Biodegradable plastic made from soybean products. II. Effects of cross-linking and cellulose incorporation on mechanical properties and water absorption

1994 ◽  
Vol 2 (3) ◽  
pp. 211-217 ◽  
Author(s):  
I. Paetau ◽  
C. -Z. Chen ◽  
J. Jane
Keyword(s):  
Mechanical Properties ◽  
Water Absorption ◽  
Biodegradable Plastic ◽  
Cross Linking

scholarly journals ACID CITRIC CROSS –LINKING OF STARCH/ POLY(VINYL ALCOHOL) BLEND

2011 ◽  
Vol 14 (4) ◽  
pp. 57-66
Author(s):  
Nguyen Thao Tran ◽  
Diem Thi Tuyet Nguyen ◽  
Tai Tan Dang
Keyword(s):  
Mechanical Properties ◽  
Citric Acid ◽  
Water Absorption ◽  
Vinyl Alcohol ◽  
Hydrophilic Polymers ◽  
Poly Vinyl Alcohol ◽  
Cross Linking ◽  
Biodegradable Materials ◽  
Starch Films

In recent times, a number of studies worldwide have focused on strengthening the interaction between the TPS and PVA or modifying with several agents to achieve better mechanical properties, in order to apply in the manufacturing of biodegradable materials. In addition, since both starch and PVA are hydrophilic polymers, they have very strong water absorption ability. In this research, the possibility of cross-linking starch films using citric acid to improve their strength and stability was examined. The study also showed the prospect to limit water absorption of the blend when solubility of the mixture can be reduced to 40%.

scholarly journals The Performance and Characterization of Biodegradable Plastic from Tapioca Starch: Effect of Modified Chitosan

2020 ◽  
Vol 15 (1) ◽  
pp. 45-52
Author(s):  
Lia Ernita ◽  
Medyan Riza ◽  
Syaubari Syaubari
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Water Absorption ◽  
Thin Sheet ◽  
Biodegradable Plastics ◽  
Biodegradable Plastic ◽  
Tapioca Starch ◽  
Modified Chitosan

The performance and characterization of biodegradable plastic from tapioca starch was studied. Modified the chitosan was one of the ingredients for produce  the biodegradable plastics. The produced biodegradable polastic were thin sheet plastic, elastic and transparent. The biodegradable plastic performance had tensile strength between 2,26-3.73 Mpa, elongation ranges from 17.24 to 76.76%, and water absorption ranges from 30.81-268.9%. In antioxidant analyze, apples are wrapped in plastic and had significant mechanical properties changes on 8th day.Morphology scanning result showed that in the chitosan-polyNIPAM there were no cavities may caused high hydrophilicity in the biodegradable plastic.

Incorporation of Iraqi Rocks in the Production of Eco-Friendly Cement Mortar

2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Structural Properties ◽  
Mechanical Milling ◽  
Cement Mortar ◽  
Cement Mortars

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.

scholarly journals Effects of Different Types of Fibers on the Physical and Mechanical Properties of MICP-Treated Calcareous Sand

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 268
Author(s):  
Jitong Zhao ◽  
Huawei Tong ◽  
Yi Shan ◽  
Jie Yuan ◽  
Qiuwang Peng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Water Absorption ◽  
Glass Fiber ◽  
Physical And Mechanical Properties ◽  
Polyester Fiber ◽  
Engineering Properties ◽  
Fiber Types ◽  
Calcite Precipitation ◽  
Calcareous Sand ◽  
Hemp Fiber

