scholarly journals Aqueous or solvent based surface modification: The influence of the combination solvent – organic functional group on the surface characteristics of titanium dioxide grafted with organophosphonic acids

2017 ◽  
Vol 416 ◽  
pp. 716-724 ◽  
Author(s):  
Annelore Roevens ◽  
Jeroen G. Van Dijck ◽  
Davy Geldof ◽  
Frank Blockhuys ◽  
Benedicte Prelot ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Surface Modification ◽  
Functional Group ◽  
Surface Characteristics ◽  
Organic Functional Group

Solution to Inverse Problem of Manufacturing by Surface Modification With Controllable Surface Integrity Correlated to Performance: A Case Study of Thermally Sprayed Coatings for Wear Performance

2017 ◽  
Vol 139 (6) ◽  
Author(s):  
X. P. Zhu ◽  
P. C. Du ◽  
Y. Meng ◽  
M. K. Lei ◽  
D. M. Guo
Keyword(s):  
Inverse Problem ◽  
Surface Modification ◽  
Surface Integrity ◽  
High Performance ◽  
Surface Characteristics ◽  
Spray Angle ◽  
Functional Surface ◽  
Machining Processes ◽  
Wear Performance ◽  
Surface Features

Inverse problem of manufacturing is studied under a framework of high performance manufacturing of components with functional surface layer, where controllable generation of surface integrity is emphasized due to its pivotal role determining final performance. Surface modification techniques capable of controlling surface integrity are utilized to verify such a framework of manufacturing, by which the surface integrity desired for a high performance can be more effectively achieved as reducing the material and geometry constraints of manufacturing otherwise unobtainable during conventional machining processes. Here, thermal spraying of WC–Ni coatings is employed to coat stainless steel components for water-lubricated wear applications, on which a strategy for direct problem from process to performance is implemented with surface integrity adjustable through spray angle and inert N2 shielding. Subsequently, multiple surface integrity parameters can be evaluated to identify the major ones responsible for wear performance by elucidating the wear mechanism, involving surface features (coating porosity and WC phase retention) and surface characteristics (microhardness, elastic modulus, and toughness). The surface features predominantly determine tribological behaviors of coatings in combination with the surface characteristics that are intrinsically associated with the surface features. Consequently, the spray process with improved N2 shielding is designed according to the desired surface integrity parameters for higher wear resistance. It is demonstrated that the correlations from processes to performance could be fully understood and established via controllable surface integrity, facilitating solution to inverse problem of manufacturing, i.e., realization of a material and geometry integrated manufacturing.

scholarly journals SURFACE MODIFICATION OF TITANIUM DIOXIDE NANOPARTICLES WITH ACRYLIC ACID/ISOBUTYLENE COPOLYMER UNDER ULTRASONIC TREATMENT

2019 ◽  
Vol 16 (32) ◽  
pp. 338-344
Author(s):  
Nikolay A. BULYCHEV ◽  
Lev N. RABINSKIY
Keyword(s):  
Titanium Dioxide ◽  
Surface Modification ◽  
Composite Materials ◽  
Acrylic Acid ◽  
Ultrasonic Treatment ◽  
Titanium Dioxide Nanoparticles ◽  
Polymer Coatings ◽  
Pigment Surface ◽  
Electrokinetic Sonic Amplitude ◽  
Modification Of Titanium

The influence of the ultrasonic treatment of block copolymer solution on its solid-liquid interface behavior was investigated in detail. The surface modification of titanium dioxide nanoparticles in aqueous dispersions of specially tailor-made periodic acrylic acid/isobutylene copolymer by ultrasonic treatment was studied in order to get new approaches for the creation of hybrid composite materials or polymer coatings. The pigment surface modification by the above copolymer was comparatively investigated regarding conventional adsorption as contrasted to an ultrasonic treatment assisted procedure. The course and efficiency of the polymer adsorption onto the pigment surface were quantified by electrokinetic sonic amplitude measurements. The higher efficiency of the pigment surface coating by the copolymer as achieved by ultrasonic treatment in comparison to conventional adsorption is a consequence of ultrasonically induced pigment surface activation. Two perspective avenues of the utilization of the discovered effects for creation of organic-inorganic composite materials are anticipated: the nanoparticles could first be treated by ultrasound in the presence of polymers and so create a surface modifying coating and the second option is an entrainment of the nanoparticles into the monomer matrix which can be polymerized afterward yielding a polymer with immobilized nanoparticles.

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