Selective incorporation of dyes with fluorocarbon and hydrocarbon chains into coexisting micellar phases of sodium perfluorooctanoate and dimethyl tetradecyl aminoixde

Author(s):  
F. H. Haegel ◽  
H. Hoffmann
Author(s):  
S. W. Hui ◽  
T. P. Stewart

Direct electron microscopic study of biological molecules has been hampered by such factors as radiation damage, lack of contrast and vacuum drying. In certain cases, however, the difficulties may be overcome by using redundent structural information from repeating units and by various specimen preservation methods. With bilayers of phospholipids in which both the solid and fluid phases co-exist, the ordering of the hydrocarbon chains may be utilized to form diffraction contrast images. Domains of different molecular packings may be recgnizable by placing properly chosen filters in the diffraction plane. These domains would correspond to those observed by freeze fracture, if certain distinctive undulating patterns are associated with certain molecular packing, as suggested by X-ray diffraction studies. By using an environmental stage, we were able to directly observe these domains in bilayers of mixed phospholipids at various temperatures at which their phases change from misible to inmissible states.


2017 ◽  
Vol 890 ◽  
pp. 252-259
Author(s):  
Le Wang ◽  
Guan Cheng Jiang ◽  
Xin Lin ◽  
Xian Min Zhang ◽  
Qi Hui Jiang

Molecular dynamics simulations are used to study the dissociation inhibiting mechanism of lecithin for structure I hydrates. Adsorption characteristics of lecithin and PVP (poly (N-vinylpyrrolidine)) on the hydrate surfaces were performed in the NVT ensemble at temperatures of 277K and the hydrate dissociation process were simulated in the NPT ensemble at same temperature. The results show that hydrate surfaces with lecithin is more stable than the ones with PVP for the lower potential energy. The conformation of lecithin changes constantly after the balanced state is reached while the PVP molecular dose not. Lecithin molecule has interaction with lecithin nearby and hydrocarbon-chains of lecithin molecules will form a network to prevent the diffusion of water and methane molecules, which will narrow the available space for hydrate methane and water movement. Compared with PVP-hydrate simulation, analysis results (snapshots and mass density profile) of the dissociation simulations show that lecithin-hydrate dissociates more slowly.


1985 ◽  
Vol 6 (4) ◽  
pp. 389-400 ◽  
Author(s):  
Yukihiko Aramaki ◽  
Asaichi Inaba ◽  
Seishi Tsuchiya

2007 ◽  
Vol 35 (15) ◽  
pp. 5154-5164 ◽  
Author(s):  
Daniela Castanotto ◽  
Kumi Sakurai ◽  
Robert Lingeman ◽  
Haitang Li ◽  
Louise Shively ◽  
...  

2012 ◽  
Vol 102 (3) ◽  
pp. 413a
Author(s):  
Walter E. Teague ◽  
Olivier Soubias ◽  
Nola L. Fuller ◽  
R. Peter Rand ◽  
Klaus Gawrisch

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