Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids

2017 ◽  
Vol 25 (9) ◽  
pp. 1182-1186 ◽  
Author(s):  
Xingxing Wang ◽  
Peng Zhang ◽  
Penglei Cui ◽  
Weiguo Cheng ◽  
Suojiang Zhang
Keyword(s):  
Ionic Liquids ◽  
Dimethyl Carbonate ◽  
Glycerol Carbonate

Synthesis of glycerol carbonate from glycerol and dimethyl carbonate in basic ionic liquids

2011 ◽  
Vol 84 (3) ◽  
pp. 755-762 ◽  
Author(s):  
Cinzia Chiappe ◽  
Sunita Rajamani
Keyword(s):  
Ionic Liquids ◽  
Process Optimization ◽  
Building Block ◽  
Dimethyl Carbonate ◽  
Quantitative Yield ◽  
Glycerol Carbonate ◽  
Renewable Materials ◽  
Conversion Yield ◽  
Solvent Additive ◽  
Fold Excess

Glycerol carbonate is a key multifunctional compound used as solvent, additive, and building block in alternative chlorine-free processes. Here, we report the synthesis of glycerol carbonate from renewable materials (glycerol and dimethyl carbonate, DMC) using basic ionic liquids (ILs) as catalysts. After process optimization, it has been possible to isolate pure glycerol carbonate in quantitative yield using a three-fold excess of DMC and ca. 15 % of IL. The IL could be reused at least four times without any significant reduction in the conversion yield.

CaO-catalyzed synthesis of glycerol carbonate from glycerol and dimethyl carbonate: Isolation and characterization of an active Ca species

2011 ◽  
Vol 401 (1-2) ◽  
pp. 220-225 ◽  
Author(s):  
Fidelis Stefanus Hubertson Simanjuntak ◽  
Tae Kyung Kim ◽  
Sang Deuk Lee ◽  
Byoung Sung Ahn ◽  
Hoon Sik Kim ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
Glycerol Carbonate ◽  
Isolation And Characterization

scholarly journals Ionic liquids as eco-friendly catalysts for converting glycerol and urea into high value-added glycerol carbonate

2015 ◽  
Vol 36 (3) ◽  
pp. 336-343 ◽  
Author(s):  
Juanjuan Chen ◽  
Chang Wang ◽  
Bin Dong ◽  
Wenguang Leng ◽  
Jun Huang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Value Added ◽  
Glycerol Carbonate

Transesterification of Isosorbide with Dimethyl Carbonate Catalyzed by Task‐Specific Ionic Liquids

ChemSusChem ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1169-1178 ◽  
Author(s):  
Wei Qian ◽  
Xin Tan ◽  
Qian Su ◽  
Weiguo Cheng ◽  
Fei Xu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Dimethyl Carbonate

scholarly journals Heterogeneous synthesis of glycerol carbonate from glycerol and dimethyl carbonate catalyzed by LiCl/CaO

2019 ◽  
Vol 23 (4) ◽  
pp. 494-502 ◽  
Author(s):  
Ying Tang ◽  
YuYing Xue ◽  
Zhaoyi Li ◽  
Tianlan Yan ◽  
Rui Zhou ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
Glycerol Carbonate
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