Superhydrophobic and superelastic thermoplastic polyurethane/multiwalled carbon nanotubes porous monolith for durable oil/water separation

2020 ◽  
Vol 21 ◽  
pp. 100378 ◽  
Author(s):  
Shihang Ye ◽  
Bo Wang ◽  
Yutao Shi ◽  
Bingzhong Wang ◽  
Yiru Zhang ◽  
...  
Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2431
Author(s):  
Wen Zhang ◽  
Juanjuan Wang ◽  
Xue Han ◽  
Lele Li ◽  
Enping Liu ◽  
...  

In this paper, effective separation of oil from both immiscible oil–water mixtures and oil-in-water (O/W) emulsions are achieved by using poly(dimethylsiloxane)-based (PDMS-based) composite sponges. A modified hard template method using citric acid monohydrate as the hard template and dissolving it in ethanol is proposed to prepare PDMS sponge composited with carbon nanotubes (CNTs) both in the matrix and the surface. The introduction of CNTs endows the composite sponge with enhanced comprehensive properties including hydrophobicity, absorption capacity, and mechanical strength than the pure PDMS. We demonstrate the successful application of CNT-PDMS composite in efficient removal of oil from immiscible oil–water mixtures within not only a bath absorption, but also continuous separation for both static and turbulent flow conditions. This notable characteristic of the CNT-PDMS sponge enables it as a potential candidate for large-scale industrial oil–water separation. Furthermore, a polydopamine (PDA) modified CNT-PDMS is developed here, which firstly realizes the separation of O/W emulsion without continuous squeezing of the sponge. The combined superhydrophilic and superoleophilic property of PDA/CNT-PDMS is assumed to be critical in the spontaneously demulsification process.


2016 ◽  
Vol 286 ◽  
pp. 148-154 ◽  
Author(s):  
Chien-Te Hsieh ◽  
Jo-Pei Hsu ◽  
Hsiu-Hui Hsu ◽  
Wei-Hsun Lin ◽  
Ruey-Shin Juang

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