Adsorption mechanism of poly(vinyl alcohol) at the mixed oxide Cu x O y –SiO 2 /aqueous solution interface

2015 ◽  
Vol 356 ◽  
pp. 905-910 ◽  
Author(s):  
M. Wiśniewska ◽  
V. Bogatyrov ◽  
K. Szewczuk-Karpisz ◽  
I. Ostolska ◽  
K. Terpiłowski
Keyword(s):  
Aqueous Solution ◽  
Mixed Oxide ◽  
Vinyl Alcohol ◽  
Adsorption Mechanism ◽  
Poly Vinyl Alcohol ◽  
Solution Interface

scholarly journals Modification of Surface Properties of Colloidal Suspensions of NixOy-SiO2 Mixed Oxides with Different Ni Contents by the Adsorption Layers of Poly(Vinyl Alcohol)

2020 ◽  
Author(s):  
M. Wiśniewska ◽  
S. Chibowski ◽  
T. Urban ◽  
G. Fijałkowska ◽  
M. Medykowska ◽  
...  
Keyword(s):  
Nickel Oxide ◽  
Mixed Oxide ◽  
Vinyl Alcohol ◽  
Mixed Oxides ◽  
Colloidal Suspensions ◽  
Surface Characteristics ◽  
Limited Range ◽  
Poly Vinyl Alcohol ◽  
Solution Interface ◽  
Adsorption Affinity

Abstract The adsorption and electrokinetic properties of hybrid silica materials composed of nickel and silicon oxides (NixOy-SiO2), characterized by different contents of nickel oxide (from 0.5 to 3 mmol/g SiO2), were examined. These solids were also modified by poly(vinyl alcohol) to change their surface characteristics. The polymer is non-toxic and very well soluble in water. Due to incomplete hydrolysis of the polymer acetate groups, its macromolecules become negatively charged. The limited range of studied pH (6–10) resulted from high solubility of nickel oxide at more acidic pH values. The spectrophotometric, surface charge and electrophoretic measurements indicated that PVA exhibits higher adsorption affinity for the surfaces of mixed oxide with a larger content of nickel in its structure. Moreover, the presence of polymeric layers on the solid surface influences considerably the structure of electrical double layer formed at the mixed oxide-aqueous solution interface.

Multiporous open-cell poly(vinyl formal) foams for sound absorption

RSC Advances ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 7653-7660 ◽  
Author(s):  
Bai Xue ◽  
Jianguo Deng ◽  
Junhua Zhang
Keyword(s):  
Aqueous Solution ◽  
Vinyl Alcohol ◽  
Sound Absorption ◽  
Poly Vinyl Alcohol ◽  
Open Cell

A series of multiporous open-cell poly(vinyl formal) (PVF) foams were obtained by crosslinking poly(vinyl alcohol) (PVA) with different contents of formaldehyde in aqueous solution.

Novel pH-Sensitive Poly(Vinyl Alcohol) Based Polyampholyte as Pervaporation Membrane

2016 ◽  
Vol 852 ◽  
pp. 979-983
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li
Keyword(s):  
Aqueous Solution ◽  
Vinyl Alcohol ◽  
Water Resistance ◽  
Graft Copolymerization ◽  
Sodium Acrylate ◽  
Poly Vinyl Alcohol ◽  
Permeate Flux ◽  
Ft Ir ◽  
Ethanol Aqueous Solution ◽  
Poly Acrylamide

Sodium acrylate (NaAA) and acrylamide (AM) were grafted onto poly (vinyl alcohol) (PVA) using potassium persulfate as an initiator, Graft copolymerization namely poly (vinyl alcohol)-g-poly (acrylamide/sodium acrylate) (PVA-g-PAM/SAC). The poly (vinyl alcohol)-g-poly (vinylamine/sodium acrylate) (PVAMC) was prepraed by Hofmann rearrangement.The PVAMC homogeneous membrane was characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM).The water resistance of the PVAMC membranes is the best when pH of the PVAMC solutions was 4, at that time the numbers of-NH3+ and-COO- groups trended to be equal, so the isoelectric point was pH=4. At 90 °C the pervaporation of PVAMC composite membrane was tested and showed that the separation factor and the permeate flux were about 1001 and 1341 g/(m2·h) for 90wt% ethanol aqueous solution, and they were about 1297 and 1040 g/(m2·h) for 90wt% isopropanol aqueous solution.

Effect of ZnO nanoparticles on the electrospinning of poly(vinyl alcohol) from aqueous solution: Influence of particle size

2013 ◽  
Vol 54 (9) ◽  
pp. 1969-1975 ◽  
Author(s):  
Tongsai Jamnongkan ◽  
Ryo Shirota ◽  
Sathish K. Sukumaran ◽  
Masataka Sugimoto ◽  
Kiyohito Koyama
Keyword(s):  
Aqueous Solution ◽  
Particle Size ◽  
Zno Nanoparticles ◽  
Vinyl Alcohol ◽  
Poly Vinyl Alcohol

scholarly journals DYNAMICAL ASPECTS OF SOL-GEL TRANSITION IN AN AQUEOUS SOLUTION OF POLY (VINYL ALCOHOL)

1984 ◽  
Vol 40 (4-5) ◽  
pp. T158-T160
Author(s):  
Motoko Komatsu ◽  
Takashi Inoue ◽  
Keizo Miyasaka
Keyword(s):  
Aqueous Solution ◽  
Vinyl Alcohol ◽  
Sol Gel ◽  
Poly Vinyl Alcohol ◽  
Sol Gel Transition ◽  
Gel Transition
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