Effect of the additions of the waste products of rare-earth elements on the properties of mullite-zircon suspensions

Refractories ◽  
1987 ◽  
Vol 28 (1-2) ◽  
pp. 65-69
Author(s):  
�. V. Degtyareva ◽  
O. T. Gud' ◽  
E. D. Lisovaya ◽  
O. N. Romaniv ◽  
P. G. Maistruk
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Waste Products

High specific surface 1-(2-pyridylazo) 2-naphthol (PAN) modified Carbon-based silicon film with cellulose nanocrystalline structure for efficient adsorption of rare earth elements

2021 ◽  
Author(s):  
Bin Wang ◽  
Yuzhe Zhang ◽  
Wen Sun ◽  
Xudong Zheng ◽  
Zhongyu Li
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Specific Surface ◽  
Cellulose Nanocrystals ◽  
Silicon Film ◽  
Nanocrystalline Structure ◽  
Heavy Rare Earth ◽  
Beneficial Result ◽  
Waste Products ◽  
Heavy Rare Earth Elements

The recovery of rare earth elements, especially heavy rare earth elements, from rare earth waste products has a high economic and environmental beneficial result. In this paper, cellulose nanocrystals used...

scholarly journals Leaching of Rare Earth Elements from Central Appalachian Coal Seam Underclays

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 577
Author(s):  
Scott N. Montross ◽  
Jonathan Yang ◽  
James Britton ◽  
Mark McKoy ◽  
Circe Verba
Keyword(s):  
Rare Earth ◽  
Coal Seam ◽  
Rare Earth Elements ◽  
Chelating Agent ◽  
Analytical Techniques ◽  
Leach Solution ◽  
Alternative Source ◽  
Waste Products ◽  
Energy Applications ◽  
Sequential Digestion

Rare earth elements (REE) are necessary for advanced technological and energy applications. To support the emerging need, it is necessary to identify new domestic sources of REE and technologies to separate and recover saleable REE product in a safe and economical manner. Underclay rock associated with Central Appalachian coal seams and prevalent in coal utilization waste products is an alternative source of REE to hard rock ores that are mainly composed of highly refractory REE-bearing minerals. This study utilizes a suite of analytical techniques and benchtop leaching tests to characterize the properties and leachability of the coal seam underclays sampled. Laboratory bench-top and flow-through reactor leaching experiments were conducted on underclay rock powders to produce a pregnant leach solution (PLS) that has relatively low concentrations of gangue elements Al, Si, Fe, and Th and is amenable to further processing steps to recover and produce purified REE product. The leaching method described here uses a chelating agent, the citrate anion, to solubilize elements that are adsorbed, or weakly bonded to the surface of clay minerals or other mineral solid phases in the rock. The citrate PLS produced from leaching specific underclay powders contains relatively higher concentrations of REE and lower concentrations of gangue elements compared to PLS produced from sequential digestion using ammonium sulfate and mineral acids. Citrate solution leaching of underclay produces a PLS with lower concentrations of gangue elements and higher concentrations of REE than achieved with hydrochloric acid or sulfuric acid. The results provide a preliminary assessment of the types of REE-bearing minerals and potential leachability of coal seam underclays from the Central Appalachian basin.

scholarly journals Potential of garnet sand as an unconventional resource of the critical high-technology metals scandium and rare earth elements

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Franziska Klimpel ◽  
Michael Bau ◽  
Torsten Graupner
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Red Mud ◽  
Waste Product ◽  
Raw Material ◽  
Added Value ◽  
Waste Products ◽  
Unconventional Resource ◽  
Disposal Cost ◽  
Industrial Waste Product

AbstractScandium is a critical raw material that is essential for the EU economy because of its potential application in enabling technologies such as fuel cells and lightweight materials. As there is currently no secure supply of Sc, several projects worldwide evaluate potential Sc sources. While elsewhere in Europe emphasis is placed upon secondary resources such as red mud, we investigated the potential of industrial garnet sand and its waste products. Since Sc readily substitutes for Mg and Fe in the crystal lattice of garnet, the garnet minerals almandine and pyrope, in particular, may show high Sc concentrations. Garnet sand, after being used as an abrasive in the cutting and sandblasting industry, is recycled several times before it is finally considered waste which eventually must be disposed of. Extraction of Sc (and rare earth elements, REE) from such garnet sand may generate added value and thereby reduce disposal cost. The studied garnet sands from different mines in Australia, India and the U.S., and industrial garnet sands commercially available in Germany from different suppliers show average Sc concentrations of 93.7 mg/kg and 90.7 mg/kg, respectively, i.e. similar to red mud. Our data also show that “fresh” and recycled garnet sands yield similar Sc concentrations. Within the framework of a minimum-waste approach, it may be feasible to utilize the industrial waste-product “garnet sand” as an unconventional source of Sc and REE, that reduces disposal cost.

