Extraction of Hg/II/ with dibutylester of N-/4-antipyryl/-amidophosphoric acid from iodide solutions

1984 ◽  
Vol 86 (1) ◽  
pp. 11-17 ◽  
Author(s):  
J. Příhoda ◽  
A. Zeman
Keyword(s):  
Amidophosphoric Acid

ChemInform Abstract: N-Alkyl-N-(alkoxycarbonyl)amidophosphoric Acid Chlorides and Isocyanates.

ChemInform ◽  
1989 ◽  
Vol 20 (31) ◽  
Author(s):  
N. K. MIKHAILYUCHENKO ◽  
B. N. KOZHUSHKO ◽  
V. A. SHOKOL
Keyword(s):  
Acid Chlorides ◽  
Amidophosphoric Acid

scholarly journals Bildung von Diammoniumdihydrogendiphosphat durch spontane Kondensation der Amidophosphorsaure in waBriger Losung / Formation of Diphosphate from Amidophosphoric Acid in Aqueous Solution

1984 ◽  
Vol 39 (1) ◽  
pp. 121-122 ◽  
Author(s):  
Fritz Seel ◽  
Norbert Klein
Keyword(s):  
Aqueous Solution ◽  
Saturated Solution ◽  
Amidophosphoric Acid

A nearly saturated solution of amidophosphoric acid in water hydrolyses to yield diammonium diphosphate. This reaction provides a diphosphate synthesis in water starting with a solution of N- methylcarbamoylphosphate which is readily ob­tained through the action of methylisocyanate upon the aqueous solution of a hydrogenphosphate.

Three new amidophosphoric acid esters with a P(O)[OCH2C(CH3)2CH2O] segment: X-ray diffraction, DFT, AIM and Hirshfeld surface investigations of bi- and tri-furcated (three and four-center) hydrogen bond interactions

2020 ◽  
Vol 235 (3) ◽  
pp. 69-84 ◽  
Author(s):  
Marjan Sadat Bozorgvar ◽  
Atekeh Tarahhomi ◽  
Arie van der Lee
Keyword(s):  
Hydrogen Bond ◽  
Crystal Packing ◽  
Closed Shell ◽  
Hirshfeld Surface ◽  
Asymmetric Unit ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrogen Bond Interactions ◽  
Amidophosphoric Acid ◽  
Acid Esters

AbstractStructural and packing features of three new amidophosphoric acid esters having a common part XP(O)[OCH2C(CH3)2CH2O], with X = [(CH3)3CNH] (1), [(CH3)2HCNH] (2) and [C6H11(CH3)N] (3), are investigated by single crystal X-ray diffraction. The results illustrate that the compounds 1 and 3 crystallize with one independent molecule in the asymmetric unit; whereas, for 2, the compound crystallizes with three independent molecules in the asymmetric unit. The crystal structures are mostly stabilized via tri-furcated hydrogen bond interactions (C–H · · ·)2(N–H · · ·)O=P in 1 and (C–H · · ·)3O=P in 3, while the stability is given by bi-furcated hydrogen bond interactions (C–H · · ·)(N–H · · ·)O=P in 2. For a better understanding of the nature, strength and energetics associated with the formation of the quoted multi-center hydrogen bond interactions, the Natural Bond Order (NBO) method from Density Functional Theory (DFT) and a topological analysis by means of Atoms In Molecules (AIM) and Hirshfeld surface procedures were performed. These studies reveal that the studied multi-center hydrogen bond interactions of the type O · · · H are favoured in the crystal packing displaying enrichment ratios larger than unity. The detailed nature of the different interactions in these multi-center interactions is studied for the first time in such compounds. It is shown that the N–H · · · O interaction is rather non-covalent closed-shell whereas the C–H · · · O interaction is more van der Waals closed-shell. Stronger hydrogen bond interactions are observed for a lower multiple H-atom acceptor oxygen in three-center hydrogen bond interactions (C–H · · ·)(N–H · · ·)O=P of 2 than for four-center interactions in 1 [i.e. (C–H · · ·)2(N–H · · ·)O=P] and 3 [i.e. (C–H · · ·)3O=P]. The better H-atom acceptability of the O atom of P=O compared with the esteric O atom is explained by the richer s-character of the hybrid orbital of the O atom acceptor of P=O coupled with enhance of the polarization and charge. The obtained results are also confirmed by Molecular Electrostatic Potential (MEP).

Bildung von Amidophosphaten und Amidophosphorsäure aus N-Methylcarbamoylphosphaten / Formation of Amidophosphates and Amidophosphoric Acid from N-Methylcarbamoyl Phosphates

1983 ◽  
Vol 38 (7) ◽  
pp. 804-807 ◽  
Author(s):  
Fritz Seel ◽  
N. Klein
Keyword(s):  
Aqueous Solutions ◽  
Sodium Potassium ◽  
Ammonium N ◽  
Amidophosphoric Acid

Abstract The synthesis of various amidophosphates can be readily accomplished in aqueous solutions by the reaction of amines with solutions of sodium, potassium or ammonium N-methylcarbamoyl phosphate, prepared by the reaction of methylisocyanate with the corresponding hydrogen phosphates. Procedures for the synthesis of NH4[O3PNH3] and Ca[O3PNH2CH3]2 · 4 H2O are described in detail.

Ethylenimine derivatives. VI. Diethylenimides of pyrimidyl-5-amidophosphoric acid

1968 ◽  
Vol 2 (2) ◽  
pp. 84-87
Author(s):  
I. E. Mamaeva ◽  
N. V. Sazonov ◽  
A. A. Kropacheva
Keyword(s):  
Amidophosphoric Acid
Sign in / Sign up

Export Citation Format

Share Document