Rheological behaviour, mechanical properties and morphological aspects of thermoplastic polyurethane reinforced with multiwalled carbon nanotubes

Author(s):  
Pietro Russo ◽  
Domenico Acierno ◽  
Paola Spena ◽  
A. D’Amore ◽  
Domenico Acierno ◽  
...  
2012 ◽  
Vol 82 (20) ◽  
pp. 2106-2115 ◽  
Author(s):  
Jonas Bouchard ◽  
Aurélie Cayla ◽  
Vincent Lutz ◽  
Christine Campagne ◽  
Eric Devaux

Nanocomposites based on Poly ((hydroxy ether) of bisphenol A) (Phenoxy) filled with multiwalled carbon nanotubes has been prepared by extrusion. Rheological behaviour and thermal degradation of these nanocomposites have been studied by melt flow index and thermogravimetric analysis. The results show that the addition of carbon nanotubes up to 2wt% increases the viscosity but does not modify significantly the spinnability of the compounds. Moreover, incorporation of these nanofillers allows an improvement of the thermal decomposition. In a second step, these nanocomposites have been processed by melt spinning to produce multifilament yarn. Transmission electron microscopy observations have been done to study carbon nanotubes dispersion and orientation. Nanocomposite morphology correlated with electrical measurements reveal an electrical percolation around 1.5 wt.% without decreasing significantly mechanical properties.


2019 ◽  
Vol 9 ◽  
pp. 184798041984085 ◽  
Author(s):  
P Kalakonda ◽  
S Banne ◽  
PB Kalakonda

Carbon nanotubes are considered to be ideal candidates for improving the mechanical properties of polymer nanocomposite scaffolds due to their higher surface area, mechanical properties of three-dimensional isotropic structure, and physical properties. In this study, we showed the improved mechanical properties prepared by backfilling of preformed hydrogels and aerogels of individually dispersed multiwalled carbon nanotubes (MWCNTs-Baytubes) and thermoplastic polyurethane. Here, we used the solution-based fabrication method to prepare the composite scaffold and observed an improvement in tensile modulus about 200-fold over that of pristine polymer at 19 wt% MWCNT loading. Further, we tested the thermal properties of composite scaffolds and observed that the nanotube networks suppress the mobility of polymer chains, the composite scaffold samples were thermally stable well above their decomposition temperatures that extend the mechanical integrity of a polymer well above its polymer melting point. The improved mechanical properties of the composite scaffold might be useful in smart material industry.


2008 ◽  
Vol 16 (8) ◽  
pp. 509-518 ◽  
Author(s):  
Fengdan Jiang ◽  
Sizhu Wu ◽  
Yongji Wei ◽  
Liqun Zhang ◽  
Guohua Hu

A melt blending process was employed to prepare nanocomposites based on thermoplastic polyurethane (TPU) and multiwalled carbon nanotubes (MWNT). The content of MWNT filled in TPU was increased till 40 phr (parts per hundreds of rubber). The morphological, structural and mechanical properties of the resulting TPU nanocomposites were systematically investigated using scanning electron microscope (SEM), transmission electron microscope (TEM), differential scanning calorimetry (DSC), X-ray diffraction (XRD), dynamic mechanical thermal analysis (DMTA) and tensile testing. The results indicated that the unmodified MWNT were dispersed finely and uniformly in the TPU matrix beyond expectation, and the microphase separation structures of the TPU nanocomposites were slightly affected by the presence of MWNT. The mechanical properties of the TPU nanocomposites containing various amounts of MWNT at both room temperature and 120 °C were studied, which demonstrated that the modulus of TPU were greatly increased and the high temperature tensile strength of TPU was also prominently improved when MWNT content is higher. Moreover, the TPU nanocomposites exhibited improved thermal and electrical conductivities that might mean the TPU/MWNT nanocomposites have potential application as multifunctional materials.


2012 ◽  
Vol 2 (6) ◽  
pp. 166-168 ◽  
Author(s):  
Dr.T.Ch.Madhavi Dr.T.Ch.Madhavi ◽  
◽  
Pavithra.P Pavithra.P ◽  
Sushmita Baban Singh Sushmita Baban Singh ◽  
S.B.Vamsi Raj S.B.Vamsi Raj ◽  
...  

2011 ◽  
Vol 528 (13-14) ◽  
pp. 4318-4324 ◽  
Author(s):  
Marcos N. dos Santos ◽  
Carlos V. Opelt ◽  
Fernando H. Lafratta ◽  
Carlos M. Lepienski ◽  
Sérgio H. Pezzin ◽  
...  

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