Catalytic transesterification of glycerol with dimethyl carbonate to glycerol carbonate with Co 3 O 4 nanoparticle incorporated MCM ‐41 derived from rice husk

2021 ◽  
Author(s):  
Shivali Arora ◽  
Vijayalakshmi Gosu ◽  
Verraboina Subbaramaiah ◽  
Tian C. Zhang
Keyword(s):  
Rice Husk ◽  
Dimethyl Carbonate ◽  
Glycerol Carbonate ◽  
Mcm 41

Synthesis of Glycerol Carbonate by Transesterification of Glycerol with Dimethyl Carbonate over Mg-Al Mixed Oxides Supported on MCM-41

2014 ◽  
Vol 1008-1009 ◽  
pp. 319-322
Author(s):  
Gong De Wu ◽  
Xiao Li Wang ◽  
Zhi Li Zhai ◽  
Ao Yun Cao
Keyword(s):  
Dimethyl Carbonate ◽  
Mixed Oxides ◽  
Supported Catalysts ◽  
Catalytic Performance ◽  
Molar Ratio ◽  
Catalyst Loading ◽  
Glycerol Carbonate ◽  
Reaction Conditions ◽  
Glycerol Conversion ◽  
Mcm 41

The Mg-Al mixed oxides were deposited on the MCM-41 via the coprecipitation followed by thermal decomposition and characterized by many techniques. In the transesterification of glycerol (GL) with dimethyl carbonate (DMC), the resulting supported catalysts exhibited much higher catalytic performance than the pure Mg-Al mixed oxides, which was ascribed to the increased basicity. Under the optimal reaction conditions, the obtained data showed that at DMC/glycerol molar ratio of 3:1, catalyst loading of 0.3 g and reaction temperature of 373 K, the glycerol conversion and glycerol carbonate yield from the process was 98.7 % and 92.5%, respectively.

Valorization of glycerol into glycerol carbonate using the stable heterogeneous catalyst of Li/MCM-41

2021 ◽  
pp. 126437
Author(s):  
Shivali Arora ◽  
Vijayalakshmi Gosu ◽  
U.K. Arun Kumar ◽  
Verraboina Subbaramaiah
Keyword(s):  
Heterogeneous Catalyst ◽  
Glycerol Carbonate ◽  
Mcm 41

CaO-catalyzed synthesis of glycerol carbonate from glycerol and dimethyl carbonate: Isolation and characterization of an active Ca species

2011 ◽  
Vol 401 (1-2) ◽  
pp. 220-225 ◽  
Author(s):  
Fidelis Stefanus Hubertson Simanjuntak ◽  
Tae Kyung Kim ◽  
Sang Deuk Lee ◽  
Byoung Sung Ahn ◽  
Hoon Sik Kim ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
Glycerol Carbonate ◽  
Isolation And Characterization

scholarly journals Heterogeneous synthesis of glycerol carbonate from glycerol and dimethyl carbonate catalyzed by LiCl/CaO

2019 ◽  
Vol 23 (4) ◽  
pp. 494-502 ◽  
Author(s):  
Ying Tang ◽  
YuYing Xue ◽  
Zhaoyi Li ◽  
Tianlan Yan ◽  
Rui Zhou ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
Glycerol Carbonate
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