scholarly journals The dissociation kinetics of Cu-dissolved organic matter complexes from soil and soil amendments

2010 ◽  
Vol 670 (1-2) ◽  
pp. 24-32 ◽  
Author(s):  
F. Amery ◽  
F. Degryse ◽  
C. Van Moorleghem ◽  
M. Duyck ◽  
E. Smolders
Author(s):  
M.I. Pinto ◽  
R. Salgado ◽  
Barbara A. Cottrell ◽  
William J. Cooper ◽  
Hugh D. Burrows ◽  
...  

2011 ◽  
Vol 8 (5) ◽  
pp. 517 ◽  
Author(s):  
Jacqueline Levy ◽  
Hao Zhang ◽  
William Davison ◽  
Rene Groben

Environmental context Interaction of metals with dissolved organic matter is one of the key processes defining metal bioavailability in water. The technique of diffusive gradients in thin films was used to investigate the kinetics of the interaction between metals and dissolved organic matter released by algae. For most metals the rate at which they were released from the organic matter was fast, but release of iron was kinetically limited. AbstractThe interaction of metals with organic matter is one of the key processes determining metal speciation and bioavailability in water. Fulvic acid tends to dominate dissolved organic carbon (DOC) in freshwaters, but organic carbon produced in situ, e.g. exudates released by algae and bacteria, is also significant. The technique of diffusive gradients in thin films (DGT) was used to investigate the lability of metal–exudate complexes using a kinetic signature approach. Exudates were harvested from three cultured freshwater alga (Chlorella vulgaris, Cryptomonas pyrenoidifera, Anabaena flos-aquae) and the filtered media supplemented with trace metals. DGT-labile metal concentrations and kinetic signatures were determined (24-h deployment). The relationship between Fe and DOC was a defining feature of the kinetic signatures. Iron was the most kinetically limited metal followed by Al and Cu, whereas Co, Ni and Pb were effectively completely labile. Exudates from Chlorella vulgaris produced the most DOC and the most marked kinetic limitation.


2011 ◽  
Vol 45 (23) ◽  
pp. 10013-10019 ◽  
Author(s):  
Frank-Dieter Kopinke ◽  
Ksenia Ramus ◽  
Juergen Poerschmann ◽  
Anett Georgi

2020 ◽  
Author(s):  
Yun-Hsuan Ho ◽  
Jie Yinn Lee ◽  
Chia-Ying Chuang

<p>Progress has been made towards optimizing extracting dissolved organic matter (DOM) using a styrene-divinylbenzene copolymer (PPL) sorbent, which is a widely used solid phase extraction (SPE) method to separate DOM from different aquatic samples. To establish the suitable extraction conditions, the effects of critical SPE variables such as loading mass, concentration, flow rate, as well as the extraction selectivity of the PPL sorbent have been systematically studied. Tens liters of water samples were collected from various aquatic environments, including headwater, downstream river water, coastal seawater, surface seawater from open ocean, seawater from open ocean at the depth of fluorescence maximum, and deep ocean water. 5g-Bond Elut PPL columns were used and the extraction kinetics of DOM were monitored liter-by-liter while extraction. Fluorescence spectrum were decomposed into their underlying chemical components resolved by PARAllel FACtor analysis (PARAFAC). Extraction selectivity of the PPL sorbent among different types of waters was verified through those fluorescence excitation emission matrices (EEMs) and chromophoric dissolved organic matter (CDOM) measurements.</p>


2016 ◽  
Vol 24 (6) ◽  
pp. 1413-1422 ◽  
Author(s):  
Francis H. Chapelle ◽  
Yuan Shen ◽  
Eric W. Strom ◽  
Ronald Benner

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