Microbial-induced calcite precipitation (MICP) has been a promising method to improve geotechnical engineering properties through the precipitation of calcium carbonate (CaCO3) on the contact and surface of soil particles in recent years. In the present experiment, water absorption and unconfined compressive strength (UCS) tests were carried out to investigate the effects of three different fiber types (glass fiber, polyester fiber, and hemp fiber) on the physical and mechanical properties of MICP-treated calcareous sand. The fibers used were at 0%, 0.10%, 0.15%, 0.20%, 0.25%, 0.30%, 0.35%, and 0.40% relative to the weight of the sand. The results showed that the failure strain and ductility of the samples could be improved by adding fibers. Compared to biocemented sand (BS), the water absorption of these three fiber-reinforced biocemented sands were, respectively, decreased by 11.60%, 21.18%, and 7.29%. UCS was, respectively, increased by 24.20%, 60.76%, and 6.40%. Polyester fiber produced the best effect, followed by glass fiber and hemp fiber. The optimum contents of glass fiber and polyester fiber were 0.20% and 0.25%, respectively. The optimum content of hemp fiber was within the range of 0.20–0.25%. Light-emitting diode (LED) microscope and scanning electron microscope (SEM) images lead to the conclusion that only a little calcite precipitation had occurred around the hemp fiber, leading to a poor bonding effect compared to the glass and polyester fibers. It was therefore suggested that polyester fiber should be used to improve the properties of biocemented sand.

scholarly journals Rational Design of Ag/ZnO Hybrid Nanoparticles on Sericin/Agarose Composite Film for Enhanced Antimicrobial Applications

2020 ◽  
Vol 22 (1) ◽  
pp. 105
Author(s):  
Wanting Li ◽  
Zixuan Huang ◽  
Rui Cai ◽  
Wan Yang ◽  
Huawei He ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Antimicrobial Activity ◽  
Composite Film ◽  
Water Absorption ◽  
Rational Design ◽  
Hybrid Nanoparticles ◽  
Gram Negative Bacteria ◽  
Gram Positive ◽  
Gram Negative ◽  
X Ray

Silver-based hybrid nanomaterials are receiving increasing attention as potential alternatives for traditional antimicrobial agents. Here, we proposed a simple and eco-friendly strategy to efficiently assemble zinc oxide nanoparticles (ZnO) and silver nanoparticles (AgNPs) on sericin-agarose composite film to impart superior antimicrobial activity. Based on a layer-by-layer self-assembly strategy, AgNPs and ZnO were immobilized on sericin-agarose films using the adhesion property of polydopamine. Scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray powder diffraction spectroscopy were used to show the morphology of AgNPs and ZnO on the surface of the composite film and analyze the composition and structure of AgNPs and ZnO, respectively. Water contact angle, swelling ratio, and mechanical property were determined to characterize the hydrophilicity, water absorption ability, and mechanical properties of the composite films. In addition, the antibacterial activity of the composite film was evaluated against Gram-positive and Gram-negative bacteria. The results showed that the composite film not only has desirable hydrophilicity, high water absorption ability, and favorable mechanical properties but also exhibits excellent antimicrobial activity against both Gram-positive and Gram-negative bacteria. It has shown great potential as a novel antimicrobial biomaterial for wound dressing, artificial skin, and tissue engineering.

scholarly journals Effect of Water Ingress on the Mechanical and Chemical Properties of Polybutylene Terephthalate Reinforced with Glass Fibers

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1261
Author(s):  
Catarina S. P. Borges ◽  
Alireza Akhavan-Safar ◽  
Eduardo A. S. Marques ◽  
Ricardo J. C. Carbas ◽  
Christoph Ueffing ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Water Absorption ◽  
Water Uptake ◽  
Significant Influence ◽  
Water Immersion ◽  
Water Diffusion ◽  
Polybutylene Terephthalate ◽  
Chemical Changes ◽  
Water Ingress ◽  
Effect Of Water

