Theoretical insights into PF6− and its alkali metal ion pairs: geometries and vibrational frequencies

2005 ◽  
Vol 50 (20) ◽  
pp. 4196-4201 ◽  
Author(s):  
Xiaopeng Xuan ◽  
Jianji Wang ◽  
Hanqing Wang
Keyword(s):  
Alkali Metal ◽  
Metal Ion ◽  
Ion Pairs ◽  
Vibrational Frequencies ◽  
Alkali Metal Ion

Photochemical reactions of fluoro-substituted ketones with amines, tetraphenylborates, and organometals: an electron spin resonance study

1980 ◽  
Vol 58 (6) ◽  
pp. 591-598 ◽  
Author(s):  
Kuang S. Chen ◽  
Terry Foster ◽  
Jeffrey K. S. Wan
Keyword(s):  
Alkali Metal ◽  
Metal Ion ◽  
Ion Pairs ◽  
Photochemical Reactions ◽  
Ammonium Ion ◽  
Electron Spin Resonance Study ◽  
Fluorine Substitution ◽  
Alkali Metal Ion ◽  
Spin Resonance ◽  
Spin Resonance Study

Ammonium ion-pairs, solvent-separated alkali-metal ion-pairs, and Group IVB organometallic adducts of fluoro-substituted ketones were generated photochemically. The structure and the controlling factors for the formation of contact ammonium ion-pair were deduced from the effects of solvent, amine, and fluorine substitution. The effect of fluorine on the formation of the alkali-metal ion-pairs and organometallic adducts was discussed.

Cation migration between two unequivalent sites in 4-cyano pyridine alkali metal ion pairs

1978 ◽  
Vol 31 (1) ◽  
pp. 31-37 ◽  
Author(s):  
Luigi Pasimeni ◽  
Carlo Corvaja ◽  
Caterina Ghio
Keyword(s):  
Alkali Metal ◽  
Metal Ion ◽  
Ion Pairs ◽  
Alkali Metal Ion ◽  
Cation Migration
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