Cross-linking Si x O y Cages with Carbon by Thermally Annealing Polyhedral Oligomeric Silsesquioxane: Structures, Morphology, and Electrochemical Properties as Lithium-Ion Battery Anodes

2016 ◽  
Vol 4 (1) ◽  
pp. 49-55 ◽  
Author(s):  
Junhua Kong ◽  
Yuefan Wei ◽  
Xuehong Lu ◽  
Chaobin He
Keyword(s):  
Electrochemical Properties ◽  
Lithium Ion Battery ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Lithium Ion ◽  
Cross Linking ◽  
Oligomeric Silsesquioxane

scholarly journals POSS-Derived Synthesis and Full Life Structural Analysis of Si@C as Anode Material in Lithium Ion Battery

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 576 ◽  
Author(s):  
Ziyu Bai ◽  
Wenmao Tu ◽  
Junke Zhu ◽  
Junsheng Li ◽  
Zhao Deng ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Anode Material ◽  
Discharge Capacity ◽  
Electrode Material ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Lithium Ion ◽  
Dynamic Features ◽  
Tem Analysis ◽  
Discharge Performance ◽  
Oligomeric Silsesquioxane

Polyhedral oligomeric silsesquioxane (POSS)-derived Si@C anode material is prepared by the copolymerization of octavinyl-polyhedral oligomeric silsesquioxane (octavinyl-POSS) and styrene. Octavinyl-polyhedral oligomeric silsesquioxane has an inorganic core (-Si8O12) and an organic vinyl shell. Carbonization of the core-shell structured organic-inorganic hybrid precursor results in the formation of carbon protected Si-based anode material applicable for lithium ion battery. The initial discharge capacity of the battery based on the as-obtained Si@C material Si reaches 1500 mAh g−1. After 550 charge-discharge cycles, a high capacity of 1430 mAh g−1 was maintained. A combined XRD, XPS and TEM analysis was performed to investigate the variation of the discharge performance during the cycling experiments. The results show that the decrease in discharge capacity in the first few cycles is related to the formation of solid electrolyte interphase (SEI). The subsequent rise in the capacity can be ascribed to the gradual morphology evolution of the anode material and the loss of capacity after long-term cycles is due to the structural pulverization of silicon within the electrode. Our results not only show the high potential of the novel electrode material but also provide insight into the dynamic features of the material during battery cycling, which is useful for the future design of high-performance electrode material.

Synthesis and electrochemical properties of FeCO 3 with different morphology for lithium-ion battery application

2017 ◽  
Vol 698 ◽  
pp. 87-93 ◽  
Author(s):  
Xiaolin Liu ◽  
Shuijin Yang ◽  
Xiao Chen ◽  
Hao Zheng ◽  
Zaiping Guo ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Battery Application
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