Interactions of a water-soluble polymeric detergent additive (polycarboxylate) with clay minerals from soil

2007 ◽  
pp. 23-29 ◽  
Author(s):  
F. Blockhaus ◽  
J. -M. Séquaris ◽  
H. D. Narres ◽  
M. J. Schwuger
Keyword(s):  
Clay Minerals ◽  
Water Soluble ◽  
Detergent Additive

scholarly journals COMPOSITION, MICROSTRUCTURE AND PROPERTIES OF QUATERNARY CLAYS OF THE PRIKHANKAYSKAYA DEPRESSION (PRIMORYE)

2019 ◽  
Vol 14 (1) ◽  
pp. 20-34
Author(s):  
T. G. RYASHCHENKO ◽  
N. N. UKHOVA ◽  
S. I. SHTELMAKH ◽  
N. I. BELYANINA ◽  
P. S. BELYANIN
Keyword(s):  
Clay Minerals ◽  
Laboratory Data ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Climatic Conditions ◽  
Water Soluble ◽  
Laboratory Studies ◽  
Microstructural Parameters ◽  
Physical Chemical ◽  
Study Results

The article considers the study results of composition, microstructure and physical-chemical properties of the quaternary clays of the Prikhankayskaya depression in district of the lake Khanka (Primorye) on the example of air-dry samples of geological borehole 45-b in the range of 18–62 m. The objective of research was to obtain new information about the properties of widespread clay sediments in this area using geologic-lithological materials and laboratory data. The schematic geologic-lithological column was composed with the selection of various zones in the quaternary clay sediments section and the border with sediments of the Neogene System. The methodological scheme of laboratory studies of clays was proposed. This scheme includes the determination of chemical and microelement composition, clay minerals, contents of carbonates, water-soluble salts, mobile forms of aluminum oxide, humus, as well as microstructural parameters (method «Microstructure») and some physical-chemical properties. Geochemical coefficients (Kz, CIA, CIW, ICV) determined the degree of chemical maturity of clays and confirmed the results of palynological studies reflecting the fluctuations of the climatic conditions of their formation. For the group of toxic microelements for the first time the special indicator (Zc) was calculated. Which was the criterion for a degree of pollution of the clay sediments section. Clay minerals of the quaternary clays are represented by smectite and hydromica. The clear change in the mineral association was found when passing to the Neogene sediments (kaolinite prevails). The method «Microstructure» revealed the aggregated type of clays microstructure, the domination of the particles of coarse dust fraction among the primary (free) particles and the almost complete absence of the particles of fine-grained sand fraction, the participation of various fractions in the composition of aggregates. The variants of the formation of certain types of aggregates (on sizes) in the fluviolacustrine «khankayskiy» clays are presented. Solid part density, water resistance (soaking time), sedimentation volume, plasticity, relative swelling (samples-pastes) were determined using standard methods for clays. By special methods, the cation exchange capacity was measured and the calculated values of the plasticity index were obtained from forecasting formulas using the yield limit. The proposed methodological scheme of complex laboratory studies of clay sediments can be recommended for problematic geologic-lithological and engineering-geological sections.

The adsorption of water-soluble polymers on mica, talc limestone, various clay minerals

1991 ◽  
Vol 59 ◽  
pp. 59-70 ◽  
Author(s):  
S.-H. Chang ◽  
M.E. Ryan ◽  
R.K. Gupta ◽  
B. Swiatkiewicz
Keyword(s):  
Clay Minerals ◽  
Water Soluble ◽  
Water Soluble Polymers ◽  
Soluble Polymers ◽  
Adsorption Of Water

Soil factors affecting the availability of potassium to plants for Western Australian soils: a glasshouse study

Soil Research ◽  
2001 ◽  
Vol 39 (3) ◽  
pp. 611 ◽  
Author(s):  
Y. Pal ◽  
R. J. Gilkes ◽  
M. T. F. Wong
Keyword(s):  
Clay Minerals ◽  
Dry Matter ◽  
Growth Period ◽  
Water Soluble ◽  
Dry Matter Yield ◽  
K Uptake ◽  
Factors Affecting ◽  
Exchangeable K ◽  
Weathering Processes ◽  
K Depletion

