Preparation and properties ofgem-dichlorocyclopropane derivatives of long-chain fatty esters

Lipids ◽  
1992 ◽  
Vol 27 (1) ◽  
pp. 59-64 ◽  
Author(s):  
Marcel S. F. Lie Ken Jie ◽  
C. F. Wong
Keyword(s):  
Fatty Esters ◽  
Derivatives Of ◽  
Long Chain

scholarly journals Structural and Solubility Parameter Correlations of Gelation Abilities for Dihydroxylated Derivatives of Long-Chain, Naturally Occurring Fatty Acids

2015 ◽  
Vol 21 (23) ◽  
pp. 8530-8543 ◽  
Author(s):  
Mohan Zhang ◽  
Sermadurai Selvakumar ◽  
Xinran Zhang ◽  
Mukund P. Sibi ◽  
Richard G. Weiss
Keyword(s):  
Fatty Acids ◽  
Solubility Parameter ◽  
Naturally Occurring ◽  
Derivatives Of ◽  
Long Chain

Synthesis and spreading behaviour of some reactive derivatives of long-chain alcohols and carboxylic acids

1984 ◽  
Vol 62 (3) ◽  
pp. 574-579 ◽  
Author(s):  
David A. Holden
Keyword(s):  
Mass Spectrometry ◽  
Fatty Acids ◽  
Surface Activity ◽  
Azo Compounds ◽  
Single Chain ◽  
Bulk Solid ◽  
Potential Applications ◽  
Curing Agents ◽  
Derivatives Of ◽  
Long Chain

Procedures are described for the synthesis of several azides, diimides, and azodiformates from long-chain alcohols and fatty acids. These reactive compounds have potential applications as thermal and photochemical curing agents, and as surface-modifying agents for the preparation of filled plastics and chromatographic packings. The surface activity of the compounds was characterized by investigations of their spreading behaviour in monolayers on water. Unlike the single-chain azides and azo compounds, which give well-defined monolayers at all temperatures, monolayers of diacyl diimides and dialkyl azodiformates with two long-chain substituents are unstable with respect to collapse to the bulk solid. The photoreaction of monolayers of octadecanoyl azide to give a mixture of products derived from an intermediate isocyanate was demonstrated by ir and mass spectrometry.

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