Reactions of tertiary butyl hypochlorite with vegetable oils and their derivatives. V. Dechlorination of chlorinated soybean oil with aqueous solutions of salts

1952 ◽  
Vol 29 (9) ◽  
pp. 367-370 ◽  
Author(s):  
H. M. Teeter ◽  
R. A. Myren
Keyword(s):  
Aqueous Solutions ◽  
Soybean Oil ◽  
Vegetable Oils ◽  
Tertiary Butyl

Motions of water molecules in dilute aqueous solutions of tertiary butyl alcohol; a neutron scattering study of hydrophobic hydration

1970 ◽  
Vol 319 (1537) ◽  
pp. 189-208 ◽  
Keyword(s):  
Aqueous Solutions ◽  
Water Structure ◽  
Hydrophobic Hydration ◽  
Step Length ◽  
Solute Concentration ◽  
Butyl Alcohol ◽  
Tertiary Butyl ◽  
Self Diffusion ◽  
Dilute Aqueous Solutions ◽  
Neutron Scattering Study

Cold neutron inelastic scattering experiments have been performed on dilute aqueous solutions of (CD 3 ) 3 COH and of solutions of (CH 3 ) 3 COH in D 2 O at 21 °C. From the broadening of the quasi-elastic peak and independently determined self-diffusion coefficients ( D ), diffusive lifetimes ( c ) of H 2 O molecules have been calculated as functions of solute concentration. The product Dc is insensitive to concentration, giving a mean diffusion step length of 0.14 nm. The inelastic portion of the spectrum, reflecting lattice-like hydrogen bonding modes indicates that the solute enhances the water ‘structure’ but that such structure bears no resemblance to ice.

scholarly journals Heating of Plant Oils-Fatty Acid Reactions versus Tocopherols Degradation

2009 ◽  
Vol 27 (Special Issue 1) ◽  
pp. S185-S187 ◽  
Author(s):  
Z. Réblová ◽  
D. Tichovská ◽  
M. Doležal
Keyword(s):  
Fatty Acid ◽  
Soybean Oil ◽  
Olive Oil ◽  
Vegetable Oils ◽  
Sunflower Oil ◽  
Rapeseed Oil ◽  
Degradation Rate ◽  
Plant Oils ◽  
Oil Sunflower ◽  
High Degradation Rate

Relationship between polymerised triacylglycerols formation and tocopherols degradation was studied during heating of four commercially accessible vegetable oils (rapeseed oil, classical sunflower oil, soybean oil and olive oil) on the heating plate with temperature 180°C. The content of polymerised triacylglycerols 6% (i.e. half of maximum acceptable content) was achieved after 5.3, 4.2, 4.1, and 2.6 hours of heating for olive oil, soybean oil, rapeseed oil and sunflower oil, respectively, while decrease in content of total tocopherols to 50% of the original content was achieved after 3.4, 1.6, 1.3, and 0.5 hours of heating for soybean oil, rapeseed oil, sunflower oil and olive oil, respectively. Because of the high degradation rate of tocopherols, decrease in content of total tocopherols to 50% of the original content was achieved at content of polymerised triacylglycerols 0.6%, 1.9%, 2.8% and 4.9% for olive oil, rapeseed oil, sunflower oil and soybean oil, respectively, i.e. markedly previous to the frying oil should be replaced.

scholarly journals Optimization of Base Catalyzed Ethanolysis of Vegetable Oils in Microreactors Using Design of Experiments

2020 ◽  
Vol 10 (5) ◽  
pp. 1624
Author(s):  
Ekaterina Borovinskaya ◽  
Eva Ritter ◽  
Wladimir Reschetilowski
Keyword(s):  
Design Of Experiments ◽  
Soybean Oil ◽  
Vegetable Oils ◽  
Flow Rate ◽  
Positive Impact ◽  
Batch Reactor ◽  
Waste Cooking Oil ◽  
Reaction Systems ◽  
Cooking Oil ◽  
Continuous Reaction

The base-catalyzed ethanolysis of soybean oil and waste cooking oil (WCO) was investigated in two types of continuous reactors (microreactor and T-mixer) and in a batch reactor. Flow rate, ethanol/oil ratio and concentration of catalyst were varied according to the design of experiments in continuous reaction systems. Regression analysis was carried out concerning the obtained product yields. Based on this analysis optimal conditions in different reactors types with soybean oil, fresh and WCO were determined. While the increased flow rate was unfavorable in the MX-mixer, it contributed to a great positive impact in the T-mixer system at flow rates higher than 2.2 mL/min. The soybean oil provides a slightly lower yield maximum (96.7%) than the fresh cooking oil (97.9%) and the waste cooking oil (97.5%). Therefore, the mix of vegetable oils in the cooking oil is more suitable for ethanolysis reaction than the soybean oil.

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