Fluorescence quantum yield of rhodamine 6G using pulsed photoacoustic technique

Pramana ◽  
1990 ◽  
Vol 34 (6) ◽  
pp. 585-590 ◽  
Author(s):  
P Sathy ◽  
Reji Philip ◽  
V P N Nampoori ◽  
C P G Vallabhan
1999 ◽  
Vol 13 (16) ◽  
pp. 563-576 ◽  
Author(s):  
C. V. BINDHU ◽  
S. S. HARILAL ◽  
V. P. N. NAMPOORI ◽  
C. P. G. VALLABHAN

Dual beam thermal lens technique is successfully employed for the determination of absolute fluorescence quantum yield of rhodamine 6G laser dye in different solvents. A 532 nm radiation from a Q-switched Nd:YAG laser was used for the excitation purpose. The fluorescence quantum yield values are found to be strongly influenced by environmental effects. It has been observed that fluorescence yield is greater for rhodamine 6G in ethylene glycol system than in water or in methanol. Our results also indicate that parameters like concentration of the dye solution, aggregate formation and excited state absorption affect the absolute values of fluorescence yield significantly.


2019 ◽  
Vol 2019 ◽  
pp. 1-5 ◽  
Author(s):  
Suwaphit Phoemphoonthanyakit ◽  
Panpailin Seeharaj ◽  
Pattareeya Damrongsak ◽  
Kitsakorn Locharoenrat

In this work, the use of Fe3O4 magnetic nanoparticles in the adsorption of rhodamine 6G solution was evaluated via absorbance and fluorescence spectroscopy using the UV-Vis spectrometer. The adsorption mechanism of rhodamine 6G on Fe3O4 was determined with respect to the adsorbent dosage (2.5–10 mg/L) and treatment time (0–150 min). The experimental data revealed that the fluorescence quantum yield of rhodamine 6G was inversely proportional to the percentage of dye removal. The highest efficiency of dye removal was obtained at 10 mg/L Fe3O4, and the adsorption capacity was about 150 mg/g, together with a reduced treatment time of 30 min, owing to active adsorption of Fe3O4. We believe that our study makes a significant contribution to the literature because Fe3O4 magnetic nanoparticles were found to be able to quench rhodamine 6G dye molecules, which will aid in eliminating toxic and hazardous pollutants from dye wastewater, which are otherwise detrimental to the environment and human health.


1987 ◽  
Vol 42 (12) ◽  
pp. 1451-1455 ◽  
Author(s):  
C. Bojarski ◽  
G. Żurkowska

In the system rhodamine 6G (donor)/rhodamine B (acceptor) the reverse energy transfer considerably increases the donor fluorescence quantum yield, particularly in the high concentration region. These experimental results confirm a theoretical model with no adjustable parameters.


1996 ◽  
Vol 50 (12) ◽  
pp. 1505-1511 ◽  
Author(s):  
J. Georges ◽  
N. Arnaud ◽  
L. Parise

The high incident irradiances available with pulsed lasers can lead to a significant depletion of the ground-state population of the chromophore and to optical saturation effects. As a result, the optical absorption coefficient decreases as a function of the excitation energy and, because the amount of energy released by radiative and nonradiative relaxation processes depends on the amount of energy absorbed, nonlinear energy-dependent signals are obtained. Therefore, large errors can be introduced when fluorescence and photothermal data are used to determine fluorescence quantum yields. This work provides experimental results describing the effects of optical saturation on fluorescence and thermal lens measurements for rhodamine 6G in various media and over a wide energy range. It is shown that, when optical saturation is avoided, the photothermal method gives accurate absolute values of Φf ranging from 0.93 to 0.95, depending on the solvent. On the contrary, fluorescence measurements seem to be sensitive to additional experimental artifacts that are more difficult to characterize and to eliminate. Index Headings: Optical saturation; Thermal lens spectrometry; Fluorescence; Rhodamine 6G; Fluorescence quantum yield.


Talanta ◽  
2012 ◽  
Vol 90 ◽  
pp. 30-37 ◽  
Author(s):  
Christian Würth ◽  
Martín G. González ◽  
Reinhard Niessner ◽  
Ulrich Panne ◽  
Christoph Haisch ◽  
...  

2021 ◽  
Vol 2 (18) ◽  
pp. 6083-6093
Author(s):  
Yuto Miyake ◽  
Goichiro Seo ◽  
Kotaro Matsuhashi ◽  
Noriyuki Takada ◽  
Kaname Kanai

Melem tetramer, the newly synthesized carbon nitride compound is composed of oligomers with four melem units, is stable in air, and has improved optical properties compared to melon.


Nanoscale ◽  
2021 ◽  
Author(s):  
Parinaz Fathi ◽  
Ayman Roslend ◽  
Kritika Mehta ◽  
Parikshit Moitra ◽  
Kai Zhang ◽  
...  

Increasing the fluorescence quantum yield of fluorophores is of great interest for in vitro and in vivo biomedical imaging applications. At the same time, photobleaching and photodegradation resulting from continuous...


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