Conformational investigation on retinal by PCILO method

1981 ◽  
Vol 90 (6) ◽  
pp. 485-495
Author(s):  
M M Dhingra ◽  
Anil Saran
1982 ◽  
Vol 47 (7) ◽  
pp. 1884-1892
Author(s):  
A. N. Abdel Rahman ◽  
S. Abdel Rahman

Tetra- and hexapeptides containing Pro-Gly or Gly-Pro or Aib-Pro in their sequences were synthesized using the liquid-phase method. The high solubility of the poly(ethylene glycol) bound peptides in water and in organic solvents enables the application of the singlet-singlet energy transfer method for conformational investigation of these peptides. The conformational study in solid state by IR and in solution by CD were carried out in parallel to the energy transfer method. The qualitative results generated by IR and CD were found to be in good agreement with the quantitative end-to-end distances given by the energy transfer method.


1996 ◽  
Vol 37 (12) ◽  
pp. 2015-2018 ◽  
Author(s):  
Nicolas Vivas ◽  
Yves Glories ◽  
Isabelle Pianet ◽  
Bernard Barbe ◽  
Michel Laguerre

1984 ◽  
Vol 62 (1) ◽  
pp. 6-10 ◽  
Author(s):  
E. R. Maia ◽  
A. Péguy ◽  
S. Pérez

N,N-Dimethyl ethanolamine N-oxide (DMEAO) belongs to the class of tertiary amine oxide molecules that are good solvents for cellulose, although not being cyclic. Crystallographic investigation shows that anhydrous DMEAO is monoclinic, space group Cc, a = 25.725(9), b = 7.023(4), c = 9.483(5) Å, β = 101.16(10)°, Z = 12. The crystal structure has been solved by direct methods and refined to a final R value of 0.063 for 575 observed reflexions. Three independent molecules are found within the asymmetric unit; one of these displays a pseudo-cyclic form dictated by the occurrence of a strong intramolecular hydrogen bond. Conformational investigation of DMEAO in solution, using ir and nmr spectroscopy shows that this pseudo-cyclic form is more likely to occur in diluted states. These findings are related to the ability of this tertiary amine oxide to act as a good solvent, up to a water content of one water molecule per DMEAO molecule.


2009 ◽  
Vol 39 (3) ◽  
pp. 218-222 ◽  
Author(s):  
EWA CISZAK ◽  
GRZEGORZ PIETRZYÑSKI ◽  
BARBARA RZESZOTARSKA

Biopolymers ◽  
1980 ◽  
Vol 19 (12) ◽  
pp. 2165-2175 ◽  
Author(s):  
Cyrille Rochas ◽  
Marguerite Rinaudo ◽  
Marc Vincendon

1994 ◽  
Vol 326 ◽  
pp. 17-24 ◽  
Author(s):  
S.B. Bulgarevich ◽  
N.A. Ivanova ◽  
D.Ya. Movshovich ◽  
A. Mannschreck ◽  
C. Kiefl

Tetrahedron ◽  
2004 ◽  
Vol 60 (40) ◽  
pp. 8929-8936 ◽  
Author(s):  
Lígia M. Rodrigues ◽  
José I. Fonseca ◽  
Hernâni L.S. Maia

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