Parametric study of the decomposition of NH3 for an induction plasma reactor design

1995 ◽  
Vol 15 (4) ◽  
pp. 693-710 ◽  
Author(s):  
Gervais Soucy ◽  
Jerzy W. Jurewicz ◽  
Maher I. Boulos
2019 ◽  
Vol 144 ◽  
pp. 159-173 ◽  
Author(s):  
Alexander Wright ◽  
Matteo Taglioli ◽  
Faraz Montazersadgh ◽  
Alex Shaw ◽  
Felipe Iza ◽  
...  

Author(s):  
X. Fan ◽  
T. Ishigaki

Abstract The in-flight modification of MoSi2 powders has been carried out by using an Ar-H2 induction plasma. Reactor pressure, powder feed rate and plate power level were taken as the experimental parameters to alter the thermal history of the injected powder particles. Metastable hexagonal structure of P-MoSi2 is the major phase observed in the induction plasma treated molybdenum disilicide powders, the stable phase of tetragonal structure of α-MoSi2 usually retains approximately 30 wt.%. Following the change in experimental condition and the deviation from stoichiometry in raw materials, low silicides, Mo5Si3 and Mo3Si, and free Si were observed. The formation of these phases are explained in terms of metastable eutectic reaction during rapid solidification processing. The relationship between the quantities of all these phases and the experimental conditions has been discussed.


1994 ◽  
Vol 14 (1) ◽  
pp. 59-71 ◽  
Author(s):  
Gervais Soucy ◽  
Jerzy W. Jurewicz ◽  
Maher I. Boulos

1997 ◽  
Vol 12 (5) ◽  
pp. 1315-1326 ◽  
Author(s):  
Xiaobao Fan ◽  
Takamasa Ishigaki ◽  
Yoichiro Sato

In-flight modification of MoSi2 powders has been carried out by using an Ar–H2 induction plasma. Reactor pressure, powder feed rate, and plate power level were taken as the experimental parameters to alter the thermal history of the injected powder particles. Metastable hexagonal structure of β–MoSi2 is the major phase observed in the Ar–H2 induction plasma-treated molybdenum disilicide powders, while the stable phase of tetragonal structure of α–MoSi2 usually retains no less than 30 wt. %. Depending on the experimental condition and the deviation from stoichiometry in raw materials, low silicides, Mo5Si3 and Mo3Si, and free Si were observed,


2019 ◽  
Author(s):  
Nasser Vahedi ◽  
Alparslan Oztekin

Abstract Thermal energy storage has become an integral part of Concentrated Solar Power (CSP) plants to guarantee continuous supply of power demand. For cost-effective solar power generation, the size and operating temperatures of CSP plants should be increased. Thermochemical energy storage (TCES) is the only available solution to meet energy density and high-temperature requirements. Air is mostly used as Heat Transfer Fluid (HTF) for high-temperature CSP plants. For the air-based system, metal redox reactions are good candidates as storage reactant. Application of metal oxide gas-solid redox reaction in storage systems requires an efficient reactor design. Cost-effectiveness and simplicity have made packed bed reactors a viable candidate for high-temperature applications. The high-pressure drop along the bed is the main drawback of such reactors preventing them from widespread applications. Split flow design modification could aid in reducing pressure drop while providing more flexibility in reactor performance control. A cylindrical split-flow packed bed reactor with an annulus for HTF flow is considered as a modified reactor design. The transient two-dimensional axisymmetric numerical model is developed for solving mass, momentum, and energy equations for both gas and solid phases using suitable reaction kinetics for the cobalt oxide redox reaction. A parametric study is performed on cylindrical-shaped split-flow reactor design as a basis for future optimization for complete storage cycle. The effect of split flow ratio and side-channel width on reactor performance are considered. It is shown that both parameters could be used effectively to design and optimize the reactor.


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