scholarly journals Substituent effects on carbon-13 NMR chemical shifts of side chain carbonyl carbons of 4-substituted 1-naphthamides

1987 ◽  
Vol 98 (3) ◽  
pp. 207-212
Author(s):  
K Rajasekaran ◽  
C Gnanasekaran ◽  
T C Wong
Keyword(s):  
Chemical Shifts ◽  
Substituent Effects ◽  
Side Chain ◽  
Nmr Chemical Shifts ◽  
Substituted 1

Die Weiterleitung von substituenten- induzierten 13C-NMR-chemischen. Verschiebungen in para-substituierten 3-Phenylpropansäure-methylestern / The Transmission of Substituent-Induced 13C NMR Chemical Shifts in para-Substituted 3-Phenyl Propanoic Acid Methyl Esters

1980 ◽  
Vol 35 (7) ◽  
pp. 934-936 ◽  
Author(s):  
R. Radeglia ◽  
S. L. Spassov ◽  
R. Stefanova ◽  
S. D. Sofia
Keyword(s):  
13C Nmr ◽  
Chemical Shifts ◽  
Methyl Esters ◽  
Substituent Effects ◽  
Side Chain ◽  
Parameter Method ◽  
Propanoic Acid ◽  
Nmr Chemical Shifts ◽  
13C Nmr Chemical Shifts ◽  
Acid Methyl

Carbon-13 chemical shifts have been measured of para-substituted 3-phenyl propanoic acid methyl esters. The substituent-induced 13C shifts of the side chain were related to Hammett substituent effects by the dual substituent parameter method. The transmission of substituent effects and the factors that influence 13C shifts are discussed

Substituent effects in fluoromethylnaphthalenes by 19F nuclear magnetic resonance

1981 ◽  
Vol 59 (17) ◽  
pp. 2642-2649 ◽  
Author(s):  
Elisabeth A. Dixon ◽  
Alfred Fischer ◽  
Frank P. Robinson
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Aromatic Ring ◽  
Chemical Shifts ◽  
Substituent Effects ◽  
Resonance Interaction ◽  
Parameter Analysis ◽  
Side Chain ◽  
Temperature Dependent ◽  
Substituted 1 ◽  
Electron Withdrawing Substituents

19F substituent chemical shifts (SCS) are reported for a series of twenty-one 3- and 4-substituted 1-fluoromethylnaphthalenes. The fluoromethylnaphthalenes exhibit an inverse SCS dependence: electron-withdrawing substituents produce upfield shifts. The results correlate well with SCS values previously reported for substituted benzyl fluorides. Hammett correlations are poor with conjugatively electron-withdrawing substituents exhibiting weaker than expected effects in the 3-position and stronger than expected effects in the 4-position. Dual substituent parameter analysis confirms the enhanced substituent–aromatic ring resonance interaction when the substituent is in the 4-position (ρR/ρI = 2). There is no evidence for enhanced resonance interaction between fluoromethyl side-chain and aromatic ring. The 19F chemical shift of 1-fluoromethylnaphthalene is markedly temperature dependent.

Substituent Effects on 31P NMR Chemical Shifts and 1JP–Se of triarylselenophosphates

2010 ◽  
Vol 185 (4) ◽  
pp. 772-784 ◽  
Author(s):  
Zaira Domínguez ◽  
Javier Hernández ◽  
Lorena Silva-Gutiérrez ◽  
Magali Salas-Reyes ◽  
Mario Sánchez ◽  
...  
Keyword(s):  
31P Nmr ◽  
Chemical Shifts ◽  
Substituent Effects ◽  
Nmr Chemical Shifts

scholarly journals Substituenteneinflüsse auf die 13C–NMR-chemischen Verschiebungen cis- und trans-konfigurierter Trimethincyanine / Substituent Effects on the 13C NMR Chemical Shifts of Trimethincyanines with cis and trans Configuration

1976 ◽  
Vol 31 (12) ◽  
pp. 1641-1645 ◽  
Author(s):  
Walter Grahn
Keyword(s):  
13C Nmr ◽  
Chemical Shifts ◽  
Substituent Effects ◽  
Electron Systems ◽  
Coupling Constant ◽  
Electronic Effects ◽  
Nmr Chemical Shifts ◽  
Monosubstituted Benzenes ◽  
Cis And Trans ◽  
C Nmr

The 13C NMR chemical shifts of fifteen 6 substituted 2,3-dihydro-1,4-diazepinium salts (cis trimethincyanines) (1) and twelve 2 substituted bis(dimethylamino)trimethinium salts (trans trimethincyanines) (2) have been determined. A comparison of the substituentinduced shifts (13C SCS) of 1 and 2 allows no distinction between steric and electronic effects. In the three 6 п-electron systems 1, 2 and monosubstituted benzenes the 13C SCS are similar for the substituent bearing carbon atoms. A surprisingly large 4JFCCNC coupling constant has been observed.

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