Influence of the concentration and the nature of the supporting electrolyte on the electrochemical reduction of nitrate on tin cathode

2007 ◽  
Vol 52 (23) ◽  
pp. 6412-6420 ◽  
Author(s):  
I. Katsounaros ◽  
G. Kyriacou
Keyword(s):  
Electrochemical Reduction ◽  
Supporting Electrolyte

Voltammetry in the absence of excess supporting electrolyte – ECE-DISP1 reactions: The electrochemical reduction of 2-nitrobromobenzene in acetonitrile solvent

2011 ◽  
Vol 659 (1) ◽  
pp. 25-35 ◽  
Author(s):  
Edward O. Barnes ◽  
Yijun Wang ◽  
Juan G. Limon-Petersen ◽  
Stephen R. Belding ◽  
Richard G. Compton
Keyword(s):  
Electrochemical Reduction ◽  
Supporting Electrolyte

scholarly journals Electrochemically modified Corey–Fuchs reaction for the synthesis of arylalkynes. The case of 2-(2,2-dibromovinyl)naphthalene

2018 ◽  
Vol 14 ◽  
pp. 891-899 ◽  
Author(s):  
Fabiana Pandolfi ◽  
Isabella Chiarotto ◽  
Marta Feroci
Keyword(s):  
Electrochemical Reduction ◽  
Supporting Electrolyte ◽  
Cathodic Reduction ◽  
Terminal Alkyne ◽  
High Yields

The electrochemical reduction of 2-(2,2-dibromovinyl)naphthalene in a DMF solution (Pt cathode) yields selectively 2-ethynylnaphthalene or 2-(bromoethynyl)naphthalene in high yields, depending on the electrolysis conditions. In particular, by simply changing the working potential and the supporting electrolyte, the reaction can be directed towards the synthesis of the terminal alkyne (Et4NBF4) or the bromoalkyne (NaClO4). This study allowed to establish that 2-(bromoethynyl)naphthalene can be converted into 2-ethynylnaphthalene by cathodic reduction.

Electrochemically induced chain reactions: the addition of fluorene and indene to aromatic aldehydes initiated by electrochemical reduction

1996 ◽  
Vol 74 (1) ◽  
pp. 55-63 ◽  
Author(s):  
J. C. Gard ◽  
B. Hanquet ◽  
L. Roullier ◽  
Y. Mugnier ◽  
J. Lessard
Keyword(s):  
Electrochemical Reduction ◽  
Supporting Electrolyte ◽  
Aromatic Aldehydes ◽  
Catalytic Amount ◽  
Proton Donor ◽  
Base Catalysis ◽  
Tetrabutylammonium Perchlorate ◽  
Chain Reaction ◽  
Chain Reactions ◽  
Voltammetric Behavior

The electrochemical reduction at −30 °C of 2,6-dichlorobenzaldehyde (1a), benzaldehyde (1b), and terephthalaldehyde (2) in tetrahydrofuran with tetrabutylammonium perchlorate as supporting electrolyte, under an argon atmosphere and in the presence of fluorene or indene, gives carbinols resulting from the addition of fluorene or indene and requires only a catalytic amount of electricity. The chain reaction is initiated by proton abstraction from fluorene or indene by a base electrogenerated by reduction of the aldehyde and the propagation involves the addition of the carbanion to the aldehyde followed by regeneration of the nucleophile by proton transfer from the proton donor to the alkoxide anion (base-catalyzed addition). The voltammetric behavior of the aldehydes in the absence and in the presence of fluorene or indene is also presented. Key words: electrochemical reduction, aromatic aldehydes, addition of fluorene (indene), base catalysis, chain reaction.

In Situ X-Ray Absorption Studies of the Electrochemical Reduction of Hydroxocobalamin

1997 ◽  
Vol 7 (C2) ◽  
pp. C2-619-C2-620 ◽  
Author(s):  
M. Giorgett ◽  
I. Ascone ◽  
M. Berrettoni ◽  
S. Zamponi ◽  
R. Marassi
Keyword(s):  
Electrochemical Reduction ◽  
X Ray ◽  
Absorption Studies ◽  
X Ray Absorption
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