Surfactant-assisted preparation of core-shell-type TiO 2 –Fe 2 O 3 composites and their photocatalytic activities under room light irradiation

2014 ◽  
Vol 316 ◽  
pp. 187-193 ◽  
Author(s):  
Inseok Jang ◽  
Kyoung-Eun You ◽  
Young Chai Kim ◽  
Seong-Geun Oh
Keyword(s):  
Light Irradiation ◽  
Core Shell ◽  
Room Light ◽  
Shell Type ◽  
Photocatalytic Activities ◽  
Surfactant Assisted

scholarly journals Fabrication of Hollow Core-Shell Type Si/C Nanocomposites by a Simple Process

2017 ◽  
Vol 15 (0) ◽  
pp. 69-73 ◽  
Author(s):  
Kei Wakabayashi ◽  
Daichi Yamaura ◽  
Kazuki Ito ◽  
Naoya Kameda ◽  
Toshio Ogino
Keyword(s):  
Core Shell ◽  
Hollow Core ◽  
Simple Process ◽  
Shell Type

scholarly journals CdSe/ZnS Core-Shell-Type Quantum Dot Nanoparticles Disrupt the Cellular Homeostasis in Cellular Blood–Brain Barrier Models

2021 ◽  
Vol 22 (3) ◽  
pp. 1068
Author(s):  
Katarzyna Dominika Kania ◽  
Waldemar Wagner ◽  
Łukasz Pułaski
Keyword(s):  
Gene Expression ◽  
Quantum Dot ◽  
Blood Brain Barrier ◽  
Protein Gene ◽  
Brain Barrier ◽  
Core Shell ◽  
Cellular Homeostasis ◽  
Blood Brain ◽  
Shell Type ◽  
The Impact

Two immortalized brain microvascular endothelial cell lines (hCMEC/D3 and RBE4, of human and rat origin, respectively) were applied as an in vitro model of cellular elements of the blood–brain barrier in a nanotoxicological study. We evaluated the impact of CdSe/ZnS core-shell-type quantum dot nanoparticles on cellular homeostasis, using gold nanoparticles as a largely bioorthogonal control. While the investigated nanoparticles had surprisingly negligible acute cytotoxicity in the evaluated models, a multi-faceted study of barrier-related phenotypes and cell condition revealed a complex pattern of homeostasis disruption. Interestingly, some features of the paracellular barrier phenotype (transendothelial electrical resistance, tight junction protein gene expression) were improved by exposure to nanoparticles in a potential hormetic mechanism. However, mitochondrial potential and antioxidant defences largely collapsed under these conditions, paralleled by a strong pro-apoptotic shift in a significant proportion of cells (evidenced by apoptotic protein gene expression, chromosomal DNA fragmentation, and membrane phosphatidylserine exposure). Taken together, our results suggest a reactive oxygen species-mediated cellular mechanism of blood–brain barrier damage by quantum dots, which may be toxicologically significant in the face of increasing human exposure to this type of nanoparticles, both intended (in medical applications) and more often unintended (from consumer goods-derived environmental pollution).

scholarly journals Effect of Core-Shell Ag@TiO2Volume Ratio on Characteristics of TiO2-Based DSSCs

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Ho Chang ◽  
Chih-Hao Chen ◽  
Mu-Jung Kao ◽  
Hsin-Han Hsiao
Keyword(s):  
Conversion Efficiency ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Photoelectric Conversion Efficiency ◽  
Core Shell ◽  
Photoelectric Conversion ◽  
Shell Type ◽  
Degussa P25 ◽  
Triton X

This paper aims to develop photoanode material required by dye-sensitized solar cells. The material prepared is in the form of Ag@TiO2core-shell-type nanocomposites. This material is used to replace the titanium oxide powder commonly used in general DSSCs. The prepared Ag@TiO2core-shell-type nanocomposites are mixed with Degussa P25 TiO2in different proportions. Triton X-100 is added and polyethylene glycol (PEG) at 20 wt% is used as a polymer additive. This study tests the particle size and material properties of Ag@TiO2core-shell-type nanocomposites and measures the photoelectric conversion efficiency and IPCE of DSSCs. Experimental results show that the DSSC prepared by Ag@TiO2core-shell-type nanocomposites can achieve a photoelectric conversion efficiency of 3.67%. When Ag@TiO2core-shell-type nanocomposites are mixed with P25 nanoparticles in specific proportions, and when the thickness of the photoelectrode thin film is 28 μm, the photoelectric conversion efficiency can reach 6.06%, with a fill factor of 0.52, open-circuit voltage of 0.64V, and short-circuit density of 18.22 mAcm−2. Compared to the DSSC prepared by P25 TiO2only, the photoelectric conversion efficiency can be raised by 38% under the proposed approach.

Synthesis of highly monodispersed teardrop-shaped core–shell SiO2/TiO2 nanoparticles and their photocatalytic activities

2015 ◽  
Vol 351 ◽  
pp. 320-326 ◽  
Author(s):  
Lihong Wu ◽  
Yifeng Zhou ◽  
Wangyan Nie ◽  
Linyong Song ◽  
Pengpeng Chen
Keyword(s):  
Tio2 Nanoparticles ◽  
Core Shell ◽  
Photocatalytic Activities

Solvothermal synthesis and visible light-driven photocatalytic degradation for tetracycline of Fe-doped SrTiO3

RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47615-47624 ◽  
Author(s):  
Ping Li ◽  
Chunbo Liu ◽  
Guoling Wu ◽  
Yang Heng ◽  
Shuang Lin ◽  
...  
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Solvothermal Synthesis ◽  
Solvothermal Method ◽  
Light Irradiation ◽  
Photocatalytic Activities ◽  
Visible Light Driven ◽  
Facile Solvothermal Method

In this paper, Fe-doped SrTiO3 (FSTO) photocatalysts were successfully prepared via a facile solvothermal method, and their photocatalytic activities for degrading tetracycline (TC) under visible light irradiation were examined.

scholarly journals Synthesis, Analysis, and Testing of BiOBr-Bi2WO6Photocatalytic Heterojunction Semiconductors

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Xiangchao Meng ◽  
Zisheng Zhang
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Degradation Process ◽  
Light Irradiation ◽  
Enhancement Effect ◽  
Electron Hole ◽  
Experimental Conditions ◽  
Synthesis Conditions ◽  
Optimum Synthesis ◽  
Photocatalytic Activities

In photocatalysis, the recombination of electron-hole pairs is generally regarded as one of its most serious drawbacks. The synthesis of various composites with heterojunction structures has increasingly shed light on preventing this recombination. In this work, a BiOBr-Bi2WO6photocatalytic heterojunction semiconductor was synthesized by the facile hydrothermal method and applied in the photocatalytic degradation process. It was determined that both reaction time and temperature significantly affected the crystal structure and morphologies of the photocatalysts. BiOBr (50 at%)-Bi2WO6composites were prepared under optimum synthesis conditions (120°C for 6 h) and by theoretically analyzing the DRS results, it was determined that they possessed the suitable band gap (2.61 eV) to be stimulated by visible-light irradiation. The photocatalytic activities of the as-prepared photocatalysts were evaluated by the degradation ofRhodamine B (RhB)under visible-light irradiation. The experimental conditions, including initial concentration, pH, and catalyst dosage, were explored and the photocatalysts in this system were proven stable enough to be reused for several runs. Moreover, the interpreted mechanism of the heterojunction enhancement effect proved that the synthesis of a heterojunction structure provided an effective method to decrease the recombination rate of the electron-hole pairs, thereby improving the photocatalytic activity.

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