Theoretical studies on the kinetics and mechanism of multi-channel gas-phase unimolecular reaction of ethyl acetate

2013 ◽  
Vol 1009 ◽  
pp. 43-49 ◽  
Author(s):  
Vahid Saheb ◽  
Sayyed Mohammad Ali Hosseini
Keyword(s):  
Ethyl Acetate ◽  
Gas Phase ◽  
Kinetics And Mechanism ◽  
Theoretical Studies ◽  
Unimolecular Reaction

scholarly journals Theoretical studies on gas-phase kinetics and mechanism of H-abstraction reaction from methanol by ClO and BrO radicals

RSC Advances ◽  
2015 ◽  
Vol 5 (49) ◽  
pp. 39110-39121 ◽  
Author(s):  
Samiyara Begum ◽  
Ranga Subramanian
Keyword(s):  
Gas Phase ◽  
Theoretical Approach ◽  
Kinetics And Mechanism ◽  
Theoretical Studies ◽  
Gas Phase Kinetics ◽  
Abstraction Reaction

The gas-phase kinetics and mechanism of two channel hydrogen (H) abstraction reaction either hydroxyl H-atom or methyl H-atom from methanol (CH3OH) by halogen monoxide (XO, X = Cl, Br) radical have been investigated using theoretical approach.

Reesterification of ethyl acetate by propanol catalysed by glycidyl methacrylate copolymers containing sulphonic acid groups

1981 ◽  
Vol 46 (8) ◽  
pp. 1941-1946 ◽  
Author(s):  
Karel Setínek
Keyword(s):  
Liquid Phase ◽  
Ethyl Acetate ◽  
Kinetic Study ◽  
Gas Phase ◽  
Nonlinear Regression ◽  
Kinetic Data ◽  
Glycidyl Methacrylate ◽  
Kinetic Equations ◽  
Methacrylate Copolymers ◽  
Styrene Divinylbenzene

A series of differently crosslinked macroporous 2,3-epoxypropyl methacrylate-ethylenedimethacrylate copolymers with chemically bonded propylsulphonic acid groups were used as catalysts for the kinetic study of reesterification of ethyl acetate by n-propanol in the liquid phase at 52 °C and in the gas phase at 90 °C. Analysis of kinetic data by the method of nonlinear regression for a series of equations of the Langmuir-Hinshelwood type showed that kinetic equations which describe best the course of the reaction are the same as for the earlier studied sulphonated macroporous styrene-divinylbenzene copolymers. Compared types of catalysts differ, however, in the dependence of their activity on the degree of crosslinking of the copolymer used.

Experimental and theoretical studies of the gas-phase protonation of aliphatic phosphine oxides and phosphoramides

1985 ◽  
Vol 107 (19) ◽  
pp. 5352-5358 ◽  
Author(s):  
J. C. Bollinger ◽  
R. Houriet ◽  
C. W. Kern ◽  
D. Perret ◽  
J. Weber ◽  
...  
Keyword(s):  
Gas Phase ◽  
Theoretical Studies ◽  
Phosphine Oxides ◽  
Experimental And Theoretical Studies

ChemInform Abstract: Transient 1,1-Dimethyl-1-germene, (CH3)2Ge=CH2. Gas-Phase Pyrolytic Generation and EIMS, Matrix Isolation FTIR, and Theoretical Studies.

ChemInform ◽  
2010 ◽  
Vol 29 (37) ◽  
pp. no-no
Author(s):  
V. M. KHABASHESKU ◽  
K. N. KUDIN ◽  
J. TAMAS ◽  
S. E. BOGANOV ◽  
J. L. MARGRAVE ◽  
...  
Keyword(s):  
Gas Phase ◽  
Matrix Isolation ◽  
Theoretical Studies
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