Coordination of iron ions in the form of histidinyl dinitrosyl complexes does not prevent their genotoxicity

2012 ◽  
Vol 20 (22) ◽  
pp. 6732-6738 ◽  
Author(s):  
Hanna Lewandowska ◽  
Tomasz M. Stępkowski ◽  
Jarosław Sadło ◽  
Grzegorz P. Wójciuk ◽  
Karolina E. Wójciuk ◽  
...  
Keyword(s):  
Iron Ions ◽  
Dinitrosyl Complexes

ДИНИТРОЗИЛЬНЫЕ КОМПЛЕКСЫ ЖЕЛЕЗА C ТИОЛСОДЕРЖАЩИМИ ЛИГАНДАМИ ПРЕДСТАВЛЕНЫ В ЖИВЫХ ОРГАНИЗМАХ В ОСНОВНОМ ИХ БИЯДЕРНОЙ ФОРМОЙ

2020 ◽  
Vol 65 (6) ◽  
pp. 1142-1153
Author(s):  
В.Д. Микоян ◽  
◽  
Е.Н. Бургова ◽  
Р.Р. Бородулин ◽  
А.Ф. Ванин ◽  
...  
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Sodium Nitrite ◽  
Iron Complexes ◽  
Paramagnetic Resonance ◽  
First Case ◽  
Dinitrosyl Iron ◽  
Electron Paramagnetic ◽  
Dinitrosyl Complexes

The number of mononitrosyl iron complexes with diethyldithiocarbamate, formed in the liver of mice in vivo and in vitro after intraperitoneal injection of binuclear dinitrosyl iron complexes with N-acetyl-L-cysteine or glutathione, S-nitrosoglutathione, sodium nitrite or the vasodilating drug Isoket® was assessed by electron paramagnetic resonance (EPR). The number of the said complexes, in contrast to the complexes, formed after nitrite or Isoket administration, the level of which sharply increased after treatment of liver preparations with a strong reducing agent - dithionite, did not change in the presence of dithionite. It was concluded that, in the first case, EPR-detectable mononitrosyl iron complexes with diethyldithiocarbamate in the absence and presence of dithionite appeared as a result of the reaction of NO formed from nitrite with Fe2+-dieth- yldithiocarbamate and Fe3+-diethyldithiocarbamate complexes, respectively. In the second case, mononitrosyl iron complexes with diethyldithiocarbamate appeared as a result of the transition of iron-mononitosyl fragments from ready-made iron-dinitrosyl groups of binuclear dinitrosyl complexes, which is three to four times higher than the content of the mononuclear form of these complexes in the tissue...

Determination of the Average Energy of Iron Ions in the Axial Direction of a Micropinch Discharge Using an Ion Collector

2019 ◽  
Vol 82 (10) ◽  
pp. 1387-1391
Author(s):  
S. A. Sarantsev ◽  
I. F. Raevskii ◽  
V. A. Kostyushin ◽  
A. S. Savelov
Keyword(s):  
Average Energy ◽  
Axial Direction ◽  
Iron Ions

Magnetic properties of PbO–Sb2O3–As2O3 glasses containing iron ions

2004 ◽  
Vol 284 ◽  
pp. 363-368 ◽  
Author(s):  
B.V. Raghavaiah ◽  
D. Krishna Rao ◽  
N. Veeraiah
Keyword(s):  
Magnetic Properties ◽  
Iron Ions

scholarly journals Optical glass-ceramics based on nanosized crystals of magnesium aluminate spinel doped with iron ions

2020 ◽  
Vol 1697 ◽  
pp. 012156
Author(s):  
V Bukina ◽  
O Dymshits ◽  
I Alekseeva ◽  
M Tsenter ◽  
S Zapalova ◽  
...  
Keyword(s):  
Optical Glass ◽  
Glass Ceramics ◽  
Magnesium Aluminate ◽  
Magnesium Aluminate Spinel ◽  
Iron Ions ◽  
Nanosized Crystals

Diffusion of Iron Ions Through Protective Coatings on Steel

CORROSION ◽  
1992 ◽  
Vol 48 (8) ◽  
pp. 666-670 ◽  
Author(s):  
T. Skoulikidis ◽  
A. Ragoussis
Keyword(s):  
Protective Coatings ◽  
Iron Ions

scholarly journals Pulsed Electric Field (PEF) Enhances Iron Uptake by the Yeast Saccharomyces cerevisiae

Biomolecules ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 850
Author(s):  
Karolina Nowosad ◽  
Monika Sujka ◽  
Urszula Pankiewicz ◽  
Damijan Miklavčič ◽  
Marta Arczewska
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Electric Field ◽  
Metal Ion ◽  
Treatment Time ◽  
Control Sample ◽  
Pulsed Electric Field ◽  
Yeast Cells ◽  
Iron Ions ◽  
Metal Ion Binding ◽  
Yeast Saccharomyces Cerevisiae

The aim of the study was to investigate the influence of a pulsed electric field (PEF) on the level of iron ion accumulation in Saccharomyces cerevisiae cells and to select PEF conditions optimal for the highest uptake of this element. Iron ions were accumulated most efficiently when their source was iron (III) nitrate. When the following conditions of PEF treatment were used: voltage 1500 V, pulse width 10 μs, treatment time 20 min, and a number of pulses 1200, accumulation of iron ions in the cells from a 20 h-culture reached a maximum value of 48.01 mg/g dry mass. Application of the optimal PEF conditions thus increased iron accumulation in cells by 157% as compared to the sample enriched with iron without PEF. The second derivative of the FTIR spectra of iron-loaded and -unloaded yeast cells allowed us to determine the functional groups which may be involved in metal ion binding. The exposure of cells to PEF treatment only slightly influenced the biomass and cell viability. However, iron-enriched yeast (both with or without PEF) showed lower fermentative activity than a control sample. Thus obtained yeast biomass containing a high amount of incorporated iron may serve as an alternative to pharmacological supplementation in the state of iron deficiency.

Transformation of tetrabromobisphenol a in the iron ions-catalyzed auto-oxidation of HSO32−/SO32− process

2020 ◽  
Vol 235 ◽  
pp. 116197
Author(s):  
Pengchao Xie ◽  
Li Zhang ◽  
Jingwen Wang ◽  
Yujia Zou ◽  
Songlin Wang ◽  
...  
Keyword(s):  
Tetrabromobisphenol A ◽  
Iron Ions

Fl–DFO molecules@mesoporous silica materials: Highly sensitive and selective nanosensor for dosing with iron ions

2011 ◽  
Vol 358 (1) ◽  
pp. 136-145 ◽  
Author(s):  
Bao-Lian Su ◽  
Nicolas Moniotte ◽  
Noan Nivarlet ◽  
Li-Hua Chen ◽  
Zheng-Yi Fu ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Iron Ions ◽  
Highly Sensitive ◽  
Silica Materials ◽  
Mesoporous Silica Materials

Assessment of role of iron ions on the physical and spectroscopic properties of multi-component Na2O−PbO−Bi2O3−SiO2 glass ceramics

2017 ◽  
Vol 91 (1) ◽  
pp. 92-107 ◽  
Author(s):  
M. V. Sambasiva Rao ◽  
A. Suneel Kumar ◽  
G. Chinna Ram ◽  
Ch. Tirupataiah ◽  
D. Krishna Rao
Keyword(s):  
Glass Ceramics ◽  
Spectroscopic Properties ◽  
Iron Ions ◽  
Sio2 Glass
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