Bimetallic alkoxides of barium and zirconium: Preparation of BaZrO3 powder

1997 ◽  
Vol 8 (1-3) ◽  
pp. 111-115
Author(s):  
E. P. Turevskaya ◽  
D. V. Berdyev ◽  
N. Ya. Turova
Keyword(s):  
Bimetallic Alkoxides

ChemInform Abstract: Bimetallic Alkoxides of Zinc and Aluminum.

ChemInform ◽  
1988 ◽  
Vol 19 (30) ◽  
Author(s):  
M. AGGRAWAL ◽  
R. C. MEHROTRA
Keyword(s):  
Bimetallic Alkoxides

Bimetallic alkoxides of niobium

Polyhedron ◽  
1995 ◽  
Vol 14 (12) ◽  
pp. 1531-1542 ◽  
Author(s):  
E.P. Turevskaya ◽  
N.Ya. Turova ◽  
A.V. Korolev ◽  
A.I. Yanovsky ◽  
Yu.T. Struchkov
Keyword(s):  
Bimetallic Alkoxides

Bimetallic alkoxides of aluminium-hafnium and aluminium-zirconium. X-ray structure of Al2Hf(OPri)10

Polyhedron ◽  
1997 ◽  
Vol 16 (4) ◽  
pp. 663-670 ◽  
Author(s):  
E.P. Turevskaya ◽  
D.V. Berdyev ◽  
N.Ya. Turova ◽  
Z.A. Starikova ◽  
A.I. Yanovsky ◽  
...  
Keyword(s):  
X Ray ◽  
Bimetallic Alkoxides

Bimetallic Alkoxides of Nickel(II) with Niobium(V) and Tantalum(V)

1985 ◽  
Vol 40 (10) ◽  
pp. 1371-1376 ◽  
Author(s):  
R. Jain ◽  
A. K. Rai ◽  
R. C. Mehrotra
Keyword(s):  
Molecular Weight ◽  
Nickel Chloride ◽  
Reflectance Spectroscopy ◽  
Octahedral Geometry ◽  
Molar Ratio ◽  
New Class ◽  
Elemental Analyses ◽  
Visible Reflectance ◽  
Bimetallic Alkoxides ◽  
Interchange Reactions

A new class of bimetallic isopropoxides of nickel(II) with niobium and tantalum with the general formula, Ni[M(OPri)6]2, (where M = Nb or Ta) have been synthesized by the reaction of nickel chloride isopropanolate, NiCl2·ϰPriOH, with potassium hexaisopropoxy metalates, KM(OPri)6, (M = Nb or Ta) in the molar ratio 1:2. These derivatives have been characterized by elemental analyses, molecular weight determinations, infrared and visible reflectance spectroscopy in addition to magnetic susceptibility measurements. Alcohol interchange reactions of these bimetallic alkoxides have also been studied. On the basis of above studies, an octahedral geometry has been assigned to Ni(II) in primary bimetallic alkoxides while in secondary derivatives, it appears that there exists an equilibrium between octahedral and tetrahedral forms.

Preparation Of Single-Phase Knbo3, Using Bimetallc Alkoxides

1990 ◽  
Vol 180 ◽  
Author(s):  
Mostafa M. Amini ◽  
Michael D. Sacks
Keyword(s):  
Thin Films ◽  
Single Phase ◽  
Methanol Solution ◽  
Multiphase Material ◽  
Niobium Ethoxide ◽  
Bimetallic Alkoxides ◽  
Hydrolysis Of ◽  
Propanol Solution

ABSTRACTSingle-phase KNbO3 was prepared using bimetallic alkoxides. Potassium-niobium ethoxide, KNb(OC2H5)6, and potassium-niobium propoxide, KNb(OC3H7)6, were synthesized and subsequently hydrolyzed using several water concentrations. Potassium-deficient particles were rapidly precipitated when higher water concentrations were used and this resulted in the formation of a multiphase material after calcination. In contrast, single-phase KNbO3 powders could be prepared by two methods: (1) hydrolysis of KNb(OC3H7)6/propanol solutions using 1 mole water (per mole of propoxide) added as a water/propanol solution and (2) hydrolysis of KNb(OC2H5)6,/ethanol solutions using 1 mole of water (per mole of ethoxide) added as a water/methanol solution. The latter method was also used to form thin films of KNbO3.

ChemInform Abstract: Synthesis and Properties of Bimetallic Alkoxides of Trivalent Titanium.

ChemInform ◽  
1988 ◽  
Vol 19 (48) ◽  
Author(s):  
L. I. VYSHINSKAYA ◽  
V. V. DROBOTENKO ◽  
T. P. SAMARINA
Keyword(s):  
Bimetallic Alkoxides ◽  
Trivalent Titanium
Sign in / Sign up

Export Citation Format

Share Document