scholarly journals An extended thermodynamic model for size-dependent thermoelectric properties at nanometric scales: Application to nanofilms, nanocomposites and thin nanocomposite films

2016 ◽  
Vol 40 (3) ◽  
pp. 2143-2160 ◽  
Author(s):  
H. Machrafi
2005 ◽  
Vol 20 (9) ◽  
pp. 2516-2522 ◽  
Author(s):  
George Sirinakis ◽  
Rezina Siddique ◽  
Christos Monokroussos ◽  
Michael A. Carpenter ◽  
Alain E. Kaloyeros

Nanocomposite films consisting of gold nanoparticles embedded in an yttria stabilized zirconia (YSZ) matrix were synthesized at room temperature by radio-frequency co-sputtering from YSZ and Au targets at a 5 mTorr working pressure. The films were subsequently annealed for 2 h in 1 atm argon, with the annealing temperature varied from 600 to 1000 °C in steps of 100 °C. The composition, microstructure, and optical properties of the films were characterized as a function of annealing temperature by Rutherford backscattering spectrometry, scanning electron microscopy, Auger electron spectroscopy, x-ray diffraction, and absorption spectroscopy. An optical absorption band due to the surface plasmon resonance (SPR) of the Au nanoparticles was observed around a wavelength of 600 nm. Furthermore, the SPR band full width at half-maximum exhibited an inverse linear dependence on the radius of the Au nanoparticle, with a slope parameter A = 0.18, indicating a weak interaction between the YSZ matrix and the Au nanoparticles. The experimentally observed SPR dependence on nanoparticle size is discussed within the context of the Mie theory and its size-dependent optical constants.


2012 ◽  
Vol 285 (24) ◽  
pp. 5433-5439 ◽  
Author(s):  
Pullarkat P. Jeeju ◽  
S. Jayalekshmi ◽  
K. Chandrasekharan ◽  
P. Sudheesh

2011 ◽  
Vol 60 (8) ◽  
pp. 1263-1268 ◽  
Author(s):  
Pullarkat P Jeeju ◽  
Augustine M Sajimol ◽  
Vallath G Sreevalsa ◽  
Sreekanth J Varma ◽  
S Jayalekshmi

RSC Advances ◽  
2016 ◽  
Vol 6 (58) ◽  
pp. 53339-53344 ◽  
Author(s):  
Woohwa Lee ◽  
Young Hun Kang ◽  
Jun Young Lee ◽  
Kwang-Suk Jang ◽  
Song Yun Cho

This study investigates a treatment method with ethylene glycol for improving the thermoelectric properties of CNT/PEDOT:PSS nanocomposite films.


Author(s):  
M. C. Carrisi ◽  
M. A. Mele ◽  
S. Pennisi

Recently, the 14 moments model of extended thermodynamics for dense gases and macromolecular fluids has been considered and an exact solution, of the restrictions imposed by the entropy principle and that of Galilean relativity, has been obtained without using Taylor's expansions. Here, we prove the uniqueness of the above solution and exploit other pertinent conditions such as the convexity of the function h ′ related to the entropy density, the problem of subsystems and the fact that the flux in the conservation law of mass must be the moment of order 1 in the conservation law of momentum. The results present interesting aspects which were not suspected when only approximated solutions of this problem were known.


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