Electron spin resonance study of o-benzosemiquinone alkali metal ion pairs

1975 ◽  
Vol 71 ◽  
pp. 193 ◽  
Author(s):  
Marina Brustolon ◽  
Luigi Pasimeni ◽  
Carlo Corvaja
Keyword(s):  
Electron Spin Resonance ◽  
Alkali Metal ◽  
Electron Spin ◽  
Metal Ion ◽  
Ion Pairs ◽  
Electron Spin Resonance Study ◽  
Alkali Metal Ion ◽  
Spin Resonance ◽  
Spin Resonance Study

Photochemical reactions of fluoro-substituted ketones with amines, tetraphenylborates, and organometals: an electron spin resonance study

1980 ◽  
Vol 58 (6) ◽  
pp. 591-598 ◽  
Author(s):  
Kuang S. Chen ◽  
Terry Foster ◽  
Jeffrey K. S. Wan
Keyword(s):  
Alkali Metal ◽  
Metal Ion ◽  
Ion Pairs ◽  
Photochemical Reactions ◽  
Ammonium Ion ◽  
Electron Spin Resonance Study ◽  
Fluorine Substitution ◽  
Alkali Metal Ion ◽  
Spin Resonance ◽  
Spin Resonance Study

Ammonium ion-pairs, solvent-separated alkali-metal ion-pairs, and Group IVB organometallic adducts of fluoro-substituted ketones were generated photochemically. The structure and the controlling factors for the formation of contact ammonium ion-pair were deduced from the effects of solvent, amine, and fluorine substitution. The effect of fluorine on the formation of the alkali-metal ion-pairs and organometallic adducts was discussed.

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