A glasshouse experiment was conducted with 41 surface and 8 subsurface soils to measure their potassium (K) supply capacities and K depletion of soils by ryegrass growth for 260 days and harvesting at ~40-day intervals. Dry matter yield ranged from 0.22 g to 25.4 g/kg soil, cumulative K uptake ranged from 0.006 to 1.49 cmol/kg soil, and values of K concentration (%) in the first cut herbage ranged from 0.40% to 5.97%. Some of the light-textured soils were so impoverished in K that symptoms of K deficiency appeared during the first growth period. Water-soluble K + exchangeable K accounted for 43–100% of cumulative K uptake by the ryegrass. Multiple regression analysis indicated that 68% of the variation in dry matter yield and 90% of the variation in K uptake may be predicted by the exchangeable K content of these soils. The 6 harvests of ryegrass extracted only 0.21–12.07% of total K from these soils, which was not sufficient to cause discernible mineralogical changes in most soils. For some soils vermiculite was formed at the expense of illite/mica by K release to plants. For soils containing vermiculite but no other K-bearing clay minerals, vermiculite peaks broadened on K depletion by plants. Major proportions of total K in these soils are present in silicate minerals, yet only minor amounts are released to plants by very slow weathering processes. For soils that do not contain any K bearing clay minerals, very minor amounts of feldspar may have dissolved to release K.

scholarly journals Towards the design of new and improved drilling fluid additives using molecular dynamics simulations

2010 ◽  
Vol 82 (1) ◽  
pp. 43-60 ◽  
Author(s):  
Richard L. Anderson ◽  
H. Christopher Greenwel ◽  
James L. Suter ◽  
Rebecca M. Jarvis ◽  
Peter V. Coveney
Keyword(s):  
Molecular Dynamics ◽  
Clay Minerals ◽  
Computer Simulations ◽  
Large Scale ◽  
Drilling Fluid ◽  
Water Soluble ◽  
Dynamics Simulation ◽  
Drilling Fluids ◽  
Clay Swelling ◽  
Poly Ethylene

During exploration for oil and gas, a technical drilling fluid is used to lubricate the drill bit, maintain hydrostatic pressure, transmit sensor readings, remove rock cuttings and inhibit swelling of unstable clay based reactive shale formations. Increasing environmental awareness and resulting legislation has led to the search for new, improved biodegradable drilling fluid components. In the case of additives for clay swelling inhibition, an understanding of how existing effective additives interact with clays must be gained to allow the design of improved molecules. Owing to the disordered nature and nanoscopic dimension of the interlayer pores of clay minerals, computer simulations have become an increasingly useful tool for studying clay-swelling inhibitor interactions. In this work we briefly review the history of the development of technical drilling fluids, the environmental impact of drilling fluids and the use of computer simulations to study the interactions between clay minerals and swelling inhibitors. We report on results from some recent large-scale molecular dynamics simulation studies on low molecular weight water-soluble macromolecular inhibitor molecules. The structure and interactions of poly(propylene oxide)-diamine, poly(ethylene glycol) and poly(ethylene oxide)-diacrylate inhibitor molecules with montmorillonite clay are studied.

scholarly journals Effect of Rice Straw on Potassium Availability in Illite Containing Soils of Central Plain, Thailand

2021 ◽  
Vol 18 (6) ◽  
Author(s):  
Timtong DARUNSONTAYA ◽  
Wittaya JINDALUANG
Keyword(s):  
Clay Minerals ◽  
Rice Straw ◽  
Soil Samples ◽  
Water Soluble ◽  
K Uptake ◽  
Maximum Increase ◽  
Exchangeable K ◽  
Soil Potassium ◽  
Straw Incorporation ◽  
K Release

Soil potassium (K) in various forms and the effect of rice straw on soil K release were studied in lowland soils containing illite clay minerals. Surface soils of 2 Inceptisols and 2 Alfisols were collected to study. Soil samples were incubated for 120 days with rice straw incorporation at different rates (0, 3,125, 6,250, and 9,375 kg/ha), and various forms of K in soils were determined at various times during the period of incubation. The results showed that the readily available K content (water-soluble K + exchangeable K) of the studied soils increased with the increasing rate of rice straw incorporation. In addition, non-exchangeable K content also increased with the increasing rate of rice straw incorporation by fixation process for all soils. The maximum increase of water-soluble K content of the studied soils was observed on the 4th day of incubation for all treatments, corresponding to the decrease of exchangeable K content at the same time. This result indicated that water-soluble K and exchangeable K were in equilibrium. Changes of non-exchangeable K content during the period of incubation through alternate release and fixation processes were observed monthly. This result suggested that most of the readily available K enhanced by rice straw incorporation would be beneficial for K uptake by the plant.

