxyl radicals following the electro-Fenton (EF) process. Data showed that in the experimental setup used for the study, the applied cell voltage required for the optimal value of the synergy parameter could be lowered to 5V in the 3D-NCPEs process, which is significantly better than the 15–20 V needed for synergy to be found in the 3D-GAC process. Compared to previous studies with 3D-GAC, the removal of pesticides 2,6 dichlorobenzamide (BAM), 2-methyl-4-chlorophenoxyaceticacid (MCPA), and methylchlorophenoxypropionic acid (MCPP) was also enhanced in the 3D-NCPE system.


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