Functionalized polar Octa(γ-chloropropyl) polyhedral oligomeric silsesquioxane assisted polyimide nanofiber composite membrane with excellent ionic conductivity and wetting mechanical strength towards enhanced lithium-ion battery

2020 ◽  
Vol 192 ◽  
pp. 108080 ◽  
Author(s):  
Nanping Deng ◽  
Lu Wang ◽  
Yong Liu ◽  
Chongli Zhong ◽  
Weimin Kang ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Mechanical Strength ◽  
Lithium Ion Battery ◽  
Composite Membrane ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Lithium Ion ◽  
Nanofiber Composite ◽  
Oligomeric Silsesquioxane

scholarly journals POSS-Derived Synthesis and Full Life Structural Analysis of Si@C as Anode Material in Lithium Ion Battery

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 576 ◽  
Author(s):  
Ziyu Bai ◽  
Wenmao Tu ◽  
Junke Zhu ◽  
Junsheng Li ◽  
Zhao Deng ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Anode Material ◽  
Discharge Capacity ◽  
Electrode Material ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Lithium Ion ◽  
Dynamic Features ◽  
Tem Analysis ◽  
Discharge Performance ◽  
Oligomeric Silsesquioxane

Polyhedral oligomeric silsesquioxane (POSS)-derived Si@C anode material is prepared by the copolymerization of octavinyl-polyhedral oligomeric silsesquioxane (octavinyl-POSS) and styrene. Octavinyl-polyhedral oligomeric silsesquioxane has an inorganic core (-Si8O12) and an organic vinyl shell. Carbonization of the core-shell structured organic-inorganic hybrid precursor results in the formation of carbon protected Si-based anode material applicable for lithium ion battery. The initial discharge capacity of the battery based on the as-obtained Si@C material Si reaches 1500 mAh g−1. After 550 charge-discharge cycles, a high capacity of 1430 mAh g−1 was maintained. A combined XRD, XPS and TEM analysis was performed to investigate the variation of the discharge performance during the cycling experiments. The results show that the decrease in discharge capacity in the first few cycles is related to the formation of solid electrolyte interphase (SEI). The subsequent rise in the capacity can be ascribed to the gradual morphology evolution of the anode material and the loss of capacity after long-term cycles is due to the structural pulverization of silicon within the electrode. Our results not only show the high potential of the novel electrode material but also provide insight into the dynamic features of the material during battery cycling, which is useful for the future design of high-performance electrode material.

Enhanced ionic conductivity and electrochemical capacity of lithium ion battery based on PVDF-HFP/HDPE membrane

2016 ◽  
Vol 170 ◽  
pp. 126-129 ◽  
Author(s):  
Junying He ◽  
Jiuqing Liu ◽  
Jie Li ◽  
Yanqing Lai ◽  
Xiufeng Wu
Keyword(s):  
Ionic Conductivity ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Electrochemical Capacity

Enhancing ionic conductivity with fluorination in organosilyl solvents for lithium-ion battery electrolytes

2019 ◽  
Vol 9 (4) ◽  
pp. 1200-1205 ◽  
Author(s):  
Leslie J. Lyons ◽  
Tom Derrah ◽  
Steven Sharpe ◽  
Seiyoung Yoon ◽  
Scott Beecher ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
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