Phase behavior in sodium cholate/calcium chloride mixtures

2007 ◽  
pp. 24-28
Author(s):  
V. Babić-Ivančić ◽  
D. Škrtić ◽  
N. Filipović-Vinceković
Keyword(s):  
Phase Behavior ◽  
Calcium Chloride ◽  
Sodium Cholate

Mechanism of Alcohol Displacement of Oil from Porous Media

1961 ◽  
Vol 1 (03) ◽  
pp. 195-212 ◽  
Author(s):  
J.J. Taber ◽  
I.S.K. Kamath ◽  
Ronald L. Reed
Keyword(s):  
Phase Behavior ◽  
Calcium Chloride ◽  
Solid Phase ◽  
Equilibrium Phase ◽  
Water System ◽  
Commercial Application ◽  
Practical Result ◽  
Immiscible Mixture ◽  
Two Phases ◽  
Tie Line

Abstract Alcohol floods of consolidated sandstone cores have shown the process to be strongly dependent on the phase behavior of the particular alcohol-oil-water system used. This means that in many cases the mechanism does not conform to the idea of a piston-like displacement. Instead, it is found that by changing the alcohol it is possible to change the relative velocities of the oil and water and, in fact, the entire mechanism of the process. The effects of rate, viscosity, initial saturation, distance travelled and hysteresis of relative permeability on the alcohol flooding mechanism are discussed. Introduction Reasons for interest in the use of alcohol to miscibly displace oil and water from a porous medium appear in the existing literature. The mechanism of the displacement has been considered and the apparent implications formulated into a theory which presumably would enable one to predict the essential features of the process. Unfortunately, most of the reported experiments have been performed with unconsolidated or artificially consolidated sands. With these systems some of the noteworthy facets of the process are obscured and resulting data appear uncertain. It is the purpose of this paper to show how the use of consolidated sandstones has led to revision of the mechanism and, hence, the theory of alcohol flooding. The practical result is increased pessimism toward the possibilities of commercial application of the simplest form of the alcohol-slug process. However elucidation of the mechanism has made it possible to define the essential characteristics of a system of slugs which will behave in a nearly piston-like fashion and, thus, yield the best possible result. Equilibrium Phase Behavior Fig. 1 is a diagram of the ternary system isopropyl alcohol (IPA)-Soltrol-calcium chloride brine. Brine was used to prevent plugging of the core and calcium chloride was used because sodium chloride brine exhibits a solid phase with Soltrol and IPA. If alcohol is added in increments to the immiscible mixture of water and oil represented by Point A, the path followed by the successively equilibrated samples will be on the Line ABC and pass from the immiscible region to the miscible region by crossing the binodal curve at B. Consider the intersection D of this path with the tie Line EF. The quantity of oleic phase is proportional to the Segment ED and the quantity of the aqueous phase is proportional to DF. Compositions of the two phases are specified by Points E and F. It is clear that in the case shown the oleic phase is diminishing and entirely disappears when miscibility is achieved.

Phase Behavior of Bis(Quaternary Ammonium Bromide)/Sodium Cholate/H2O System

2005 ◽  
Vol 26 (1) ◽  
pp. 39-51 ◽  
Author(s):  
M. Jendric ◽  
N. Filipović‐Vinceković ◽  
M. Vinceković ◽  
M. Bujan ◽  
I. Primožić
Keyword(s):  
Phase Behavior ◽  
Quaternary Ammonium ◽  
Sodium Cholate ◽  
Ammonium Bromide

Interactions in Aqueous Systems Containing Sodium Cholate/Calcium Chloride Mixtures

1996 ◽  
Vol 177 (2) ◽  
pp. 646-657 ◽  
Author(s):  
N. Filipović-Vinceković ◽  
V. Babić-Ivančić ◽  
I. Šmit
Keyword(s):  
Calcium Chloride ◽  
Sodium Cholate ◽  
Aqueous Systems

Phase behavior of cationic and anionic surfactants at low concentrations

1992 ◽  
Vol 50 (1) ◽  
pp. 694-695
Author(s):  
E. Naranjo
Keyword(s):  
Phase Behavior ◽  
Structural Characterization ◽  
Dynamic Systems ◽  
Anionic Surfactants ◽  
Intermolecular Forces ◽  
Stable Form ◽  
Surfactant Mixtures ◽  
Low Concentrations ◽  
Cationic And Anionic Surfactants ◽  
General Method

Equilibrium vesicles, those which are the stable form of aggregation and form spontaneously on mixing surfactant with water, have never been demonstrated in single component bilayers and only rarely in lipid or surfactant mixtures. Designing a simple and general method for producing spontaneous and stable vesicles depends on a better understanding of the thermodynamics of aggregation, the interplay of intermolecular forces in surfactants, and an efficient way of doing structural characterization in dynamic systems.

Solution Properties and Phase Behavior of Ammonium Hexylene Octyl Succinate in Water and Water-Oil System

1970 ◽  
Vol 3 (1) ◽  
Author(s):  
Md. Hamidul Kabir ◽  
Ravshan Makhkamov ◽  
Shaila Kabir
Keyword(s):  
Critical Micelle Concentration ◽  
Phase Behavior ◽  
Liquid Crystalline ◽  
Carbon Number ◽  
Phase Region ◽  
Solution Properties ◽  
Middle Phase ◽  
Two Phase ◽  
Lamellar Liquid Crystal ◽  
Drug Ingredient

The solution properties and phase behavior of ammonium hexylene octyl succinate (HOS) was investigated in water and water-oil system. The critical micelle concentration (CMC) of HOS is lower than that of anionic surfactants having same carbon number in the lipophilic part. The phase diagrams of a water/ HOS system and water/ HOS/ C10EO8/ dodecane system were also constructed. Above critical micelle concentration, the surfactant forms a normal micellar solution (Wm) at a low surfactant concentration whereas a lamellar liquid crystalline phase (La) dominates over a wide region through the formation of a two-phase region (La+W) in the binary system. The lamellar phase is arranged in the form of a biocompatible vesicle which is very significant for the drug delivery system. The surfactant tends to be hydrophilic when it is mixed with C10EO8 and a middle-phase microemulsion (D) is appeared in the water-surfactant-dodecane system where both the water and oil soluble drug ingredient can be incorporated in the form of a dispersion. Hence, mixing can tune the hydrophile-lipophile properties of the surfactant. Key words: Ammonium hexylene octyl succinate, mixed surfactant, lamellar liquid crystal, middle-phase microemulsion. Dhaka Univ. J. Pharm. Sci. Vol.3(1-2) 2004 The full text is of this article is available at the Dhaka Univ. J. Pharm. Sci. website

THERMAL CONDUCTIVITY ENHANCEMENT OF MATERIAL FOR CALCIUM CHLORIDE/WATER THERMOCHEMICAL ENERGY STORAGE

2018 ◽  
Author(s):  
Takuma Ohtaki ◽  
Maho Mitsuo ◽  
Takayuki Terauchi ◽  
Hiroshi Iguchi ◽  
Keiko Fujioka ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Calcium Chloride ◽  
Thermal Conductivity Enhancement ◽  
Conductivity Enhancement ◽  
Chloride Water
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