Immobilized Triazolium Salts as Precursors to Chiral Carbenes - Rhodium-Catalyzed Asymmetric Hydrosilylation as a First Test Reaction

1998 ◽  
Vol 2 (7) ◽  
pp. 105-108 ◽  
Author(s):  
Dieter Enders ◽  
Heike Gielen ◽  
Klaus Breuer
Keyword(s):  
Test Reaction ◽  
Triazolium Salts

Evolution of an abnormal light test reaction

1971 ◽  
Vol 103 (2) ◽  
pp. 154-157 ◽  
Author(s):  
W. K. Stern
Keyword(s):  
Test Reaction

Test Reaction Scale

1956 ◽  
Author(s):  
J. R. Wittenborn
Keyword(s):  
Test Reaction

scholarly journals Application of microwave radiation in the grafting of acidic sites on SBA-15 type material

2021 ◽  
Author(s):  
Maciej Trejda ◽  
Magdalena Drobnik ◽  
Ardian Nurwita
Keyword(s):  
Microwave Radiation ◽  
Thermal Analyses ◽  
Conventional Heating ◽  
Material Surface ◽  
Test Reaction ◽  
Study Materials ◽  
Mesoporous Support ◽  
Acidic Sites ◽  
Post Synthesis ◽  
Adsorption Desorption

AbstractMesoporous silica of SBA-15 type was modified for the first time with 3-(trihydroxysiyl)-1-propanesulfonic acid (TPS) by post-synthesis modification involving microwave or conventional heating in order to generate the Brønsted acidic centers on the material surface. The samples structure and composition were examined by low temperature N2 adsorption/desorption, XRD, HRTEM, elemental and thermal analyses. The surface properties were evaluated by esterification of acetic acid with n-hexanol used as the test reaction. A much higher efficiency of TPS species incorporation was reached with the application of microwave radiation for 1 h than conventional modification for 24 h. It was found that the structure of mesoporous support was preserved after modification using both methods applied in this study. Materials obtained with the use of microwave radiation showed a superior catalytic activity and high stability.

scholarly journals Imposed dynamic irradiation to intensify photocatalytic reactions

2021 ◽  
Author(s):  
Fabian Guba ◽  
Florian Gaulhofer ◽  
Dirk Ziegenbalg
Keyword(s):  
Large Scale ◽  
Reaction Rate ◽  
Photochemical Reactions ◽  
Test Reaction ◽  
Light Emitting ◽  
Photochemical Processes ◽  
Spatially Distributed ◽  
Photocatalytic Reactions ◽  
The Impact ◽  
Photonic Efficiency

AbstractDynamic irradiation is a potent option to influence the interaction between photochemical reactions and mass transport to design high performant and efficient photochemical processes. To systematically investigate the impact of this parameter, the photocatalytic reduction of nitrobenzene was conducted as a test reaction. Dynamic irradiation was realized through provoked secondary flow patterns, multiple spatially distributed light emitting diodes (LEDs) and electrical pulsation of LEDs. A combined experimental and theoretical approach revealed significant potential to enhance photochemical processes. The reaction rate was accelerated by more than 70% and even more important the photonic efficiency was increased by more than a factor of 4. This renders imposed dynamic irradiation an innovative and powerful tool to intensify photoreactions on the avenue to large scale sustainable photochemical processes.

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