Performance of Polymer Electrolyte Membrane Fuel Cell Single Cells Prepared Using Hierarchical Microporous-Mesoporous Carbon Supported Pt Nanoparticles Activated Catalysts

2016 ◽  
Vol 203 ◽  
pp. 221-229 ◽  
Author(s):  
S. Sepp ◽  
K. Vaarmets ◽  
J. Nerut ◽  
I. Tallo ◽  
E. Tee ◽  
...  
2019 ◽  
Vol 8 (1) ◽  
pp. 493-502
Author(s):  
Yunqi Li ◽  
Danping Xiong ◽  
Yuwei Liu ◽  
Mingtao Liu ◽  
Jinzhang Liu ◽  
...  

AbstractThe catalysts performance degradation is a crucial issue in decay of the polymer electrolyte membrane fuel cell (PEMFC). The effect of Nafion content, dispersity of Pt nanoparticles and selected types of carbon support on the degradation of electrochemical surface area (ECSA) and double layer capacitance (DLC) were experimentally discussed by accelerated stress test (AST). The catalyst with 20wt% Nafion content exhibited better catalyst performance. i.e., the less DLC and ECSA degradation during AST. Catalysts with well Pt dispersity showed superior %ECSA (the percentage change of ECSA) retention. The heat-treated catalysts exhibited the lowest ECSA and DLC degradation rate due to the larger Pt particle and high carbon corrosion resistance. Moreover, a multi-order model describing the correlation between ECSA and DLC degradation was proposed, providing a vital reference for quantitatively investigating ECSA and DLC degradation in the catalysts with different catalysts structural parameters.


Energies ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 4048
Author(s):  
Huu Linh Nguyen ◽  
Jeasu Han ◽  
Xuan Linh Nguyen ◽  
Sangseok Yu ◽  
Young-Mo Goo ◽  
...  

Durability is the most pressing issue preventing the efficient commercialization of polymer electrolyte membrane fuel cell (PEMFC) stationary and transportation applications. A big barrier to overcoming the durability limitations is gaining a better understanding of failure modes for user profiles. In addition, durability test protocols for determining the lifetime of PEMFCs are important factors in the development of the technology. These methods are designed to gather enough data about the cell/stack to understand its efficiency and durability without causing it to fail. They also provide some indication of the cell/stack’s age in terms of changes in performance over time. Based on a study of the literature, the fundamental factors influencing PEMFC long-term durability and the durability test protocols for both PEMFC stationary and transportation applications were discussed and outlined in depth in this review. This brief analysis should provide engineers and researchers with a fast overview as well as a useful toolbox for investigating PEMFC durability issues.


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