scholarly journals In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions

2012 ◽  
Vol 2 (1) ◽  
Author(s):  
Yi-Chun Lu ◽  
Ethan J. Crumlin ◽  
Gabriel M. Veith ◽  
Jonathon R. Harding ◽  
Eva Mutoro ◽  
...  
2018 ◽  
Vol 61 (20) ◽  
pp. 2123-2128 ◽  
Author(s):  
Baohua Mao ◽  
Yang Dai ◽  
Jun Cai ◽  
Qingtian Li ◽  
Chenggong Jiang ◽  
...  

2015 ◽  
Vol 119 (40) ◽  
pp. 23082-23093 ◽  
Author(s):  
Audrey S. Duke ◽  
Randima P. Galhenage ◽  
Samuel A. Tenney ◽  
Salai C. Ammal ◽  
Andreas Heyden ◽  
...  

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Marc Benjamin Hahn ◽  
Paul M. Dietrich ◽  
Jörg Radnik

AbstractIonizing radiation damage to DNA plays a fundamental role in cancer therapy. X-ray photoelectron-spectroscopy (XPS) allows simultaneous irradiation and damage monitoring. Although water radiolysis is essential for radiation damage, all previous XPS studies were performed in vacuum. Here we present near-ambient-pressure XPS experiments to directly measure DNA damage under water atmosphere. They permit in-situ monitoring of the effects of radicals on fully hydrated double-stranded DNA. The results allow us to distinguish direct damage, by photons and secondary low-energy electrons (LEE), from damage by hydroxyl radicals or hydration induced modifications of damage pathways. The exposure of dry DNA to x-rays leads to strand-breaks at the sugar-phosphate backbone, while deoxyribose and nucleobases are less affected. In contrast, a strong increase of DNA damage is observed in water, where OH-radicals are produced. In consequence, base damage and base release become predominant, even though the number of strand-breaks increases further.


2017 ◽  
Vol 53 (37) ◽  
pp. 5231-5234 ◽  
Author(s):  
Jack Chun-Ren Ke ◽  
Alex S. Walton ◽  
David J. Lewis ◽  
Aleksander Tedstone ◽  
Paul O'Brien ◽  
...  

Near-ambient-pressure X-ray photoelectron spectroscopy enables the study of the reaction of in situ-prepared methylammonium lead iodide (MAPI) perovskite at realistic water vapour pressures for the first time.


2015 ◽  
Vol 174 ◽  
pp. 532-541 ◽  
Author(s):  
Benedetto Bozzini ◽  
Matteo Amati ◽  
Patrizia Bocchetta ◽  
Simone Dal Zilio ◽  
Axel Knop-Gericke ◽  
...  

2010 ◽  
Vol 518 (24) ◽  
pp. e31-e33 ◽  
Author(s):  
Q. Chen ◽  
Y.P. Feng ◽  
J.W. Chai ◽  
Z. Zhang ◽  
J.S. Pan ◽  
...  

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