Short fiber reinforced polymers are widely used in the construction of electronic housings, where they are often exposed to harsh environmental conditions. The main purpose of this work is the in-depth study and characterization of the water uptake behavior of PBT-GF30 (polybutylene terephthalate with 30% of short glass fiber)as well as its consequent effect on the mechanical properties of the material. Further analysis was conducted to determine at which temperature range PBT-GF30 starts experiencing chemical changes. The influence of testing procedures and conditions on the evaluation of these effects was analyzed, also drawing comparisons with previous studies. The water absorption behavior was studied through gravimetric tests at 35, 70, and 130 °C. Fiber-free PBT was also studied at 35 °C for comparison purposes. The effect of water and temperature on the mechanical properties was analyzed through bulk tensile tests. The material was tested for the three temperatures in the as-supplied state (without drying or aging). Afterwards, PBT-GF30 was tested at room temperature following water immersion at the three temperatures. Chemical changes in the material were also analyzed through Fourier-transform infrared spectroscopy (FTIR). It was concluded that the water diffusion behavior is Fickian and that PBT absorbs more water than PBT-GF30 but at a slightly higher rate. However, temperature was found to have a more significant influence on the rate of water diffusion of PBT-GF30 than fiber content did. Temperature has a significant influence on the mechanical properties of the material. Humidity contributes to a slight drop in stiffness and strength, not showing a clear dependence on water uptake. This decrease in mechanical properties occurs due to the relaxation of the polymeric chain promoted by water ingress. Between 80 and 85 °C, after water immersion, the FTIR profile of the material changes, which suggests chemical changes in the PBT. The water absorption was simulated through heat transfer analogy with good results. From the developed numerical simulation, the minimum plate size to maintain the water ingress unidirectional was 30 mm, which was validated experimentally.

scholarly journals Influence of Rhamnolipids and Ionic Cross-Linking Conditions on the Mechanical Properties of Alginate Hydrogels as a Model Bacterial Biofilm

2021 ◽  
Vol 22 (13) ◽  
pp. 6840
Author(s):  
Natalia Czaplicka ◽  
Szymon Mania ◽  
Donata Konopacka-Łyskawa
Keyword(s):  
Mechanical Properties ◽  
Pure Water ◽  
Testing Machine ◽  
Bacterial Biofilm ◽  
Ion Trapping ◽  
Cross Linking ◽  
Box Behnken Design ◽  
Compression Load ◽  
Alginate Hydrogels ◽  
Biofilm Structure

The literature indicates the existence of a relationship between rhamnolipids and bacterial biofilm, as well as the ability of selected bacteria to produce rhamnolipids and alginate. However, the influence of biosurfactant molecules on the mechanical properties of biofilms are still not fully understood. The aim of this research is to determine the effect of rhamnolipids concentration, CaCl2 concentration, and ionic cross-linking time on the mechanical properties of alginate hydrogels using a Box–Behnken design. The mechanical properties of cross-linked alginate hydrogels were characterized using a universal testing machine. It was assumed that the addition of rhamnolipids mainly affects the compression load, and the value of this parameter is lower for hydrogels produced with biosurfactant concentration below CMC than for hydrogels obtained in pure water. In contrast, the addition of rhamnolipids in an amount exceeding CMC causes an increase in compression load. In bacterial biofilms, the presence of rhamnolipid molecules does not exceed the CMC value, which may confirm the influence of this biosurfactant on the formation of the biofilm structure. Moreover, rhamnolipids interact with the hydrophobic part of the alginate copolymer chains, and then the hydrophilic groups of adsorbed biosurfactant molecules create additional calcium ion trapping sites.

scholarly journals Effects of water absorption on the mechanical properties of hybrid natural fibre/phenol formaldehyde composites

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sekar Sanjeevi ◽  
Vigneshwaran Shanmugam ◽  
Suresh Kumar ◽  
Velmurugan Ganesan ◽  
Gabriel Sas ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Water Absorption ◽  
Hybrid Composites ◽  
Phenol Formaldehyde ◽  
Natural Fibre ◽  
The Other ◽  
Fibre Reinforcement ◽  
Dry Conditions

AbstractThis investigation is carried out to understand the effects of water absorption on the mechanical properties of hybrid phenol formaldehyde (PF) composite fabricated with Areca Fine Fibres (AFFs) and Calotropis Gigantea Fibre (CGF). Hybrid CGF/AFF/PF composites were manufactured using the hand layup technique at varying weight percentages of fibre reinforcement (25, 35 and 45%). Hybrid composite having 35 wt.% showed better mechanical properties (tensile strength ca. 59 MPa, flexural strength ca. 73 MPa and impact strength 1.43 kJ/m2) under wet and dry conditions as compared to the other hybrid composites. In general, the inclusion of the fibres enhanced the mechanical properties of neat PF. Increase in the fibre content increased the water absorption, however, after 120 h of immersion, all the composites attained an equilibrium state.

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