Rapid determination of hydrogen peroxide in the wood pulp bleaching streams by a dual-wavelength spectroscopic method

2004 ◽  
Vol 507 (2) ◽  
pp. 281-284 ◽  
Author(s):  
X.-S Chai ◽  
Q.X Hou ◽  
Q Luo ◽  
J.Y Zhu
RSC Advances ◽  
2019 ◽  
Vol 9 (22) ◽  
pp. 12580-12584
Author(s):  
Xiaojie Tu ◽  
Zhanbo Hu ◽  
Xin-Sheng Chai ◽  
Yuting Su

In this study, a dual-wavelength spectroscopic method for rapid determination of organic matter in sludge was developed.


1988 ◽  
Vol 34 (8) ◽  
pp. 1607-1610 ◽  
Author(s):  
P A Bolhuis ◽  
R Zwart ◽  
P R Bär ◽  
M de Visser ◽  
H J van der Helm

Abstract After ischemic exercise tests, performed to detect glycogenoses or myoadenylate deaminase (EC 3.5.4.6) deficiency, the increases in serum lactate and ammonia usually are measured. Determination of hypoxanthine instead of ammonia can also be used to show myoadenylate deaminase deficiency, but HPLC of hypoxanthine is time-consuming. As a substitute, we developed an indirect enzymatic equilibrium method for hypoxanthine based on coupling the chromogenic system 3,5-dichloro-2-hydroxy-benzenesulfonic acid/4-aminophenazone with formation of hydrogen peroxide by xanthine oxidase (EC 1.1.3.22). The pH optimum is at 7.8 and the absorbance maximum at 510 nm. The calibration curve is linear from 0 to 100 mumol/L and the detection limit is 0.9 mumol/L. Analytical variability (CV) was 1.5% to 3.6% within-run, 4.5% to 8.5% between-run. The assay can be performed with a standard spectrophotometer or a centrifugal analyzer. The coefficient of correlation was 0.68 between hypoxanthine and ammonia increases in plasma from controls who performed the exercise test.


2009 ◽  
Vol 30 (11) ◽  
pp. 1983-1990 ◽  
Author(s):  
Xiaocong Gong ◽  
Qingling Li ◽  
Kehua Xu ◽  
Xin Liu ◽  
Hongmin Li ◽  
...  

2006 ◽  
Vol 22 (6) ◽  
pp. 815-817 ◽  
Author(s):  
Maki ONODA ◽  
Takefumi UCHIYAMA ◽  
Ken-ichi MAWATARI ◽  
Kiyoko KANEKO ◽  
Kazuya NAKAGOMI

2010 ◽  
Vol 88 (1) ◽  
pp. 39-46 ◽  
Author(s):  
M. M. Mossoba ◽  
A. Seiler ◽  
H. Steinhart ◽  
J. K. G. Kramer ◽  
L. Rodrigues-Saona ◽  
...  

2020 ◽  
Vol 10 (10) ◽  
pp. 3545
Author(s):  
Rahul Joshi ◽  
Ritu Joshi ◽  
Changyeun Mo ◽  
Mohammad Akbar Faqeerzada ◽  
Hanim Z. Amanah ◽  
...  

Grignard reagent is one of the most popular materials in chemical and pharmaceutical reaction processes, and requires high quality with minimal adulteration. In this study, Raman spectroscopic technique was investigated for the rapid determination of toluene content, which is one of the common adulterants in Grignard reagent. Raman spectroscopy is the most suitable spectroscopic method to mitigate moisture and CO2 interference in the molecules of Grignard reagent. Raman spectra for the mixtures of toluene and Grignard reagent with different concentrations were analyzed with a partial least square regression (PLSR) method. The combination of spectral wavebands in the prediction model was optimized with a variables selection method of variable importance in projection (VIP). The results obtained from the VIP-based PLSR model showed the reliable performance of Raman spectroscopy for predicting the toluene concentration present in Grignard reagent with a correlation coefficient value of 0.97 and a standard error of prediction (SEP) of 0.71%. The results showed that Raman spectroscopy combined with multivariate analysis could be an effective analytical tool for rapid determination of the quality of Grignard reagent.


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