In situ SERS and X-ray photoelectron spectroscopy studies on the pH-dependant adsorption of anthraquinone-2-carboxylic acid on silver electrode

2016 ◽  
Vol 367 ◽  
pp. 153-159 ◽  
Author(s):  
Dan Li ◽  
Shaojie Jia ◽  
Essy Kouadio Fodjo ◽  
Hu Xu ◽  
Yuhong Wang ◽  
...  
2010 ◽  
Vol 518 (24) ◽  
pp. e31-e33 ◽  
Author(s):  
Q. Chen ◽  
Y.P. Feng ◽  
J.W. Chai ◽  
Z. Zhang ◽  
J.S. Pan ◽  
...  

2007 ◽  
Vol 90 (20) ◽  
pp. 203109 ◽  
Author(s):  
Chia-Lin Chang ◽  
Vaithiyalingam Shutthanandan ◽  
Subhash C. Singhal ◽  
Shriram Ramanathan

MRS Bulletin ◽  
2007 ◽  
Vol 32 (12) ◽  
pp. 1022-1030 ◽  
Author(s):  
Hendrik Bluhm ◽  
Michael Hävecker ◽  
Axel Knop-Gericke ◽  
Maya Kiskinova ◽  
Robert Schlögl ◽  
...  

AbstractX-ray photoelectron spectroscopy (XPS) is a quantitative, chemically specific technique with a probing depth of a few angstroms to a few nanometers. It is therefore ideally suited to investigate the chemical nature of the surfaces of catalysts. Because of the scattering of electrons by gas molecules, XPS is generally performed under vacuum conditions. However, for thermodynamic and/or kinetic reasons, the catalyst's chemical state observed under vacuum reaction conditions is not necessarily the same as that of a catalyst under realistic operating pressures. Therefore, investigations of catalysts should ideally be performed under reaction conditions, that is, in the presence of a gas or gas mixtures. Using differentially pumped chambers separated by small apertures, XPS can operate at pressures of up to 1 Torr, and with a recently developed differentially pumped lens system, the pressure limit has been raised to about 10 Torr. Here, we describe the technical aspects of high-pressure XPS and discuss recent applications of this technique to oxidation and heterogeneous catalytic reactions on metal surfaces.


2015 ◽  
Vol 119 (40) ◽  
pp. 23082-23093 ◽  
Author(s):  
Audrey S. Duke ◽  
Randima P. Galhenage ◽  
Samuel A. Tenney ◽  
Salai C. Ammal ◽  
Andreas Heyden ◽  
...  

2012 ◽  
Vol 2 (1) ◽  
Author(s):  
Yi-Chun Lu ◽  
Ethan J. Crumlin ◽  
Gabriel M. Veith ◽  
Jonathon R. Harding ◽  
Eva Mutoro ◽  
...  

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