A Resorcinol-Formaldehyde Resin as an Embedding Material for Electron Microscopy of Membranes

1969 ◽  
Vol 27 ◽  
pp. 328-329 ◽  
Author(s):  
J. G. Robertson ◽  
D. F. Parsons
Keyword(s):  
Electron Microscopy ◽  
Osmium Tetroxide ◽  
Neutral Lipids ◽  
Lipid Extraction ◽  
Water Soluble ◽  
Formaldehyde Resin ◽  
Electron Microscope Autoradiography ◽  
Resorcinol Formaldehyde ◽  
Major Disadvantage ◽  
Cell Organization

The extraction of lipids from tissues during fixation and embedding for electron microscopy is widely recognized as a source of possible artifact, especially at the membrane level of cell organization. Lipid extraction is also a major disadvantage in electron microscope autoradiography of radioactive lipids, as in studies of the uptake of radioactive fatty acids by intestinal slices. Retention of lipids by fixation with osmium tetroxide is generally limited to glycolipids, phospholipids and highly unsaturated neutral lipids. Saturated neutral lipids and sterols tend to be easily extracted by organic dehydrating reagents prior to embedding. Retention of the more saturated lipids in embedded tissue might be achieved by developing new cross-linking reagents, by the use of highly water soluble embedding materials or by working at very low temperatures.

Ferritin Labeled Antibody Staining of Thin Sections

1969 ◽  
Vol 27 ◽  
pp. 420-421
Author(s):  
J. D. McLean ◽  
S. J. Singer
Keyword(s):  
Biological Material ◽  
Water Soluble ◽  
Thin Sections ◽  
Antibody Staining ◽  
Thin Sectioning ◽  
Ultrathin Sections

The successful application of ferritin labeled antibodies (F-A) to ultrathin sections of biological material has been hampered by two main difficulties. Firstly the normally used procedures for the preparation of material for thin sectioning often result in a loss of antigenicity. Secondly the polymers employed for embedding may non-specifically absorb the F-A. Our earlier use of cross-linked polyampholytes as embedding media partially overcame these problems. However the water-soluble monomers used for this method still extract many lipids from the material.

Hydrated form of some clay minerals observed using a film sealed environmental cell

1978 ◽  
Vol 36 (1) ◽  
pp. 72-73
Author(s):  
N. Kohyama ◽  
K. Fukushima ◽  
A. Fukami
Keyword(s):  
Clay Minerals ◽  
Morphological Changes ◽  
Carbon Film ◽  
Electron Microscopic Observation ◽  
Adsorbed Water ◽  
Electron Microscopic ◽  
Hydrated Form ◽  
Thin Carbon ◽  
Environmental Cell ◽  
Thin Carbon Film

Since the interlayer or adsorbed water of some clay minerals are quite easily dehydrated in dried air, in vacuum, or at moderate temperatures even in the atmosphere, the hydrated forms have not been observed by a conventional electron microscope(TEM). Recently, specific specimen chambers, “environmental cells(E.C.),” have been developed and confirmed to be effective for electron microscopic observation of wet specimen without dehydration. we observed hydrated forms of some clay minerals and their morphological changes by dehydration using a TEM equipped with an E.C..The E.C., equipped with a single hole copper-microgrid sealed by thin carbon-film, attaches to a TEM(JEM 7A) with an accelerating voltage 100KV and both gas pressure (from 760 Torr to vacuum) and relative humidity can be controlled. The samples collected from various localities in Japan were; tubular halloysite (l0Å) from Gumma Prefecture, sperical halloysite (l0Å) from Tochigi Pref., and intermediate halloysite containing both tubular and spherical types from Fukushima Pref..

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