scholarly journals Rare Earth Element Recovery from Acidic Extracts of Florida Phosphate Mining Materials Using Chelating Polymer 1-Octadecene, Polymer with 2,5-Furandione, Sodium Salt

Minerals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 477 ◽  
Author(s):  
Joseph P. Laurino ◽  
Jack Mustacato ◽  
Zachary J. Huba
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Sodium Salt ◽  
Mining Wastes ◽  
Waste Products ◽  
Phosphate Mining ◽  
Global Demand ◽  
Chelating Polymer ◽  
Florida Phosphate ◽  
Alternative Sources

To meet the growing global demand for rare earth elements (REEs), nontraditional mining sources of these metals are being investigated. Phosphate ore and phosphate mining wastes have been identified as possible alternative sources to REEs. In this study, REEs were extracted from Florida phosphate mining materials using mineral and organic acids. The REEs were then recovered at high efficiencies using a chelating polymer, 1-octadecene, polymer with 2,5-furandione, sodium salt. At pH 1.5, the chelation polymer effectively bound nearly 100% of the rare earth elements extracted from the solids. Overall extraction and recovery yields were between 80% for gadolinium and 8% for praseodymium from amine tailings, between 70% for terbium and 7% for praseodymium from phosphogypsum, between 56% for scandium and 15% for praseodymium from phosphate rock, and between 77% for samarium and 31% for praseodymium from waste clay. These results suggest that this chelating polymer efficiently recovers rare earth elements from acidic extracts of phosphate mining waste products.

scholarly journals Extraction of Eu(III), Gd(III), and Tb(III) in aqueous two-phase systems based on polyethylene glycol 1500-NaNO3-H2O with the addition of extractants (D2EHPA, TBP, TOMAN)

2022 ◽  
Vol 1212 (1) ◽  
pp. 012012
Author(s):  
A Ya Fedorov ◽  
A V Levina ◽  
M I Fedorova
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Organic Solvents ◽  
Point Of View ◽  
Water Soluble ◽  
Rational Approach ◽  
Two Phase ◽  
Waste Products ◽  
Aqueous Two Phase Systems ◽  
Phase Systems

Abstract Luminophores that used, for example, in fluorescent lamps, contain a large number of rare earth elements. Therefore, the processing of waste equipment containing luminophores is a rational approach to the obtaining of rare-earth metals, firstly, from the economics point of view, since they have a high cost, and secondly, from the ecological point of view, since environmental pollution will not occur. The cheapest way to extract rare earth elements from waste products is to dissolve them in strong acids and the following reprocessing by liquid extraction methods. In this case, neutral or ion exchange extractants (tributyl phosphate, di(2-ethylhexyl)phosphoric acid and quaternary ammonium salts) are used, which show high extraction ability and, in some cases, selectivity. Their applying is associated with the use of non-polar organic solvents, which contradicts the principles of «green» chemistry. A good and promising alternative to organic solvents can be aqueous two-phase systems, which have already proved themselves as low-toxic, but highly effective systems for the separation of a number of metals. Thus, in this work, we performed an experimental study of the interphase distribution of Eu(III), Gd(III), and Tb(III) in two-phase systems based on water-soluble polymers with or without the introduction of traditional organic extractants as an additive. The possibility of using such ATPS as a «green» solvent for traditional extragents for Eu(III), Gd(III), and Tb(III) extraction has been shown.

scholarly journals Extraction of rare earth elements from waste products of phosphate industry

2021 ◽  
Vol 256 ◽  
pp. 117857
Author(s):  
Abderraouf Soukeur ◽  
Anthony Szymczyk ◽  
Yassine Berbar ◽  
Mourad Amara
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Waste Products ◽  
Phosphate Industry
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