Electrochemical and ATR-FTIR study of dimethyl ether and methanol electro-oxidation on sputtered Pt electrode

2007 ◽  
Vol 52 (19) ◽  
pp. 5781-5788 ◽  
Author(s):  
Yan Liu ◽  
Masashi Muraoka ◽  
Shigenori Mitsushima ◽  
Ken-Ichiro Ota ◽  
Nobuyuki Kamiya
2008 ◽  
Vol 53 (28) ◽  
pp. 8298-8304 ◽  
Author(s):  
Qian Zhang ◽  
Zhongfang Li ◽  
Suwen Wang ◽  
Wei Xing ◽  
Rujun Yu ◽  
...  

2000 ◽  
Vol 147 (11) ◽  
pp. 4058 ◽  
Author(s):  
Jens T. Müller ◽  
Peter M. Urban ◽  
Wolfgang F. Hölderich ◽  
Kevin M. Colbow ◽  
J. Zhang ◽  
...  

2005 ◽  
Vol 7 (5) ◽  
pp. 459-465 ◽  
Author(s):  
M.H. Shao ◽  
J. Warren ◽  
N.S. Marinkovic ◽  
P.W. Faguy ◽  
R.R. Adzic

2012 ◽  
Vol 608-609 ◽  
pp. 894-897
Author(s):  
Hai Tao Wang ◽  
Zhen Jin ◽  
Yu Chun Qin

Three kinds of ions (I-、Fe2+and MnO4-) were appended into the methanol aqueous solution respectively as an additive and the Cyclic voltammograms of the aqueous solutions were studied. The results showed that Fe2+had obvious promotion effect for electro-oxidation of methanol and could improve the methanol anodic oxidation current by 85 percent. The promotion effect of the thulium Ions were related with the electronic distribution of these elements and their adsorption on the Pt electrode surface. I-and MnO4-could facilitate the electro-oxidation of methanol at different extent.


2013 ◽  
Vol 1 (2) ◽  
pp. 448-454 ◽  
Author(s):  
Min Yin ◽  
Yunjie Huang ◽  
Qingfeng Li ◽  
Jens Oluf Jensen ◽  
Lars N. Cleemann ◽  
...  

2007 ◽  
Vol 174 (1) ◽  
pp. 176-179 ◽  
Author(s):  
Tian Tian ◽  
Changpeng Liu ◽  
Jianhui Liao ◽  
Wei Xing ◽  
Tianhong Lu

2014 ◽  
Vol 1044-1045 ◽  
pp. 43-46
Author(s):  
Chiu Wen Chen ◽  
Je Wei Li ◽  
Chang Mao Hung ◽  
Jiann Yuh Lou ◽  
Cheng Di Dong

This study investigated the feasibility of the electrochemical degradation of benzene (C6H6) in a NaCl electrolyte solution between 0.05 and 0.5 M under the temperature of 298 K and reaction concentration between 1.28×10-5 and 1.28×10-3 M with an applied potential of 3 V was conducted in this study to investigate the destruction of the C6H6 in the batch reactors using a Pt/XC-72 composite as a catalyst. Experimental results indicated that the optimal conditions in the reaction were developed as a NaCl solution with 0.1 M at pH of 1.0 under C6H6 concentration of 6.41×10-4 M. The results reveal that electrochemical degradation of C6H6 in acidic medium is highly effective, while a maximum about 41% reduction at 120 min was achieved with Pt/XC-72 composite during the electrochemical degradation. In comparsion, the removal efficiency reached only 29% with the Pt electrode, showing the suitability of the Pt/XC-72 composites for electro-oxidation of C6H6. As a result, XC-72 carbon black materials played an important role in the decomposition of C6H6. Furthermore, the Pt/XC-72 composite used in this research has been developed as a potential catalyst for the application of C6H6 electro-oxidation.


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