Gas-Liquid chromatography of fatty derivatives. I. Separation of homologous series ofa-olefins, n-hydrocarbons, n-nitriles, and n-alcohols

1959 ◽  
Vol 36 (1) ◽  
pp. 20-23 ◽  
Author(s):  
W. E. Link ◽  
H. M. Hickman ◽  
R. A. Morrissette
Keyword(s):  
Liquid Chromatography ◽  
Homologous Series ◽  
Gas Liquid Chromatography

Gas-liquid chromatography of saturated fluorinated carboxylic acid esters 1. Retention in homologous series

1991 ◽  
Vol 40 (2) ◽  
pp. 359-365
Author(s):  
E. P. Promyshlennikova ◽  
V. E. Kirichenko ◽  
K. I. Pashkevich ◽  
D. N. Grigor'eva ◽  
R. V. Golovnya
Keyword(s):  
Liquid Chromatography ◽  
Carboxylic Acid ◽  
Homologous Series ◽  
Gas Liquid Chromatography ◽  
Acid Esters

Paraffins of Cigar Smoke

1965 ◽  
Vol 48 (5) ◽  
pp. 1059-1062
Author(s):  
S Osman ◽  
J Barsox ◽  
C J Dooley
Keyword(s):  
Liquid Chromatography ◽  
Column Chromatography ◽  
Infrared Spectra ◽  
Homologous Series ◽  
Mass Spectra ◽  
Chromatographic Behavior ◽  
Gas Liquid Chromatography ◽  
The Individual ◽  
Individual Hydrocarbons

Abstract Column chromatography was used to isolate a fraction from cigar smoke condensate containing a homologous series of normal paraffinic hydrocarbons; the individual hydrocarbons were separated by gas-liquid chromatography and characterized by their infrared spectra, mass spectra, and gas chromatographic behavior. Those compounds identified include the normal paraffins from dodecane to pentacosane. This fraction was isolated from the smoke condensates of four cigar types containing unblended filler tobacco that varied considerably in smoking characteristics. Qualitatively, the four types were identical, but quantitative differences were observed.

A study of asphalt-aggregate interactions using inverse gas-liquid chromatography

1974 ◽  
Vol 24 (11) ◽  
pp. 645-654 ◽  
Author(s):  
F. Alan Barbour ◽  
Richard V. Barbour ◽  
J. Claine Peterson
Keyword(s):  
Liquid Chromatography ◽  
Gas Liquid Chromatography

GASCHROMATOGRAPHIC DETERMINATION OF STEROIDS IN THE URINE OF PATIENTS WITH CUSHING'S SYNDROME

1971 ◽  
Vol 67 (2) ◽  
pp. 303-315 ◽  
Author(s):  
A. J. Moolenaar ◽  
A. P. van Seters
Keyword(s):  
Liquid Chromatography ◽  
Cushing’S Syndrome ◽  
Normal Subjects ◽  
Diagnostic Value ◽  
Cushing's Syndrome ◽  
Gas Liquid Chromatography ◽  
Obese Subjects

ABSTRACT The 17-oxosteroids were estimated in the urine of 27 patients with Cushing's syndrome by gas-liquid chromatography (G. L. C.). The values of the various steroid fractions are compared with those of normal subjects, patients with thyrotoxicosis and obese subjects. The effect of the age of the patients on the diagnostic value of the invidual 17-oxosteroids and their ratios is discussed.

Simultaneous Determination of Lactulose and Mannitol in Urine of Burn Patients by Gas-Liquid Chromatography

1992 ◽  
Author(s):  
Ronald L. Shippee ◽  
Avery A. Johnson ◽  
William G. Cioffi ◽  
James Lasko ◽  
Thomas E. LeVoyer
Keyword(s):  
Liquid Chromatography ◽  
Simultaneous Determination ◽  
Gas Liquid Chromatography ◽  
Burn Patients

Obtaining and Characterization of Alhagi persarum Boiss. et Buhse Callus Cell Cultures, Isoflavonoid Producers

2020 ◽  
Vol 36 (6) ◽  
pp. 35-48
Author(s):  
D.V. Коchkin ◽  
G.I. Sobolkovа ◽  
А.А. Fоmеnkov ◽  
R.А. Sidorov ◽  
А.М. Nоsоv
Keyword(s):  
Fatty Acids ◽  
Cell Culture ◽  
Liquid Chromatography ◽  
Secondary Metabolites ◽  
Cell Cultures ◽  
Mass Spectrometric ◽  
Mass Spectrometric Detection ◽  
Gas Liquid Chromatography ◽  
Callus Cell

The physiological characteristics of the callus cell cultures of Alhagi persarum Boiss et Buhse, a member of the legume family, widely used in folk medicine, have been studied. It was shown that the source of the explant was an important factor in the initiation of callusogenesis: more intense callusogenesis (almost 100%) was observed for explants from various organs of sterile seedlings, rather than intact plants (less than 30%). As a result, more than 20 lines of morphologically different callus cell cultures were obtained, and the growth parameters for the 5 most intensively growing lines were determined. The composition of fatty acids (FA) of total lipids and secondary metabolites in the most physiologically stable callus line Aр-207 was analyzed. Using capillary gas-liquid chromatography with mass spectrometric detection (GLC-MS), 19 individual C12--C24 FAs were identified, the main fraction of which were palmitic (~ 23%), stearic (~ 22%), linoleic (~ 14%) and α-linolenic (~ 33%) acids. The established atypical ratio of FAs (a simultaneous high content of both saturated FAs and polyunsaturated α-linolenic acid) is possibly due to the adaptation of cells to in vitro growth conditions. Phytochemical analysis of the secondary metabolites was carried out using ultra-performance liquid chromatography with electrospray ionization mass spectrometric detection (UPLC MS). Compounds belonging to different structural groups of isoflavones were found. Aglycones (calycosin, formononetin and afrormosin isomer), glucosides (formononetin glucoside), as well as esters of glucosides (malonylglycosides of calicosin, formononetin, afrormosin isomers, glycitein and genistein) were detected. These secondary metabolites are widespread in plants of the Fabaceae family; however, isoflavones are rare in representatives of the Alhagi genus. The presence of malonylated isoflavone glycosides in Alhagi spp. was shown for the first time. endemic plant species, Alhagi, in vitro cell culture, callus cell culture, isoflavones, fatty acids All studies were carried out using the equipment of the "Experimental Biotechnological Facility" and the "All-Russian Collection of Cell Cultures of Higher Plants" of IРР RAS. This work was supported by the Russian Foundation for Basic Research (RFBR), contract no.18-54-06021 (Az_a), and the Government of the Russian Federation, Megagrant Project no. 075-15-2019-1882.

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