scholarly journals Mechanisms of stress corrosion cracking and intergranular attack in alloy 600 in high temperature caustic and pure water

1985 ◽  
Vol 7 (3) ◽  
pp. 237-245 ◽  
Author(s):  
R. Bandy ◽  
D. Vanrooyen
CORROSION ◽  
2004 ◽  
Vol 60 (3) ◽  
pp. 229-236 ◽  
Author(s):  
M. Yamamoto ◽  
J. Kuniya ◽  
S. Uchida

Abstract Uniaxial constant load (UCL) tests of the nickel-based alloy X750 (UNS N07550) were performed in high-temperature pure water (288°C, 8 ppm dissolved oxygen [DO]) to investigate stress corrosion cracking (SCC) fracture time and the crack initiation process. The SCC fracture was initiated at a stress level below the 0.2% offset yield stress and many small cracks were observed in the middle of the nonfractured test specimens. The distribution of the crack length for each observation time is shown by Weibull probability distributions. Crack initiation and propagation process had different behavior depending on the applied stress level and the stress intensity factor at the crack tip. SCC initiation at the minimum applied stress is discussed with respect to the grain size, which depended on the size of an initial crack.


CORROSION ◽  
1977 ◽  
Vol 33 (1) ◽  
pp. 20-26 ◽  
Author(s):  
G. J. THEUS

Abstract Modified Streicher and 288 C (550 F) electrochemical caustic stress corrosion tests were performed on Alloy 600 to determine the relationship between acid intergranular attack susceptibility and caustic stress corrosion cracking (SCC) susceptibility. Mill annealed and solution annealed materials with and without a subsequent 621 C (1150 F) heat treatment (simulated stress relief) were evaluated. Susceptibility to attack in the Streicher test was greatest for material that had received a 621 C (1150 F) heat treatment, whereas this heat treatment caused the same material to be least susceptible to cracking in the electrochemical tests. The conclusions drawn from these results are: (1) stress relieving Alloy 600 does improve its resistance to caustic SCC, and (2) resistance of Alloy 600 to acid intergranular attack does not imply resistance of Alloy 600 to caustic SCC. Therefore, the results demonstrate the need for selecting corrosion qualification tests which are relevant to service conditions.


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