Fractionation of poly(vinyl alcohol) derived from poly(vinyl acetate) from its aqueous solution induced by shearing force-IV

1971 ◽  
Vol 248 (1-2) ◽  
pp. 893-898 ◽  
Author(s):  
K. Yamaura ◽  
S. Kinugasa ◽  
S. Matsuzawa
RSC Advances ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 7653-7660 ◽  
Author(s):  
Bai Xue ◽  
Jianguo Deng ◽  
Junhua Zhang

A series of multiporous open-cell poly(vinyl formal) (PVF) foams were obtained by crosslinking poly(vinyl alcohol) (PVA) with different contents of formaldehyde in aqueous solution.


2016 ◽  
Vol 852 ◽  
pp. 979-983
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li

Sodium acrylate (NaAA) and acrylamide (AM) were grafted onto poly (vinyl alcohol) (PVA) using potassium persulfate as an initiator, Graft copolymerization namely poly (vinyl alcohol)-g-poly (acrylamide/sodium acrylate) (PVA-g-PAM/SAC). The poly (vinyl alcohol)-g-poly (vinylamine/sodium acrylate) (PVAMC) was prepraed by Hofmann rearrangement.The PVAMC homogeneous membrane was characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM).The water resistance of the PVAMC membranes is the best when pH of the PVAMC solutions was 4, at that time the numbers of-NH3+ and-COO- groups trended to be equal, so the isoelectric point was pH=4. At 90 °C the pervaporation of PVAMC composite membrane was tested and showed that the separation factor and the permeate flux were about 1001 and 1341 g/(m2·h) for 90wt% ethanol aqueous solution, and they were about 1297 and 1040 g/(m2·h) for 90wt% isopropanol aqueous solution.


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